gm2wNo80了微地 0 Ca.C cag猫aw08 OH NHCH3 (CH)C-C)CHCH,C ona (14)CHCH3 HO:SCHCH3 HO-CHCHs CHa CH CH NaOCHCHs CHCH-CHCHOCHCHs CH3 HOCHCH3 HO-CHCH3 CH2=CHCH CH CH2-CHCH CH3 Br Br CH3 (15)HSO/165 ONa OCH:CH:OH (16) ICH3 ()HOCH2(CH2)2CH2CI HO(CH2)4CN OH CH3 (18)CHs CHCOH 了0 Br Br ()OHO.CH.OH OH OCH3 (20)HNO3/H2SO4 NO. ⊙No2 NO2 NO2 13-7 由大到小 (I)ABDC (2)BCA (3)BACD (4)ABCD (5)CBAD (6)ABDC (7)CABD (8)DCAB (9)ACBD 010 BDAC 66 CH3 OH ❵ 7 ❛ CH3 CH3 O C (CH3CHO)3Al (8) O O (9) O CH2 CH2 OC2H5 CH3 CH3 OH OH (10) C6H5C CH2 O C6H5CH CH2 NHCH3 (11 ) O (14) CHCH3 CH3 CHCH3 CH3 HO3S CHCH3 CH3 HO CHCH3 CH3 NaO CHCH3 CH3 CH3CH=CHCH2O CHCH3 CH3 CH3 HO CH2=CHCH CHCH3 CH3 HO CH2 CHCH Br Br
15 H2SO4 /165 C ONa OCH2CH2OH Br CH3 CH3 (18) OH Br CH3 O CH3 OH O OCH2CH2OH (19 ) OH OH CH3 ( NO2 20 ) HNO3 /H2SO4 NO2 NO2 NO2 O 13-7
  ABDC  BCA  BACD  ABCD CBAD ABDC  CABD  DCAB ACBD  BDAC (CH3)2 H OH CH3 (12 ) (CH3 )2 (CH3 )2 (CH3 ) C 2 C CH3 C2H5 CHCH3 C=C (13 ) ONa Br C2H5 CH3 CH3 (16 ) C OH H + I (17 ) HOCH2 (CH2 )2CH2Cl HO(CH2 )4CN