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E. Laarz et al /Journal of the European Ceramic Society 21(2001)1027-1035 1035 Development (NUTEK) and the industrial partner 9. Wasche. R. Steinborn. G. Baader. F: Elektrokinetische Mes- (Erasteel Kloster AB, Ericsson Cables AB, Hoganas sungen zur Charakterisierung wassriger nanodisperser TIN-Sus- AB, Kanthal AB, OFCON Optical Fibre Consultants pensione. Fortschrittsber. DKG, 1994. 9(5), 151-158 (in AB, Sandvik AB, Seco Tools AB, Uniroc AB) is grate German 10. Cesarano Ill, J. and Aksay, I. A, Processing of highly con- fully acknowledged centrated aqueous a-alumina suspensions stabilized with poly electrolytes. J. Am. Ceram Soc., 1988, 71, 1062-1067 I1. Bergstrom, L, Rheological properties of Al2OrSiC whisker References mposite suspensions. J. Mater. Sci., 1996, 31 57-5270 12. Santhiya, D, Nandini, G, Subramanian, S, Natarajan, K. A 1. Whitney, E. D.(ed ) Ceramic cutting tools- materials, de and Malghan, S G, Effect of polymer molecular weight on the nt, and performance. Noyes Publications, Park Ridge, USA, adsorption of polyacrylic acid at the alumina-water interface. Colloid Surf..A,1998,133.157-163 2. Johansson, K.E. Palm. T and Werner. P. E, An automatic 13. Nass, R, Albayrak, S, Aslan, M. and Schmidt, M, Colloidal microdensitometer for X-ray powder diffraction photographs. J. processing and sintering of nano-scale TiN. In Ceramic Transac- Phws.Sci. Instru.,1980.13,1289-1291 ons. Vol. 51. ed. H. Hausner. G. L. Messing and S.I. Hirano 3. Werner, P. E, A fortran program for least-squa merican Ceramic Society, Westerville. 1995 rystal structure cell dimensions. Arkiv for Ken ares geg n mesta Shih. C.J. and Hon. M.-H.. Electrokinetic and rheological 516. properties of aqueous TiN suspensions with ammonium salt of 4. Ahlen, N, Johnsson, M. and Nygren, M, Carbothermal synth (methacrylic acid). Eur. Cere oc.1999,19,.2773- esis of TiC whiskers via a vapour-liquid-solid growth mechan- 2780 ism.J.Am. Ceran.Soc.,1996.79,2803-2808 15. Yeh, C.-H. and Hon, M.-H, Dispersion and stabilization of 5. Ahlen, N,Johnsson, M. and Nygren, M, Synthesis of TIN CI aqueous TiC suspensions. Ceramics International. 1995, 21,65- whiskers.J. Mater. Sci. Lett. 1999. 18. 1071-1074 6. Wagner, J, Janssen, S, Rupp, R, May, R. and Hempelmann. 16. Bergstrom, L. and Bostedt, E, Surface chemistry of silicon R. Characterization of nanoscale titanium nitride dispersions by nitride powders: electrokinetic behaviour and ESCA studies. nall-angle neutron scattering. J. 4. Ceram. Soc.. 1998. 81 3313-3317 17. Zhmud, B. V, Meurk, A. and Bergstrom, L, Evaluation of sur- 7. Greenwood, R and Bergstrom, L, Electroacoustic and rheolo- face ionization parameters from AFM data. J. Colloid Int. Sci. gical properties of aqueous Ce-zrO2(Ce-TZP) suspensions. J. 1998,207,332-343 Eur. Ceran.Soc,1997,17,537-548 18. Dupont, L and Foissy, A, Evaluation of the adsorption trends 8. Wasche. R. and Steinborn. G. Influence of the of a low molecular-weight polyelectrolyte with a site-binding casting of nanosized TiN. J. Eur. Ceram. Soc.. 1997, 17. 421-426 model. Colloids Surf. 4. 1996. 110, 235-248J '   6FK7         6  K   #   # 8*  * # K  # ?   ?    # < ' # <  # F  #7    )     2   /2 4 ) 2 J2 6 27   %  :     "' $  " $   2 ) A   A +  F< /,,L2 2 (  K2 2 A 2   4   A2 2         G)   I    2 1, , ,  , /,>-  />,0/,/2 2 4   A2 2        5  ;    )      2 ; '  < ) /,M,  9/0 9/M2 L2  Z  2 (  !2   )   !2   )        '  '050       2 1, ;,  , , /,,M ! >-0>->2 92  Z  2 (  !2   )   !2 <)    /    2 1, 6  , , /, /,,, " /-C/0/-CL2 M2 4  (2 (  <2 + +2 !) +2   8    +2               )     2 1, ;,  , , /,,> " /0/C2 C2 H  +2   #  * 2              5   0S 6 0SA7    2 1, . ,  , , /,,C   9C09L>2 >2 4*   +2   <    H2 = U                2 1, . ,  , , /,,C   L/0LM2 ,2 4*   +2 <    H2 #  ?2B     !        *        <    2 =   8 , #)> /,,L !697 /9/0/9> 6 H  72 /-2   === (2    ) =2 2 A    )    5          ) ) 2 1, ;,  , , /,>>  /-M0/-MC2 //2 #  * 2 +      0<         2 1, 6  , , /,,M  99C09C-2 /2 < ) J2    H2 <   <2 D  K2 2   !   <2 H2 I   )           ) )      0     2  "  , ;, /,,>  /9C0/M2 /2   +2 ) <2    !2   <  !2             2 =   ?    &2 9/ 2 82 8  H2 2 !    <2=2 8 2      <  ) 4  '  /,,92 /L2 < 2(2   8  !282            5           )6  )  72 1, . ,  , , /,,, ! CC0 C>-2 /92 [  282   8  !282 J         5      2      /,,9  M90 M>2 /M2 #  * 2   #   2 <   )      B    '   <  2  "  , /,,- ! />0/,C2 /C2 S #2 &2 !  2   #  * 2 '           ?! 2 1,  " , , /,,> #  0L2 />2 J  2   ? ) 2 '              ) )       2  "  , ; /,,M # 90L>2 ., / -  , 0 1    . $    + 2+3 +45 /-9
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