赵嘉亮等:纳米技术在镁质耐火材料中应用的研究进展 83 此,纳米技术在镁质耐火材料中的应用是开发结构 3390 功能一体化的长寿命镁质耐火材料的重要途径. [15]Liu Z Y,Yuan L,Yu J K.Improvements in the mechanical properties and oxidation resistance of MgO-C refractories with the 参考文献 addition of nano-Y2O;powder.Ady Appl Ceram,2019,118(5): 249 [1]Norhasri MS M,Hamidah MS,Fadzil A M.Applications of using [16]Ding D H,Lv L H,Xiao G Q,et al.Improved properties of low- nano material in concrete:a review.Constr Build Mater,2017, carbon MgO-C refractories with the addition of multilayer grap- 133:91 hene/MgAl2O composite powders.Int J Appl Ceram Technol, [2]Dai Y J,Li Y W,Xu X F,et al.Fracture behaviour of magnesia 2020.17(2):645 refractory materials in tension with the Brazilian test.Eur Ceram [17]Zhu T B,Li Y W,Sang S B,et al.Improved thermal shock Soc,2019,39(16):5433 resistance of magnesia-graphite refractories by the addition of [3]Wang E H,Chen J H,Hou X M.Design,preparation,and MgO-C pellets.Mater Des,2017,124:16 application of new function refractories.Chin J Eng,2019, [18]Wei G P.Zhu B Q,Li X C,et al.Microstructure and mechanical 41(12):1520 properties of low-carbon Mgo-C refractories bonded by an Fe (王恩会,陈俊红,侯新梅.功能化新型耐火材料的设计、制备及 nanosheet-modified phenol resin.Ceram Int,2015,41(1):1553 应用.工程科学学报,2019,41(12):1520) [19]Yeprem H A.Effect of iron oxide addition on the hydration [4]Dai Y J,Li Y W.Jin S L,et al.Mechanical and fracture resistance and bulk density of doloma.J Eur Ceram Soc,2007, investigation of magnesia refractories with acoustic emission- 27(2-3):1651 based method.J Eur Ceram Soc,2020,40(1):181 [20]Ghosh A,Tripathi H S.Sintering behaviour and hydration [5]Roy J,Chandra S,Maitra S.Nanotechnology in castable resistance of reactive dolomite.Ceram Int,2012,38(2):1315 refractory.Ceram Int,2019,45(1):19 [21]Lee JK,Choi H S,Lee S J.Effect of Fe2O3 additions on the [6]Yao H B,Yao S Z,Luo C,et al.Current research and developing hydration resistance of CaO.J Ceram Process Res,2012,13(5): trend of MgO-C bricks.ChinJEng,2018,40(3):253 646 (姚华柏,姚苏哲,骆昶,等.镁碳砖的研究现状与发展趋势.工 [22]Shahraki A,Ghasemi-Kahrizsangi S,Nemati A.Performance 程科学学报,2018,40(3):253) improvement of MgO-CaO refractories by the addition of nano- [7]Bag M,Adak S,Sarkar R.Study on low carbon containing sized AlO:.Mater Chem Phys,2017,198:354 MgO-C refractory:use of nano carbon.Ceram In,2012.38(3): [23]Dehsheish H G,Karamian E,Owsalou R G,et al.Improvement in 2339 performance of MgO-Ca refractory composites by addition of [8]Luz A P,Souza T M,Pagliosa C,et al.In situ hot elastic modulus Iron (IIl)oxide nanoparticles.Ceram Int,2018,44(13):15880 evolution of MgO-C refractories containing Al,Si or Al-Mg anti- [24]Ghasemi-Kahrizsangi S,Sedeh M B.Dehsheikh H G,et al. oxidants.Ceram Int,2016,42(8):9836 Densification and properties of ZrO2 nanoparticles added [9]Xiao J L,Chen J F,Wei Y W,et al.Oxidation behaviors of magnesia-doloma refractories.Ceram Int,2016,42(14):15658 MgO-C refractories with different Si/SiC ratio in the 1100- [25]Ghasemi-Kahrizsangi S,Dehsheikh H G,Karamian E,et al.Effect 1500℃range.Ceram Int,2019,45(17):21099 of MgAl,O nanoparticles addition on the densification and [10]Bag M,Adak S,Sarkar R.Nano carbon containing MgO-C ref- properties of Mgo-Cao refractories.Ceram Int,2017,43(6): ractory:effect of graphite content.CeramIn,012.38(6):4909 5014 [11]Ding D H,Chong X C,Xiao G Q,et al.Combustion synthesis of [26]Mao HH,Selleby M,Sundman B.A re-evaluation of the liquid BC/Al2O,/C composite powders and their effects on properties of phases in the Cao-Al2O:and MgO-Al2O:systems.Calphad, low carbon MgO-C refractories.Ceram /nt,2019,45(13):16433 2004,28(3):307 [12]Zhu T B,Li Y W,Sang S B,et al.Effect of nanocarbon sources on [27]Beketov I V,Medvedev A I,Samatov O M,et al.Synthesis and microstructure and mechanical properties of MgO-C refractories luminescent properties of MgAlO:Eu nanopowders.J Alloys Ceram Int,2014,40(3):4333 Compd,2014,586(Suppl 1):S472 [13]Wang J K.In-situ Catalytic Preparation Mechanism of Car- [28]Yang L,Meng Q,Lu N,et al.Combustion synthesis and spark bon Nanotube/SiC and Their Application in MgO-C Refractory plasma sintering of MgAl,O-graphene composites.Ceram Int, [Dissertation].Wuhan:Wuhan University of Science and 2019,45(6:7635 Technology,2018 [29]Tong S H,Zhao J Z,Zhang Y C,et al.Corrosion mechanism of (王军凯.碳纳米管/碳化硅原位催化制备、机理及其在MgO-C Al-MgO-MgAl2O refractories in RH refining furnace during 耐火材料中的应用学位论文].武汉:武汉科技大学,2018) production of rail steel.Ceram Int,2020.46(8):10089 [14]Rastegar H,Bavand-vandchali M,Nemati A,et al.Phase and [30]Hashimoto S,Honda S,Hiramatsu T,et al.Fabrication of porous microstructural evolution of low carbon MgO-C refractories with spinel (MgAl2O)from porous alumina using a template method. addition of Fe-catalyzed phenolic resin.Ceram Int,2019,45(3): Ceram Int,.2013.39(2):2077此,纳米技术在镁质耐火材料中的应用是开发结构− 功能一体化的长寿命镁质耐火材料的重要途径. 参 考 文 献 Norhasri M S M, Hamidah M S, Fadzil A M. Applications of using nano material in concrete: a review. Constr Build Mater, 2017, 133:91 [1] Dai Y J, Li Y W, Xu X F, et al. Fracture behaviour of magnesia refractory materials in tension with the Brazilian test. J Eur Ceram Soc, 2019, 39(16): 5433 [2] Wang E H, Chen J H, Hou X M. Design, preparation, and application of new function refractories. Chin J Eng, 2019, 41(12): 1520 (王恩会, 陈俊红, 侯新梅. 功能化新型耐火材料的设计、制备及 应用. 工程科学学报, 2019, 41(12):1520) [3] Dai Y J, Li Y W, Jin S L, et al. Mechanical and fracture investigation of magnesia refractories with acoustic emissionbased method. J Eur Ceram Soc, 2020, 40(1): 181 [4] Roy J, Chandra S, Maitra S. Nanotechnology in castable refractory. Ceram Int, 2019, 45(1): 19 [5] Yao H B, Yao S Z, Luo C, et al. Current research and developing trend of MgO–C bricks. Chin J Eng, 2018, 40(3): 253 (姚华柏, 姚苏哲, 骆昶, 等. 镁碳砖的研究现状与发展趋势. 工 程科学学报, 2018, 40(3):253) [6] Bag M, Adak S, Sarkar R. Study on low carbon containing MgO –C refractory: use of nano carbon. Ceram Int, 2012, 38(3): 2339 [7] Luz A P, Souza T M, Pagliosa C, et al. In situ hot elastic modulus evolution of MgO–C refractories containing Al, Si or Al–Mg antioxidants. Ceram Int, 2016, 42(8): 9836 [8] Xiao J L, Chen J F, Wei Y W, et al. Oxidation behaviors of MgO –C refractories with different Si/SiC ratio in the 1100 – 1500 ℃ range. Ceram Int, 2019, 45(17): 21099 [9] Bag M, Adak S, Sarkar R. Nano carbon containing MgO –C refractory: effect of graphite content. Ceram Int, 2012, 38(6): 4909 [10] Ding D H, Chong X C, Xiao G Q, et al. Combustion synthesis of B4C/Al2O3 /C composite powders and their effects on properties of low carbon MgO–C refractories. Ceram Int, 2019, 45(13): 16433 [11] Zhu T B, Li Y W, Sang S B, et al. Effect of nanocarbon sources on microstructure and mechanical properties of MgO –C refractories. Ceram Int, 2014, 40(3): 4333 [12] Wang J K. In-situ Catalytic Preparation Mechanism of Carbon Nanotube/SiC and Their Application in MgO–C Refractory [Dissertation]. Wuhan: Wuhan University of Science and Technology, 2018 (王军凯. 碳纳米管/碳化硅原位催化制备、机理及其在MgO–C 耐火材料中的应用[学位论文]. 武汉: 武汉科技大学, 2018) [13] Rastegar H, Bavand-vandchali M, Nemati A, et al. Phase and microstructural evolution of low carbon MgO–C refractories with addition of Fe-catalyzed phenolic resin. Ceram Int, 2019, 45(3): [14] 3390 Liu Z Y, Yuan L, Yu J K. Improvements in the mechanical properties and oxidation resistance of MgO–C refractories with the addition of nano-Y2O3 powder. Adv Appl Ceram, 2019, 118(5): 249 [15] Ding D H, Lv L H, Xiao G Q, et al. Improved properties of lowcarbon MgO –C refractories with the addition of multilayer graphene/MgAl2O4 composite powders. Int J Appl Ceram Technol, 2020, 17(2): 645 [16] Zhu T B, Li Y W, Sang S B, et al. Improved thermal shock resistance of magnesia-graphite refractories by the addition of MgO–C pellets. Mater Des, 2017, 124: 16 [17] Wei G P, Zhu B Q, Li X C, et al. Microstructure and mechanical properties of low-carbon MgO –C refractories bonded by an Fe nanosheet-modified phenol resin. Ceram Int, 2015, 41(1): 1553 [18] Yeprem H A. Effect of iron oxide addition on the hydration resistance and bulk density of doloma. J Eur Ceram Soc, 2007, 27(2-3): 1651 [19] Ghosh A, Tripathi H S. Sintering behaviour and hydration resistance of reactive dolomite. Ceram Int, 2012, 38(2): 1315 [20] Lee J K, Choi H S, Lee S J. Effect of Fe2O3 additions on the hydration resistance of CaO. J Ceram Process Res, 2012, 13(5): 646 [21] Shahraki A, Ghasemi-Kahrizsangi S, Nemati A. Performance improvement of MgO –CaO refractories by the addition of nanosized Al2O3 . Mater Chem Phys, 2017, 198: 354 [22] Dehsheish H G, Karamian E, Owsalou R G, et al. Improvement in performance of MgO –CaO refractory composites by addition of Iron (III) oxide nanoparticles. Ceram Int, 2018, 44(13): 15880 [23] Ghasemi-Kahrizsangi S, Sedeh M B, Dehsheikh H G, et al. Densification and properties of ZrO2 nanoparticles added magnesia–doloma refractories. Ceram Int, 2016, 42(14): 15658 [24] Ghasemi-Kahrizsangi S, Dehsheikh H G, Karamian E, et al. Effect of MgAl2O4 nanoparticles addition on the densification and properties of MgO –CaO refractories. Ceram Int, 2017, 43(6): 5014 [25] Mao H H, Selleby M, Sundman B. A re-evaluation of the liquid phases in the CaO –Al2O3 and MgO –Al2O3 systems. Calphad, 2004, 28(3): 307 [26] Beketov I V, Medvedev A I, Samatov O M, et al. Synthesis and luminescent properties of MgAl2O4 :Eu nanopowders. J Alloys Compd, 2014, 586(Suppl 1): S472 [27] Yang L, Meng Q, Lu N, et al. Combustion synthesis and spark plasma sintering of MgAl2O4 -graphene composites. Ceram Int, 2019, 45(6): 7635 [28] Tong S H, Zhao J Z, Zhang Y C, et al. Corrosion mechanism of Al –MgO –MgAl2O4 refractories in RH refining furnace during production of rail steel. Ceram Int, 2020, 46(8): 10089 [29] Hashimoto S, Honda S, Hiramatsu T, et al. Fabrication of porous spinel (MgAl2O4 ) from porous alumina using a template method. Ceram Int, 2013, 39(2): 2077 [30] 赵嘉亮等: 纳米技术在镁质耐火材料中应用的研究进展 · 83 ·