EXAMPLE 2 0.01M0.1M HCI HC Same junction -HCl not KCl Ag/AgCl(S)/H+, CI(1 M) H H+, Cl(0. 1 M)/AgCI(S)Ag Left (1), right(2)So C2=0. 1 and C,=1.0 t=349.82/(34982+76.34)=0.82 E1=-0.05916((2*0.82)-1)og(0.1) =-005916(-0.64)(-1)=-0.038V Note: junction potential much larger significant perturbation on EcellSame junction -HCl not KCl: Ag/AgCl(s)/H+ ,Cl- (1 M)/ H+ , Cl- (0.1 M)/AgCl(s)/Ag Left (1), right (2) so c2 = 0.1 and c1 =1.0 t+ = 349.82/(349.82+76.34) = 0.82 EJ = - 0.05916 ((2 * 0.82)-1)log(0.1) = - 0.05916 (- 0.64) (-1) = - 0.038 V Note: junction potential much larger; significant perturbation on Ecell EXAMPLE 2 0.01 M HCl 0.1 M HCl H+ Cl-