MayerfF-Function and Excluded Volume The Probability P(r of finding two monomers at distance r. Boltzmann factor P(r)a exp[-U (r)/(kBT) Mayer f-function difference of boltzmann factor for two monomers at r and at oo f(r)=exp (u (r/kB t)-1 0.5 Exclude volume v-I f(r)d3r=(1-exp[-U(r)/(kBT)DdrMayer f-Function and Excluded Volume 7 The Probability P(r) of finding two monomers at distance r: Boltzmann factor Mayer f-function: difference of Boltzmann factor for two monomers at r and at λ ݂ ݎ = exp െܷ ݎ݇ Τ ஻ ܶ -1 Exclude Volume v: ݀ ݎ ݂න െ = ݒ ଷ ݎ = න 1 െ exp െܷ ݎ Τ ݇஻ܶ ݀ ଷ ݎ ܶ஻݇ Τ ݎ ܷെ exp ן ݎ ܲ