正在加载图片...
1945 W.PAULI general assumptions. I had always the feeling and I still have it today, that this is a deficiency. Of course in the beginning I hoped that the new quan- tum mechanics, with the help of which it was possible to deduce so many half-empirical formal rules in use at that time, will also rigorously deduce the exclusion principle. Instead of it there was for electrons still an exclusion: not of particular states any longer, but of whole classes of states, namely the ex- clusion of all classes different from the antisymmetrical one. The impression that the shadow of some incompleteness fell here on the bright light of success of the new quantum mechanics seems to me unavoidable. We shall resume this problem when we discuss relativistic quantum mechanics but wish to give first an account of further results of the application of wave mechanics to systems of several like particles In the paper of Heisenberg, which we are discussing, he was also able to give a simple explanation of the existence of the two non-combining spectra of helium which I mentioned in the beginning of this lecture. Indeed, besides the rigorous separation of the wave functions into symmetry classes with re- spect to space-coordinates and spin indices together, there exists an approx- imate separation into symmetry classes with respect to space coordinates alone. The latter holds only so long as an interaction between the spin and he orbital motion of the electron can be neglected. In this way the para- and ortho-helium spectra could be interpreted as belonging to the class of symmetrical and antisymmetrical wave functions respectively in the space coordinates alone. It became clear that the energy difference between cor- responding levels of the two classes has nothing to do with magnetic inter actions but is of a new type of much larger order of magnitude, which called exchange energy Of more fundamental significance is the connection of the symmetry classes with general problems of the statistical theory of heat. As is well known, this theory leads to the result that the entropy of a system is(apart from a constant factor) given by the logarithm of the number of quantum states of the whole system on a so-called energy shell. One might first expect that this number should be equal to the corresponding volume of the multi dimensional phase space divided by It, where h is Plancks constant and fthe number of degrees of freedom of the whole system. However, it turned out that for a system of N like particles, one had still to divide this quotient by N! in order to get a value for the entropy in accordance with the usual postulate of homogeneity that the entropy has to be proportional to the mass for a given inner state of the substance. In this way a qualitative distinction between32 1945 W.PAUL I general assumptions. I had always the feeling and I still have it today, that this is a deficiency. Of course in the beginning I hoped that the new quan￾tum mechanics, with the help of which it was possible to deduce so many half-empirical formal rules in use at that time, will also rigorously deduce the exclusion principle. Instead of it there was for electrons still an exclusion: not of particular states any longer, but of whole classes of states, namely the ex￾clusion of all classes different from the antisymmetrical one. The impression that the shadow of some incompleteness fell here on the bright light of success of the new quantum mechanics seems to me unavoidable. We shall resume this problem when we discuss relativistic quantum mechanics but wish to give first an account of further results of the application of wave mechanics to systems of several like particles. In the paper of Heisenberg, which we are discussing, he was also able to give a simple explanation of the existence of the two non-combining spectra of helium which I mentioned in the beginning of this lecture. Indeed, besides the rigorous separation of the wave functions into symmetry classes with re￾spect to space-coordinates and spin indices together, there exists an approx￾imate separation into symmetry classes with respect to space coordinates alone. The latter holds only so long as an interaction between the spin and the orbital motion of the electron can be neglected. In this way the para￾and ortho-helium spectra could be interpreted as belonging to the class of symmetrical and antisymmetrical wave functions respectively in the space coordinates alone. It became clear that the energy difference between cor￾responding levels of the two classes has nothing to do with magnetic inter￾actions but is of a new type of much larger order of magnitude, which one called exchange energy. Of more fundamental significance is the connection of the symmetry classes with general problems of the statistical theory of heat. As is well known, this theory leads to the result that the entropy of a system is (apart from a constant factor) given by the logarithm of the number of quantum states of the whole system on a so-called energy shell. One might first expect that this number should be equal to the corresponding volume of the multi￾dimensional phase space divided by h f , where h is Planck’s constant and f the number of degrees of freedom of the whole system. However, it turned out that for a system of N like particles, one had still to divide this quotient by N! in order to get a value for the entropy in accordance with the usual postulate of homogeneity that the entropy has to be proportional to the mass for a given inner state of the substance. In this way a qualitative distinction between
<<向上翻页向下翻页>>
©2008-现在 cucdc.com 高等教育资讯网 版权所有