·1158 北京科技大学学报 第34卷 (2)随着H,S质量浓度的增加，腐蚀电流密度 (曹楚南.腐蚀电化学.北京：化学工业出版社，1994) 增大，碳钢腐蚀加剧. [9]He W,Knudsen 00,Diplas S.Corrosion of stainless steel 316 L (3)温度升高，腐蚀极化电阻变小，腐蚀电流密 in simulated formation water environment with CO,H2 S-CI". Corros Sci,2009,51(12):2811 度上升，腐蚀加剧 [10]Keddam M,Mattos OR,Takenouti H.Reaction model for iron (4)腐蚀产物结构层中，外层絮状腐蚀产物主 dissolution studied by electrode impedance:I.Experimental re- 要是铁碳化物，接近基体表面的腐蚀产物主要是铁 sults and reaction model.Electrochem Soc,1981,128(2):257 硫化物. [11]Tang J W,Shao Y W,Guo J B,et al.The effect of H2S concen- tration on the corrosion behavior of carbon steel at 90C.Corros 参考文献 Sci,2010,52(6):2050 Bonis M R,Girgis M,Goerz K,et al.Weight loss corrosion with [12]Banas J,Lelek-Borkowska U.Mazurkiewicz B,et al.Effect of H2S:using past operations for designing future facilities//Corro- CO,and H,S on the composition and stability of passive film on i- sion 2006.San Diego,2006:122 ron alloys in geothermal water.Electrochim Acta,2007,52 [2]Ma H Y,Cheng X L,Li G Q,et al.The influence of hydrogen (18):5704 sulfide on corrosion of iron under different conditions.Corros Sci, [13]Zhang Q,Li QA,Wen J B,et al.Effect of temperature on COz/ 2000,42(10):1669 H.S corrosion rate of tubular steels.Mater Prot,2004,37(4): B]Bai Z Q,Li HL,Liu D X,et al.Corrosion factors of N80 steel in 38 simulated H2S/CO2 environment.Mater Prot,2003,36(4):31 (张清，李全安，文九巴，等.温度对油管钢C0,/H,S腐蚀 (白真权，李鹤林，刘道新，等.模拟油田C02H2S环境中 速率的影响.材料保护，2004,37(4)：38) N80钢的腐蚀及影响因素研究.材料保护，2003,36(4)：31) [14]Neshati J,Abedi S Sh,Forsat Kh,et al.Electrochemical and [4] Choi Y S,Nesic S,Ling S.Effect of H2S on the CO2 corrosion of corrosion behavior of carbon steel in SULFIRAN process.Ma- carbon steel in acidic solutions.Electrochim Acta.2011,56(4): ter Sci Eng B,2009,162(1):40 1752 05] Kang YY,Yuan X,Huang J Y,et al.Corrosion behavior of 5]General Administration of Quality Supervision,Inspection and API X52 steel in H2 S/CO2 saturated aqueous solution of 5% Quarantine of the People's Republic of China.GB/T8650-2006 NaCl.Mater Prot,2008,41(5):7 Evaluation of Pipeline and Pressure Vessel Steels for Resistance to (康永印，袁曦，黄金营，等.X52钢在H2S/C0,饱和5% Hydrogen-induced Cracking.Beijing:China Standard Press, NaC1溶液中的腐蚀行为研究.材料保护，2008,41(5)：7) 2006:11 [16]ArzolaPeralta S,Mendoza-Flores J,Duran-Romero R,et al. (中华人民共和国国家质量监督检验检疫总局.GB/T8650一 Cathodic kinetics of API X70 pipeline steel corrosion in H2S con- 2006管线钢和压力容器钢抗氢致开裂的评定方法.北京：中 taining solutions under turbulent flow conditions.Corros Eng Sci 国标准出版社，2006：11) Technol,2006,41(4):321 6]Zhang L,Li X G,Du C W.Effect of environmental factors on [17]Abelev E,Ramanarayanan T A,Bernasek S L.Iron corrosion in electrochemical behavior of X70 pipeline steel in simulated soil so- CO2/brine at low H2S concentrations:an electrochemical and lution.J fron Steel Res Int,2009,16(6):52 surface science study.J Electrochem Soc,2009,156(9):C331 7]Deng H Y,He X Y,Wang H Y,et al.Corrosion behavior of X70 [18]Veloz M A,Gonzalez I.Electrochemical study of carbon steel steel in HAc-NaAc solution with C02.J Chin Soc Corros Prot, corrosion in buffered acetic acid solutions with chlorides and H, 2007,27(4):224 S.Electroch Acta,2002,48(2)135 (邓海英，何晓英，王红云，等.X70钢在饱和CO2的HAc一 [19]Yang J W,Zhang L,Ding R M,et al.H2 S/CO,corrosion be- NaAc溶液中的腐蚀行为.中国腐蚀与防护学报，2007,27 havior of X60 pipeline steel in wet gas and solution.Acta Metall (4):224) Sin,2008,44(11):1366 [8]Cao C N.Corrosion Electrochemistry.Beijing:Chemical Industry (杨建伟，张雷，丁容明，等.X60管线钢在湿气和溶液介质 Pre5s,1994 中的H2S/C02腐蚀行为.金属学报，2008,44(11)：1366)北 京 科 技 大 学 学 报 第 34 卷 ( 2) 随着 H2 S 质量浓度的增加，腐蚀电流密度 增大，碳钢腐蚀加剧． ( 3) 温度升高，腐蚀极化电阻变小，腐蚀电流密 度上升，腐蚀加剧． ( 4) 腐蚀产物结构层中，外层絮状腐蚀产物主 要是铁碳化物，接近基体表面的腐蚀产物主要是铁 硫化物． 参 考 文 献 ［1］ Bonis M R，Girgis M，Goerz K，et al． Weight loss corrosion with H2 S: using past operations for designing future facilities / / Corro￾sion 2006． San Diego，2006: 122 ［2］ Ma H Y，Cheng X L，Li G Q，et al． The influence of hydrogen sulfide on corrosion of iron under different conditions． Corros Sci， 2000，42 ( 10) : 1669 ［3］ Bai Z Q，Li H L，Liu D X，et al． Corrosion factors of N80 steel in simulated H2 S /CO2 environment． Mater Prot，2003，36( 4) : 31 ( 白真权，李鹤林，刘道新，等． 模拟油田 CO2 /H2 S 环境中 N80 钢的腐蚀及影响因素研究． 材料保护，2003，36( 4) : 31) ［4］ Choi Y S，Nesic S，Ling S． Effect of H2 S on the CO2 corrosion of carbon steel in acidic solutions． Electrochim Acta，2011，56( 4) : 1752 ［5］ General Administration of Quality Supervision，Inspection and Quarantine of the People's Republic of China． GB /T8650—2006 Evaluation of Pipeline and Pressure Vessel Steels for Resistance to Hydrogen-induced Cracking． Beijing: China Standard Press， 2006: 11 ( 中华人民共和国国家质量监督检验检疫总局． GB /T8650— 2006 管线钢和压力容器钢抗氢致开裂的评定方法． 北京: 中 国标准出版社，2006: 11) ［6］ Zhang L，Li X G，Du C W． Effect of environmental factors on electrochemical behavior of X70 pipeline steel in simulated soil so￾lution． J Iron Steel Res Int，2009，16( 6) : 52 ［7］ Deng H Y，He X Y，Wang H Y，et al． Corrosion behavior of X70 steel in HAc-NaAc solution with CO2 ． J Chin Soc Corros Prot， 2007，27( 4) : 224 ( 邓海英，何晓英，王红云，等． X70 钢在饱和 CO2 的 HAc-- NaAc 溶液中 的 腐 蚀 行 为． 中国腐蚀与防护学报，2007，27 ( 4) : 224) ［8］ Cao C N． Corrosion Electrochemistry． Beijing: Chemical Industry Press，1994 ( 曹楚南． 腐蚀电化学． 北京: 化学工业出版社，1994) ［9］ He W，Knudsen O ，Diplas S． Corrosion of stainless steel 316 L in simulated formation water environment with CO2 -H2 S-Cl － ． Corros Sci，2009，51( 12) : 2811 ［10］ Keddam M，Mattos O R，Takenouti H． Reaction model for iron dissolution studied by electrode impedance: Ⅰ． Experimental re￾sults and reaction model． Electrochem Soc，1981，128( 2) : 257 ［11］ Tang J W，Shao Y W，Guo J B，et al． The effect of H2 S concen￾tration on the corrosion behavior of carbon steel at 90 ℃ ． Corros Sci，2010，52( 6) : 2050 ［12］ Bana ＇ s J，Lelek-Borkowska U，Mazurkiewicz B，et al． Effect of CO2 and H2 S on the composition and stability of passive film on i￾ron alloys in geothermal water． Electrochim Acta，2007，52 ( 18) : 5704 ［13］ Zhang Q，Li Q A，Wen J B，et al． Effect of temperature on CO2 / H2 S corrosion rate of tubular steels． Mater Prot，2004，37( 4) : 38 ( 张清，李全安，文九巴，等． 温度对油管钢 CO2 /H2 S 腐蚀 速率的影响． 材料保护，2004，37( 4) : 38) ［14］ Neshati J，Abedi S Sh，Forsat Kh，et al． Electrochemical and corrosion behavior of carbon steel in SULFIRAN process． Ma￾ter Sci Eng B，2009，162( 1) : 40 ［15］ Kang Y Y，Yuan X，Huang J Y，et al． Corrosion behavior of API X52 steel in H2 S /CO2 saturated aqueous solution of 5% NaCl． Mater Prot，2008，41( 5) : 7 ( 康永印，袁曦，黄金营，等． X52 钢在 H2 S /CO2 饱和 5% NaCl 溶液中的腐蚀行为研究． 材料保护，2008，41( 5) : 7) ［16］ Arzola-Peralta S，Mendoza-Flores J，Duran-Romero R，et al． Cathodic kinetics of API X70 pipeline steel corrosion in H2 S con￾taining solutions under turbulent flow conditions． Corros Eng Sci Technol，2006，41( 4) : 321 ［17］ Abelev E，Ramanarayanan T A，Bernasek S L． Iron corrosion in CO2 /brine at low H2 S concentrations: an electrochemical and surface science study． J Electrochem Soc，2009，156( 9) : C331 ［18］ Veloz M A，González I． Electrochemical study of carbon steel corrosion in buffered acetic acid solutions with chlorides and H2 S． Electroch Acta，2002，48( 2) : 135 ［19］ Yang J W，Zhang L，Ding R M，et al． H2 S /CO2 corrosion be￾havior of X60 pipeline steel in wet gas and solution． Acta Metall Sin，2008，44( 11) : 1366 ( 杨建伟，张雷，丁睿明，等． X60 管线钢在湿气和溶液介质 中的 H2 S /CO2腐蚀行为． 金属学报，2008，44( 11) : 1366) ·1158·