第12期 王喆等：捣固焦高温气化反应特性 ·1607· 图7宫碱时捣固焦A反应后微观形貌.(a)1100℃，外部：(b)1100℃，内部：(c)1200℃，外部：()1200℃，内部 Fig.7 SEM morphologies of stamp charging coke A after the reaction with alkalis:(a)1I00℃，external;(b)ll00℃，internal;(c)l200℃，ex- ternal:(d)1l00℃，internal 参考文献 6]Zhong Y F.Several worth attention issues of cokemaking with [Pan D.Improvement and development of stamp-charging coking stamping coke oven.Fuel Chem Processes,2011,42(1):1 technology in China.Fuel Chem Processes,2013,44(2):1 (钟英飞。坞固炼焦值得关注的几个问题.燃料与化工， (潘登.我国捣固炼焦技术的进步与发展方向.燃料与化工， 2011,42(1):1) 2013,44(2):1) Sun C G,Zhou Y H.Discussion on application of incoherent low- Zhou S Y.Zhao JG.Properties of Coking Coal and Quality of ash coal in stamping coking production.Gas Heat,2006,25 Coke for the Blast Furnace.Beijing:Metallurgical Industry Press, (11):29 2005 (孙长贵，周云辉.不粘结低灰煤用于捣固炼焦生产的探讨 (周师庸，赵俊国.炼焦煤性质与高炉焦炭质量.北京：治金 煤气与热力，2006,25(11)：29) 工业出版社，2005) [8] Peng C H.Improving the quality of stamp-charged coke to meet B3]Shi S Z,Lei Y H,Cao S M,et al.Influence of the bulk density of the requirement of blast furnace in Lian Steel Compony.Coal coal charge on the performance of stamp-coking coke.Wuhan Chem Ind,2007(6):16 Univ Sci Technol,2011,34(4):285 (彭陈辉.提高捣固焦炭质量，满足涟钢高炉需求.煤化工， (史世庄，雷耀辉，曹素梅，等.堆积密度对捣固炼焦焦炭性 2008(6):16) 能的影响.武汉科技大学学报，2011,34(4)：285) Zhang J P.Metallurgical coke produced in the stamping coke oven 4]Li Y H.Liu S.Application of stamped coke in blast fumnace.Coal with anthracite as major coal for coke-making.Fuel Chem Proces- Chem Ind,2010(4):45 ss,2007,37(6):9 (李应海，刘爽.坞固焦炭在高炉中的应用.煤化工，2010 (张建平以无烟煤为主在捣固焦炉中生产治金焦.燃料与化 (4):45) 工，2005,37(6)：9) [5]Ma C.Zhang JL,Pang Q H,et al.Alkali resistance comparison [10]Krishnan S H,Dash PS,Guha M,et al.Application of binder between coke made with stamp-charging battery and top-charging in stamp charge coke making.IS/J Int,2004,44(7)1150 battery under high temperature.Fuel Chem Processes,2012,43 [11]Dash P S,Krishnan S H,Sharma R,et al.Laboratory scale in- (5):25 vestigation to improve the productivity of stamp charge coke oven (马超，张建良，庞清海，等。高温捣固焦与顶装焦抗碱性差 through optimisation of bulk density of coal cake.IS/J Int,2005, 异研究.燃料与化工，2012,43(5)：25) 45(11):1577第 12 期 王 喆等: 捣固焦高温气化反应特性 图 7 富碱时捣固焦 A 反应后微观形貌． ( a) 1100 ℃，外部; ( b) 1100 ℃，内部; ( c) 1200 ℃，外部; ( d) 1200 ℃，内部 Fig． 7 SEM morphologies of stamp charging coke A after the reaction with alkalis: ( a) 1100 ℃，external; ( b) 1100 ℃，internal; ( c) 1200 ℃，ex￾ternal; ( d) 1100 ℃，internal 参 考 文 献 ［1］ Pan D． Improvement and development of stamp-charging coking technology in China． Fuel Chem Processes，2013，44( 2) : 1 ( 潘登． 我国捣固炼焦技术的进步与发展方向． 燃料与化工， 2013，44( 2) : 1) ［2］ Zhou S Y，Zhao J G． Properties of Coking Coal and Quality of Coke for the Blast Furnace． Beijing: Metallurgical Industry Press， 2005 ( 周师庸，赵俊国． 炼焦煤性质与高炉焦炭质量． 北京: 冶金 工业出版社，2005) ［3］ Shi S Z，Lei Y H，Cao S M，et al． Influence of the bulk density of coal charge on the performance of stamp-coking coke． J Wuhan Univ Sci Technol，2011，34( 4) : 285 ( 史世庄，雷耀辉，曹素梅，等． 堆积密度对捣固炼焦焦炭性 能的影响． 武汉科技大学学报，2011，34( 4) : 285) ［4］ Li Y H，Liu S． Application of stamped coke in blast furnace． Coal Chem Ind，2010( 4) : 45 ( 李应海，刘爽． 捣固焦炭在高炉中的应用． 煤化工，2010 ( 4) : 45) ［5］ Ma C，Zhang J L，Pang Q H，et al． Alkali resistance comparison between coke made with stamp-charging battery and top-charging battery under high temperature． Fuel Chem Processes，2012，43 ( 5) : 25 ( 马超，张建良，庞清海，等． 高温捣固焦与顶装焦抗碱性差 异研究． 燃料与化工，2012，43( 5) : 25) ［6］ Zhong Y F． Several worth attention issues of cokemaking with stamping coke oven． Fuel Chem Processes，2011，42( 1) : 1 ( 钟英飞． 捣固炼焦值得关注的几个问题． 燃 料 与 化 工， 2011，42( 1) : 1) ［7］ Sun C G，Zhou Y H． Discussion on application of incoherent low￾ash coal in stamping coking production． Gas Heat，2006，25 ( 11) : 29 ( 孙长贵，周云辉． 不粘结低灰煤用于捣固炼焦生产的探讨． 煤气与热力，2006，25( 11) : 29) ［8］ Peng C H． Improving the quality of stamp-charged coke to meet the requirement of blast furnace in Lian Steel Compony． Coal Chem Ind，2007( 6) : 16 ( 彭陈辉． 提高捣固焦炭质量，满足涟钢高炉需求． 煤化工， 2008( 6) : 16) ［9］ Zhang J P． Metallurgical coke produced in the stamping coke oven with anthracite as major coal for coke-making． Fuel Chem Proces￾ses，2007，37( 6) : 9 ( 张建平． 以无烟煤为主在捣固焦炉中生产冶金焦． 燃料与化 工，2005，37( 6) : 9) ［10］ Krishnan S H，Dash P S，Guha M，et al． Application of binder in stamp charge coke making． ISIJ Int，2004，44( 7) : 1150 ［11］ Dash P S，Krishnan S H，Sharma Ｒ，et al． Laboratory scale in￾vestigation to improve the productivity of stamp charge coke oven through optimisation of bulk density of coal cake． ISIJ Int，2005， 45( 11) : 1577 · 7061 ·