·816 北京科技大学学报 第36卷 -2):251 self-assembled nanoporous WO;with preferential orientation of B]Bamwenda G R,Sayama K.Arakawa H.The effect of selected re- (002)planes.Enriron Sci Technol,2007,41 (12)4422 action parameters on the photoproduction of oxygen and hydrogen [11]Zhang Q,Chakraborty A K,Lee W I.Wis0 and WO3 nanorod from a WO3-Fe2-Fe+aqueous suspension.Photochem arrays prepared by AAO-emplated electrodeposition method.Bull Photobiol A,1999,122(3):175 Korean Chem Soc,2009,30(1)227 4]Yu J,Qi L.Templatefree fabrication of hierarchically flower-ike [12]Shibuya M,Miyauchi M.Site-selective deposition of metal nano- tungsten trioxide assemblies with enhanced visible-ight-driven particles on aligned WO3 nanotrees for super-hydrophilic thin photocatalytic activity.J hazard Mater,2009,169(1-3):221 f6lms.Ade Mater,2009,21(13):1373 [5]Xiang Q,Meng G F,Zhao H B,et al.Au nanoparticle modified [13]Zhang J,Tu J,Xia X,et al.Hydrothermally synthesized WO3 WO nanorods with their enhanced properties for photocatalysis and nanowire arrays with highly improved electrochromic perform- gas sensing.J Phys Chem C,2010,114(5):2049 ance.J Mater Chem,2011,21:5492 6]Ashkarran AA,Irajizad A,Ahadian MM,et al.Synthesis and [14]Ma D,Shi G,Wang H,et al.Morphology-ailored synthesis of photocatalytic activity of WO;nanoparticles prepared by the are vertically aligned ID WO,nano-structure films for highly en- discharge method in deionized water.Nanotechnology,2008,19 hanced electrochromic performance.Mater Chem A,2013,1: (19):195709 684 Gao M J.Guo M,Wang X D.Contrast on COD photo-degradation [15]Wang J,Khoo E,Lee P S,et al.Synthesis,assembly,and in coking wastewater catalyzed by TiO,and TiO-TiO2 nanorod ar- electrochromic properties of uniform crystalline WO,nanorods.J rays.Catal Today,2011,174(1-2):79 Phys Chem C,2008,112(37):14306 [8]Cubbala S,Thangala J,Sunkara M K.Nanowire-based electro- 16] Salmaoui S,Sediri F,Gharbi N.Characterization of h-WO3 chromic devices.Sol Energy Mater Sol Cells,2007,91(9):813 nanorods synthesized by hydrothermal process.Polyhedron Cao B,Chen J,Tang X,et al.Growth of monoclinic WO3 2010,29(7):1771 nanowire array for highly sensitive NO2 detection.J Mater Chem, 07]Wang H,Quan X,Zhang Y,et al.Direct growth and photoelec- 2009,19:2323 trochemical properties of tungsten oxide nanobelt arrays.Nano- [10]Guo Y,Quan X,Lu N,et al.High photocatalytie capability of technology,2008,19(6):065704北 京 科 技 大 学 学 报 第 36 卷 － 2) : 251 ［3］ Bamwenda G Ｒ，Sayama K，Arakawa H． The effect of selected re￾action parameters on the photoproduction of oxygen and hydrogen from a WO3 － Fe2 + － Fe3 + aqueous suspension． J Photochem Photobiol A，1999，122( 3) : 175 ［4］ Yu J，Qi L． Template-free fabrication of hierarchically flower-like tungsten trioxide assemblies with enhanced visible-light-driven photocatalytic activity． J hazard Mater，2009，169( 1--3) : 221 ［5］ Xiang Q，Meng G F，Zhao H B，et al． Au nanoparticle modified WO3 nanorods with their enhanced properties for photocatalysis and gas sensing． J Phys Chem C，2010，114( 5) : 2049 ［6］ Ashkarran A A，Irajizad A，Ahadian M M，et al． Synthesis and photocatalytic activity of WO3 nanoparticles prepared by the arc discharge method in deionized water． Nanotechnology，2008，19 ( 19) : 195709 ［7］ Gao M J，Guo M，Wang X D． Contrast on COD photo-degradation in coking wastewater catalyzed by TiO2 and TiO2 -TiO2 nanorod ar￾rays． Catal Today，2011，174( 1--2) : 79 ［8］ Gubbala S，Thangala J，Sunkara M K． Nanowire-based electro￾chromic devices． Sol Energy Mater Sol Cells，2007，91( 9) : 813 ［9］ Gao B，Chen J，Tang X，et al． Growth of monoclinic WO3 nanowire array for highly sensitive NO2 detection． J Mater Chem， 2009，19: 2323 ［10］ Guo Y，Quan X，Lu N，et al． High photocatalytic capability of self-assembled nanoporous WO3 with preferential orientation of ( 002) planes． Environ Sci Technol，2007，41( 12) : 4422 ［11］ Zhang Q，Chakraborty A K，Lee W I． W18O49 and WO3 nanorod arrays prepared by AAO-templated electrodeposition method． Bull Korean Chem Soc，2009，30( 1) : 227 ［12］ Shibuya M，Miyauchi M． Site-selective deposition of metal nano￾particles on aligned WO3 nanotrees for super-hydrophilic thin films． Adv Mater，2009，21( 13) : 1373 ［13］ Zhang J，Tu J，Xia X，et al． Hydrothermally synthesized WO3 nanowire arrays with highly improved electrochromic perform￾ance． J Mater Chem，2011，21: 5492 ［14］ Ma D，Shi G，Wang H，et al． Morphology-tailored synthesis of vertically aligned 1D WO3 nano-structure films for highly en￾hanced electrochromic performance． J Mater Chem A，2013，1: 684 ［15］ Wang J，Khoo E，Lee P S，et al． Synthesis，assembly，and electrochromic properties of uniform crystalline WO3 nanorods． J Phys Chem C，2008，112( 37) : 14306 ［16］ Salmaoui S，Sediri F，Gharbi N． Characterization of h-WO3 nanorods synthesized by hydrothermal process． Polyhedron， 2010，29( 7) : 1771 ［17］ Wang H，Quan X，Zhang Y，et al． Direct growth and photoelec￾trochemical properties of tungsten oxide nanobelt arrays． Nano￾technology，2008，19( 6) : 065704 ·816·