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2-ethyipentanoic acii 3-bromo-2-ethyibutanoic acid Rcycloherenecarboryhic acid 5-bromo-2-methyibenzoic aicd In the first example, the parent chain is a pentane and the carboxylic acid group is assigned as carbon #1. On the pentane parent, there is an ethy l group in position #2 hence the name, 2-ethy pentanoic acid In the second example, there are two potential four-carbon chains; in this case the chain with the most substituents is selected as parent,(a butanoic acid Attached to the butanoic acid at carbon #2 is an ethyl group and at carbon #3, a bromine; hence the name 3-bromo-2-ethylbutanoic acid In the third example, the carboxylic acid is attached to a cycloalkene ring and will therefore be named as a"carboxylic acid" substituent (rule #4).The parent ring is a cyclohexene; letting the carboxylic acid be carbon #1, the name is 2-cyclohexenecarboxylic acid In the last example, the name is based on benzoic acid as the parent. In this case, we simply number the substituents to give the lowest number sequence at the first point of difference and arrange alphabetically 5-bromo-2-methy benzoic acid Reactions which Yield Carboxylic Acids Oxidation of Aromatic Side-Chains with Neutral PermaganateIn the first example, the parent chain is a pentane and the carboxylic acid group is assigned as carbon #1. On the pentane parent, there is an ethyl group in position #2; hence the name, 2-ethylpentanoic acid. In the second example, there are two potential four-carbon chains; in this case, the chain with the most substituents is selected as parent, (a butanoic acid). Attached to the butanoic acid at carbon #2 is an ethyl group and at carbon #3, a bromine; hence the name 3-bromo-2-ethylbutanoic acid. In the third example, the carboxylic acid is attached to a cycloalkene ring and will therefore be named as a "carboxylic acid" substituent (rule #4). The parent ring is a cyclohexene ; letting the carboxylic acid be carbon #1, the name is 2-cyclohexenecarboxylic acid. In the last example, the name is based on benzoic acid as the parent. In this case, we simply number the substituents to give the lowest number sequence at the first point of difference and arrange alphabetically; 5-bromo-2-methylbenzoic acid. Reactions which Yield Carboxylic Acids Oxidation of Aromatic Side-Chains with Neutral Permaganate
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