工程科学学报.第43卷，第1期：67-75,2021年1月 Chinese Journal of Engineering,Vol.43,No.1:67-75,January 2021 https://doi.org/10.13374/j.issn2095-9389.2020.06.17.002;http://cje.ustb.edu.cn 层状金属复合材料的发展历程及现状 张婷，许浩，李仲杰，董安平四，邢辉，杜大帆，孙宝德 上海交通大学材料科学与工程学院上海市先进高温材料及其精密成形重点实验室，上海200240 ☒通信作者，E-mail:apdong@sjtu.edu.cn 摘要三十多年来，多种层状金属复合材料的制备方法应运而生，蓬勃发展，包括爆炸复合法、轧制复合法、热压扩散法和 沉积复合法等.爆炸复合法在中厚板的制备上具有不可替代的优势，其产品广泛应用于军工、船舶、电力和化工等领域.轧 制法可以批量生产大尺寸层压板，应用最为广泛，目前层压板已经广泛用于汽车、船舶和航空航天等领域.真空热压扩散法 由于可以避免氧气等气体的污染，几年来在TiAl、Ti/TiAI和Ti6Al4VTAI层状复合材料的制备上备受关注.沉积复合法制 备的层状金属复合材料在作为耐蚀、耐磨涂层，高强导线，人体植入材料方面表现出巨大的潜力.在综述层状金属复合材料 发展历程的基础上，介绍了层状金属复合材料的制备方法及各自的优缺点，并对层状金属复合材料目前在国内外的研究现状 进行了分析和介绍. 关键词层状金属复合材料：发展历程：制备方法：研究现状：发展前景 分类号TG142.71 Development and present situation of laminated metal composites ZHANG Ting,XU Hao,LI Zhong-jie,DONG An-ping,XING Hui.DU Da-fan,SUN Bao-de Shanghai Key Lab of Advanced High-temperature Materials and Precision Forming.School of Materials Science and Engineering.Shanghai Jiao Tong University,Shanghai 200240,China Corresponding author,E-mail:apdong@sjtu.edu.cn ABSTRACT Laminated metal composites are composed of two or more metals or alloys,which integrate various excellent properties of the component materials and exhibit good comprehensive properties.The history of laminated metal composites can be traced back to more than 800 BC,and their systematic research began in the 1970s.Over the past 30 years,various methods have been invented to fabricate laminated metal composites,including explosive bonding,rolling bonding,hot-pressing bonding,and deposition bonding. Explosive bounding method has irreplaceable advantages in the preparation of medium thick plates with its products being widely used in military industry,ship,electric power,chemical industry,and other fields.On the other hand,rolling bonding is most widely used because of its ability of large quantity production.Cold roll bonding(CRB)and accumulative roll bonding(ARB)are two representative laminate preparation technologies that are utilized in the fabrication of a large number of material systems.Up to now,laminates prepared by rolling bonding are widely used in automobile,ship,aerospace,and other fields.The preparation of Ti/Al,Ti/TiAl,and Ti6Al4V/TiAl layered composites via vacuum hot-pressing bonding has attracted much attention in recent years because of its ability to avoid gas pollution such as oxygen production.Moreover,laminated metal composites produced by deposition bonding have great potential as corrosion resistant coatings,wear-resistant coatings,and high-strength conductors and implants.Although laminated metal composites have been well developed,there are still various problems to be solved.For some soft/hard material systems,the hard layer introduces plastic instability during the rolling process that destroys the continuity between layers.As a consequence,serious weakening of the comprehensive performance of the laminates is observed.Furthermore,only few studies on the design and new processes of 收稿日期：2020-06-17 基金项目：国家自然科学基金资助项目(51871152.U1760110.52071205.51821001)层状金属复合材料的发展历程及现状 张    婷，许    浩，李仲杰，董安平苣，邢    辉，杜大帆，孙宝德 上海交通大学材料科学与工程学院上海市先进高温材料及其精密成形重点实验室，上海 200240 苣通信作者，E-mail：apdong@sjtu.edu.cn 摘    要    三十多年来，多种层状金属复合材料的制备方法应运而生，蓬勃发展，包括爆炸复合法、轧制复合法、热压扩散法和 沉积复合法等. 爆炸复合法在中厚板的制备上具有不可替代的优势，其产品广泛应用于军工、船舶、电力和化工等领域. 轧 制法可以批量生产大尺寸层压板，应用最为广泛，目前层压板已经广泛用于汽车、船舶和航空航天等领域. 真空热压扩散法 由于可以避免氧气等气体的污染，几年来在 Ti/Al、Ti/TiAl 和 Ti6Al4V/TiAl 层状复合材料的制备上备受关注. 沉积复合法制 备的层状金属复合材料在作为耐蚀、耐磨涂层，高强导线，人体植入材料方面表现出巨大的潜力. 在综述层状金属复合材料 发展历程的基础上，介绍了层状金属复合材料的制备方法及各自的优缺点，并对层状金属复合材料目前在国内外的研究现状 进行了分析和介绍. 关键词    层状金属复合材料；发展历程；制备方法；研究现状；发展前景 分类号    TG142.71 Development and present situation of laminated metal composites ZHANG Ting，XU Hao，LI Zhong-jie，DONG An-ping苣 ，XING Hui，DU Da-fan，SUN Bao-de Shanghai Key Lab of Advanced High-temperature Materials and Precision Forming, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China 苣 Corresponding author, E-mail: apdong@sjtu.edu.cn ABSTRACT    Laminated metal composites are composed of two or more metals or alloys, which integrate various excellent properties of the component materials and exhibit good comprehensive properties. The history of laminated metal composites can be traced back to more than 800 BC, and their systematic research began in the 1970s. Over the past 30 years, various methods have been invented to fabricate  laminated  metal  composites,  including  explosive  bonding,  rolling  bonding,  hot-pressing  bonding,  and  deposition  bonding. Explosive bounding method has irreplaceable advantages in the preparation of medium thick plates with its products being widely used in military industry, ship, electric power, chemical industry, and other fields. On the other hand, rolling bonding is most widely used because of its ability of large quantity production. Cold roll bonding (CRB) and accumulative roll bonding (ARB) are two representative laminate  preparation  technologies  that  are  utilized  in  the  fabrication  of  a  large  number  of  material  systems.  Up  to  now,  laminates prepared  by  rolling  bonding  are  widely  used  in  automobile,  ship,  aerospace,  and  other  fields.  The  preparation  of  Ti/Al,  Ti/TiAl,  and Ti6Al4V/TiAl layered composites via vacuum hot-pressing bonding has attracted much attention in recent years because of its ability to avoid  gas  pollution  such  as  oxygen  production.  Moreover,  laminated  metal  composites  produced  by  deposition  bonding  have  great potential as corrosion resistant coatings, wear-resistant coatings, and high-strength conductors and implants. Although laminated metal composites have been well developed, there are still various problems to be solved. For some soft/hard material systems, the hard layer introduces plastic instability during the rolling process that destroys the continuity between layers. As a consequence, serious weakening of  the  comprehensive  performance  of  the  laminates  is  observed.  Furthermore,  only  few  studies  on  the  design  and  new  processes  of 收稿日期: 2020−06−17 基金项目: 国家自然科学基金资助项目（51871152，U1760110，52071205，51821001） 工程科学学报，第 43 卷，第 1 期：67−75，2021 年 1 月 Chinese Journal of Engineering, Vol. 43, No. 1: 67−75, January 2021 https://doi.org/10.13374/j.issn2095-9389.2020.06.17.002; http://cje.ustb.edu.cn