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Journal of the American Ceramic Society-Morscher et al Vol 87. No Sic BN 200mm 200mm Fig. 11. TEM micrographs(top)and carbon map(bottom, labeled"C )for SYL-iBN SiC/SiC composites showing(a)inside-debonding composite and(b) outside-debonding composite sufficient to cause interface debonding during cooldown after L.U.J.T. Ogbuji,“ ive Mode of Oxidation Degradation in a SiC-SiC The residual stress state in SiC fiber/MI caused by the infiltration of molten Si in processing. The volume expansion of the si IAG.N. Morscher and J. L. Eldridge, " Constituent Effects tress-Strain liquid to solid phase transformation coupled with a lower thermal expansion coefficient for Si compared with SiC results in residual on Fracture. Elsevier Science, Oxford, U. K in press ompression in the matrix of SiC fiber/MI matrix composites. For 1M. Steen and】.L.val this reason, outside debonding is expected to be easier to tailor ASTM Special Technical Publication, VoL. STP 1309. Edited by M. G al or MI composites compared with other Sic fiber. SiC matrix American Society for Testing and Materials, West Conshohocken, PA ons Composites Under Quasi-Static and Cyclic Loading, " Acta Metall. Mater. 41 141 1269-8l01993) References w. A. Curtin. B. K, Ahn, and N. Takeda, " Modeling Brittle and 46[0]3409-20(1998) G. N. Morscher, "" Modal Acoustic Emission Source Determination in JAm, Ceran,So,83|6l1441-4902000 Carbide Matrix Composites -N, S. Jacobson, G, N. Morscher. D. R. Bryant, and R. E. Tressler. Nondestructive evaluation, t Temperature Oxidation of Boron Nitride: Il, Boron Nitride Layers in Composites. Thompson and D. E. Chimet rican Institute of Physics. Melville, NY. 2000 JAm, Ceram.Soc,82|6l1473-82(99) Coatings for Ceramic Matrix B, K. Ahn and w. A Curtin, "Strain and Hysteresis by Stochastic Matrix Cracking Composites, "Ceram. Eng. Sci. Proc 13 [7-81 23-56(1992) 2G. N. Morscher and J. Hurst, "Stress-Rupture and Stress-R ature, "Ceram. Eng. Sci. Proc:, 22 [31 539-46(2001 2G. N Morscher and I. D. Cawley. "Intermediate Temperature Strength Degr OH,1995 Rebillat, Lamon, R, Naslain, E. Lara-Curzio m, K. Ferber, and T, M. Besmann and Y, L. Chen " Tensile Behavior of Itilayered Interphases in SiC/SiC Chemical-Vap erfaces, J. Am. Fibe ram. Eng, Sci. Prm,, in pi 2L. U J. T Ogbuji, D. R. Wheeler, and T.R. McCue,"Process-Induced Carbon Multilayered Interphases by VI, "Key Eng- Sub-Layer in SiC/BN dater,164-165,164-65 Eng.Sci.Proc2213]379-87(201 2W. A, Curtin, "Theory of Mechanical Properties of Ceramic-Matrix Compos yC-SiC) Interphases at High Tempe ites, "J. Am. Ceram. Soc., 74 [11] 2837-45(199 aler,164-165.249-52(1999) abdeljalil and w. A. Curtin, "Strength and Reliability of Fiber-Reinforced Bertrand, R. Pailler, and J. Lamon. " Influence of Strong Composites: Localized Load-sharing and Associated Size Effects. " int. J, Solids Interfaces on the Mechanical Behavior and Lifetime of Minicomposites, J. Am. Ceram Soc., 84(41787-94(200 26z. xia and W.A "HSREP lopment Program. Mater Scl. ro,22(3]371-78(2001 H. M. Yun and J. A. DiCarlo, "Comparison of the Tensile, Creep. Interphases for Woven Sic Strength Properties of Stoichiometric SiC Fibers, "Ceram. Eng. Sci. Proc., 20 [31 e7-Marure c dFI Sci oating Systems for High Strength in Ceram. Eng. Sci. Proc.,in C. Vincent, H nL, and J. Bouix, ""SiC/SiC aded Bn Interphases, " J. cumulation in a -38(2000 R. Bhatt, private communication112 Journal of the American Ceramic Society-Morscher et al. Vol. 87, No. I Fig. 11. TEM micrographs (top) and carbon map (bottom, labeled “C“) for SYL-iBN SiClSiC composites showing (a) inside-debonding composite and (b) outside-debonding composite. sufficient to cause interface debonding during cooldown after composite processing. The residual stress state in Sic fiber/MI composites is primarily caused by the infiltration of molten Si in the final step of matrix processing. The volume expansion of the Si liquid to solid phase transformation coupled with a lower thermal expansion coefficient for Si compared with Sic results in residual compression in the matrix of Sic fiber/MI matrix composites. For this reason, outside debonding is expected to be easier to tailor for MI composites compared with other Sic fiber, Sic matrix combinations. References ‘G. N. Morscher, J. Hurst, and D. Brewer, “Intermediate-Temperature Stress Rupture of a Woven Hi-Nicalon. BN-lnterphase. Sic-Matrix Composite in Air,” J. 9. Ceram. Soc.. 83 [6l 1441-49 (2000). -N. S. Jacobson. G. N. Morscher. D. R. Bryant, and R. E. Tressler. “High￾Temperature Oxidation of Boron Nitride: 11, Boron Nitride Layers in Composites.” J. Am. Ceram. Soc., 82 161 1473-82 (1999). ’H. W. Carpenter and J. W. Bohlen, “Fiber Coatings for Ceramic Matrix Composites.” Ceram. Eng. Sci. Proc., 13 [7-81 23-56 (1992). ‘R. Naslain. ‘The Concept of Layered Interphases in SiCISiC”: pp. 23-39 in Ceramic Transactions, Vol. 58. High-Temperalure Ceramic-Matrix Composites /I: Manufacturing and Materials Development. Edited by A. G. Evans and R. Naslain. American Ceramic Society, Westerville, OH, 1995. ’F. Rebillat. J. Lamon, R. Naslain, E. Lara-Curzio, M. K. Ferber. and T. M. Besmann, “Properties of Multilayered Interphases in SiUSiC Chemical-Vapor-Infiltrated Compos￾ites with ‘Weak’ and ‘Strong’ Interfaces.” J. Am Ceram. SOC., 81 191 2315-26 (1998). ‘S. Betrand. 0. Boisron. R. Pailler, J. Lamon. and R. Naslain, “(PyCISiC),, and (BN/SiC),, Nanoscale-Multilayered Interphases by Pressure-Pulsed CVI,” Key Eng. Mufer., 164-165. 164-65 (1999). ’S. Pasquier. J. Lamon, and R. Naslain, “Static Fatigue of 2D SiCISiC Composites with Multilayered (PyC-Sic),, Interphases at High Temperatures in Air.” Key Eng. Mafer., 164-165, 249-52 (1999). “S. Bertrand, R. Pailler, and J. 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