5.2 CHEMICAL EQUILIBRIUM S.J.T.U. Phase Transformation and Applications bB+cC=dD+eE Expression for a chemical reaction OWron=AG=dGD+eGE-bGB-cGc GB =GB+RTInag AG=d(Gi+RT Inap)+e(Gi RTInag)-b(GB+RT Inag)-c(Gc+RT Inac) △G=△G°+RTIn J G=0 △G°=dG)+eGE-bGB-cG& Equilibrium constant d。 e J b △G°=-RTInm）)=-RTIn K SJTU Thermodynamics of Materials Spring2006©X.J.Jin Lecture 10 electrochemistry IPhase Transformation and Applications S. J. T. U. SJTU Thermodynamics of Materials Spring 2006 © X. J. Jin Lecture 10 electrochemistry I 5.2 CHEMICAL EQUILIBRIUM + = + eEdDcCbB δ rev D E B −−+=Δ= GcGbGeGdGW C )ln()ln()ln()ln( D +=Δ RTGdG α D E ++ RTGe α E B +− RTGb α B C +− RTGc α C D D D D α +Δ=Δ ln JRTGG D D D D D D D E B C −−+=Δ cGbGeGdGG c C b B e E d D J αα αα α = B BB += RTGG lnα D α KRT α JRTG mequilibriu −=Δ ln ( ) −= ln D Equilibrium constant Expression for a chemical reaction ΔG 0 =