(13)CH3CHCH2C=CH(1 molHCI) 亲电加成双键较三键活泼 (14)CH2=CHCH2CH=CH2 (16)CH2=CHCH2C=CH2 OCH,CH,亲核加成三键较双键活泼 (1)CH3CH2CH2OSO3H,CH3CH2CH2Br,BrCH2CH2CH2Br,CH3CH2CH3 (18)CH3CHCH2CH3 CH2CH2CH2CH3(二级自由基稳定些) Br Br CH3 (19)CH3CH2CCH3 10-4 (4)>(2)>(1)>(3)(比较碳正离子形成难易) 10-5 (5)>(1)>(4)>(3)>(2 10-6 (1)A>B(2)A<B(3)A>C>B(4)A>B(⑤)A<B(稳定性大燃烧热小) 10-7 环丙烷 褪色 ()丙烷 Br2JCCY× KMnQ4 丙烯 褪色 褪色 × 褪色 ) Br2/CCl4 NH HO □ 褪色 褪色 CH≡C(CH2)2CH3 白 CH3(CH2)4CH3 Cu2Cl2 ()CH3(CH2)C=CH CH:(CH2)CH-=CH2 NHHO砖红 Br2/CCl4 褪色 3 CH3CHCH2C CH Cl ( (13 ) 1 molHCl)
 (14 ) CH2=CHCH2CH=CH2 (16 ) CH2=CHCH2C=CH2 OCH2CH3
 (17 ) CH3CH2CH2OSO3H , CH3CH2CH2Br , BrCH2CH2CH2Br , CH3CH2CH3 (18 ) CH3CHCH2CH3 Br CH2CH2CH2CH3 Br (

19 CH3 CH3CH2CCH3 Cl (20 ) CH3 Br 104   10-5     !  "#  "$#  "%# "#  "$# &'()*+,-  . (1 )


Br2 /CCl4  ×  KMnO4 ×  ✦ 2 ✧ CH C(CH2)2CH3 AgNO3 NH3H2O × × × ★ Br2/ ✩✫✪ × × ✩✫✪ ✩✬✪ CC KMnO4 l4 (3 ) CH3(CH2)4CH3 CH3 (CH2 )3C CH CH3 (CH2 )3CH=CH2 Cu2Cl2 NH3H2O × × ×
Br2 /  CCl4