有机化学(双语教学)课程教案 授课题目(教学章节或主题):第十四章.含氮有机|授课类型|理论课 化合物( Amine) 授课时间第7周第6974节 教学目标或要求:了解硝基化合物的分类,命名。了解胺的分类,命名,重氮和偶尔 氮化合物及分子重排。重点掌握胺的化学性质及重氮和偶氮化合物。 教学内容(包括基本内容、重点、难点) 含氮化合物 本章的重点是各种含氮化合物的重要反应及其在有机合成中的应用、芳环上的亲核取 代反应历程、Cope消去和 Hofmann消去反应的机理和立体化学、活泼中间体碳烯和类 碳烯的生成及其应用、烯胺的生成及其在有机合成中的应用等。 Nomenclature of Aliphatic Amines Simple amines are named as derivatives of the parent alkane, using the suffix-amine, or by using-amino to name a numbered substituent, using the following rules by replacing the-e ending with -amine, or by nam ing the nitrogen as an amino substrat a rent name elect the longest continuous carbon chain, containing the amino group, and derive the 2. Number the carbon chain, beginning at the end nearest to the amino group or, to give the lowest number at the first point of difference 3. Num ber the substituents and write the name, listing substituents alpha betically. Thus for the following example, you would number from the end closest to the nitrogen, generating the names, 3-methylpentanamine(or 1-amino-3-methy lpentane) and 5-methy 1-2-he 2-amino-5-methy1-2-hexane), respectively NH2 5 In this example, however, you number to give the lowest number at the first point of difference generating the name, 5-amino-2, 3-dimethy lhexane(not有机化学(双语教学) 课程教案 授课题目（教学章节或主题）：第十四章．含氮有机 化合物 (Amine) 授课类型 理论课 授课时间 第 7 周第 69-74 节 教学目标或要求：了解硝基化合物的分类，命名。了解胺的分类，命名，重氮和偶尔 氮化合物及分子重排。重点掌握胺的化学性质及重氮和偶氮化合物。 教学内容（包括基本内容、重点、难点）： 含氮化合物 本章的重点是各种含氮化合物的重要反应及其在有机合成中的应用、芳环上的亲核取 代反应历程、Cope 消去和 Hofmann 消去反应的机理和立体化学、活泼中间体碳烯和类 碳烯的生成及其应用、烯胺的生成及其在有机合成中的应用等。 Nomenclature of Aliphatic Amines Simple amines are named as derivatives of the parent alkane, using the suffix -amine, or by using -amino to name a numbered substituent, using the following rules: 1. Select the longest continuous carbon chain, containing the amino group, and derive the parent name by replacing the -e ending with -amine, or by naming the nitrogen as an amino substituent. 2. Number the carbon chain, beginning at the end nearest to the amino group, or, to give the lowest number at the first point of difference. 3. Number the substituents and write the name, listing substituents alphabetically. Thus for the following example, you would number from the end closest to the nitrogen, generating the names, 3-methylpentanamine (or 1-amino-3-methylpentane) and 5-methyl-2-hexanamine (or 2-amino-5-methyl-2-hexane), respectively. In this example, however, you number to give the lowest number at the first point of difference, generating the name, 5-amino-2,3-dimethylhexane (not