内张力 前张力 后张力 Anomeric effect 端基异构效应 Walden inversion 瓦尔登反转 外消旋化 Isoinversion 等反转 Isoracemization 等消旋 机理 Unimolecular nucleophilic 单分子亲核取代 Bimolecular nucleophilic sub-stitution双分子亲核取代 Bimolecular nucleophilic substi-tution(wih双分子亲核取代(含烯丙型 重排) 分子内亲核取代 Aromatic nucleophilic substitu-tion 芳香亲核取代 Unimolecular electrophilic sub-stitution 单分子亲电取代 Bimolecular electrophilic substi-tution 双分子亲电取代 Nucleophile-assisted unimolecu-ar亲核体协助单分子亲电取 electrophilic substitution 代 单分子消除 Bimolecular elimination 双分子消除 Unimolecular elimination through the conjugate单分子共轭碱消除 Bimolecular elimination through the conjugate双分子共轭碱消除 Bimolecular elimination with for-- mation of a双分子羰基形成消除 carbonyl group Unimolecular acid- catalyzed acyl-oxygen单分子酸催化酰氧断裂 Bimolecular base-catalyzed acyl- oxygen双分子碱催化酰氧断裂 Unimolecular acid-catalyzed alkyl- oxygen单分子酸催化烷氧断裂 Bimolecular base-catalyzed al-. kyl-oxygen双分子碱催化烷氧断裂 I-allyl complex mechanism π烯丙型络合机理 Borderline mechanism 边理机理 Heterolysis 异裂 Heterolytic michanism 异裂机理 CounrerIgegen ion 反荷离子 Ion pair 离子对6 I strain 内张力 F strain 前张力 B strain 后张力 Anomeric effect 端基异构效应 Walden inversion 瓦尔登反转 Racemization 外消旋化 Isoinversion 等反转 Isoracemization 等消旋 Homochiral 纯手性[的] Mechanism 机理 Unimolecular nucleophilic 单分子亲核取代 Bimolecular nucleophilic sub-stitution 双分子亲核取代 Bimolecular nucleophilic substi-tution(with allylic rearrange-ment) 双分子亲核取代（含烯丙型 重排） Internal nucleophilic substiru-tion 分子内亲核取代 Aromatic nucleophilic substitu-tion 芳香亲核取代 Unimolecular electrophilic sub-stitution 单分子亲电取代 Bimolecular electrophilic substi-tution 双分子亲电取代 Nucleophile-assisted unimolecu-lar electrophilic substitution 亲核体协助单分子亲电取 代 Unimolecular elimination 单分子消除 Bimolecular elimination 双分子消除 Unimolecular elimination through the conjugate base 单分子共轭碱消除 Bimolecular elimination through the conjugate base 双分子共轭碱消除 Bimolecular elimination with for-mation of a carbonyl group 双分子羰基形成消除 Unimolecular acid-catalyzed acyl-oxygen cleavage 单分子酸催化酰氧断裂 Bimolecular base-catalyzed acyl-oxygen cleavage 双分子碱催化酰氧断裂 Unimolecular acid-catalyzed alkyl-oxygen cleavage 单分子酸催化烷氧断裂 Bimllecular base-catalyzed al- kyl-oxygen cleavage 双分子碱催化烷氧断裂 π-allyl complex mechanism π烯丙型络合机理 Borderline mechanism 边理机理 Homolysis 均裂 Heterolysis 异裂 Heterolytic michanism 异裂机理 Counrer[gegen]ion 反荷离子 Ion pair 离子对