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.1574 工程科学学报,第41卷,第12期 (3)平衡析出相计算结果表明在连铸过程中 1995:723 会形成M-Al-O夹杂物,这使其成为连铸坯中主 [12]Ye G Z,Jonsson P,Lund T.Thermodynamics and kinetics of the 要的夹杂物类型.当钢中铝质量分数超过3×105 modification of Al,O,inclusions./S//Int,1996,36(Suppl):S105 时,连铸过程中会形成氧化铝类夹杂物 [13]Itoh H,Hino M,Ban-Ya S.Thermodynamics on the formation of spinel nonmetallic inclusion in liquid steel.Metall Mater Trans B. 参考文献 1997,28(5):953 [14]Park J H,Lee S B,Kim D S.Inclusion control of ferritic stainless [1]Todoroki H,Inada S.Recent innovation and prospect in production steel by aluminum deoxidation and calcium treatment.Metall technology of specialty steels with high cleanliness.Bull Iron Steel Mater Trans B.2005,36(1):67 m1Jpn,2003,8(8:575 [15]Li J Y,Cheng GG,Ruan Q,et al.Evolution mechanism of oxide [2]Park J H,Todoroki H.Control of MgO-Al2O;spinel inclusions in inclusions in titanium-stabilized AISI 443 stainless steel.Metall stainless steels.ISI/Int,2010,50(10):1333 Ma1 er Trans E,2018,49(5):2357 [3] Li J Y,Cheng GG,Qian G Y,et al.Line defect on surface of hot [16]Li J Y,Cheng GG,Ruan Q,et al.Evolution mechanism of (cold)-rolled 304 stainless steel sheet.China Merall,2017,27(1): inclusions in Al-killed,Ti-bearing 11Cr stainless steel with Ca 29 treatment./S//Int,2018,58(6):1042 (李璟宇,成国光,钱国余,等.304不锈钢热(冷)轧板表面线缺陷 [17]Wang X Y,Qiu S T,Zou Z S,et al.Study on steel deoxidation 中国治金,2017,271):29) [4] with Al-Ca compound alloy.Chin J Eng,2017,39(5):702 Chen S H,Jiang M,He X F,et al.Top slag refining for inclusion (王晓英,仇圣桃,邹宗树,等.A-Ca复合合金钢水脱氧机理的 composition transform control in tire cord steel.IntJ Miner Metall 研究.工程科学学报,2017,39(5):702) Ma1er,2012,19(6):490 [5] [18]Goto H,Miyazawa K I,Yamada W,et al.Effect of cooling rate on Cheng L M,Zhang L F,Shen P.Interfacial phenomena in ironmaking and steelmaking.Chin J Eng,2018,40(10):1139 composition of oxides precipitated during solidification of steels. (程礼梅,张立峰,沈平钢铁冶金过程中的界面现象.工程科学 SJmL,1995,35(6):708 学报,2018,40(10):1139) [19]Nurmi S,Louhenkilpi S,Holappa L.Thermodynamic evaluation of [6] Thapliyal V,Kumar A,Robertson D,et al.Inclusion modification inclusions formation and behaviour in steels during casting and in Si-Mn killed steels using titanium addition./S//Int,2015, solidification.Steel Res Int,2009,80(6):436 55(1):190 [20]Choi J Y,Kim S K,Kang Y B,et al.Compositional evolution of [7]Park J H.Kang Y B.Effect of ferrosilicon addition on the oxide inclusions in austenitic stainless steel during continuous composition of inclusions in 16Cr-14Ni-Si stainless steel melts casting.Steel Res Int,2015,86(3):284 Metall Mater Trans B,2006,37(5):791 [21]Okuyama G,Yamaguchi K,Takeuchi S,et al.Effect of slag [Mizuno K.Todoroki H,Noda M.et al.Effects of Al and Ca in composition on the kinetics of formation of Al2O3-MgO ferrosilicon alloys for deoxidation on inclusion composition in inclusions in aluminum killed ferritic stainless steel./SI//nt,2000, type 304 stainless steel.Iron Steelmaker,2001,28(8):93 40(2):121 [9]Itoh H,Hino M.Ban-Ya S.Thermodynamics on the formation of [22]Park J H,Kim D S.Effect of CaO-AlO;-Mgo slags on the non-metallic inclusion of spinel (MgO.Al2O3)in liquid steel. formation of Mgo-Al,O;inclusions in ferritic stainless steel. Tes-o-Hagane,1998,84(2:85 Metall Mater Trans B,2005,36(4):495 [10]Zhang L F,Thomas B G.State of the art in evaluation and control [23]Park J H.Thermodynamic investigation on the formation of of steel cleanliness.ISI/Int,2003,43(3):271 inclusions containing MgAl2O spinel during 16Cr-14Ni austenitic [11]Rackers K G,Thomas B G.Clogging in continuous casting stainless steel manufacturing processes.Mater Sci Eng,2008, nozzles /78th Steelmaking Conference Proceedings.Nashville, 472(1-2):43(3)平衡析出相计算结果表明在连铸过程中 会形成 Mn−Al−O 夹杂物,这使其成为连铸坯中主 要的夹杂物类型. 当钢中铝质量分数超过 3×10−5 时,连铸过程中会形成氧化铝类夹杂物. 参    考    文    献 Todoroki H, Inada S. Recent innovation and prospect in production technology of specialty steels with high cleanliness. Bull Iron Steel Inst Jpn, 2003, 8(8): 575 [1] Park J H, Todoroki H. Control of MgO·Al2O3 spinel inclusions in stainless steels. ISIJ Int, 2010, 50(10): 1333 [2] Li J Y, Cheng G G, Qian G Y, et al. Line defect on surface of hot (cold)-rolled 304 stainless steel sheet. China Metall, 2017, 27(1): 29 (李璟宇, 成国光, 钱国余, 等. 304不锈钢热(冷)轧板表面线缺陷. 中国冶金, 2017, 27(1):29 ) [3] Chen S H, Jiang M, He X F, et al. Top slag refining for inclusion composition transform control in tire cord steel. Int J Miner Metall Mater, 2012, 19(6): 490 [4] Cheng  L  M,  Zhang  L  F,  Shen  P.  Interfacial  phenomena  in ironmaking and steelmaking. Chin J Eng, 2018, 40(10): 1139 (程礼梅, 张立峰, 沈平. 钢铁冶金过程中的界面现象. 工程科学 学报, 2018, 40(10):1139 ) [5] Thapliyal V, Kumar A, Robertson D, et al. Inclusion modification in  Si –Mn  killed  steels  using  titanium  addition. ISIJ Int,  2015, 55(1): 190 [6] Park  J  H,  Kang  Y  B.  Effect  of  ferrosilicon  addition  on  the composition  of  inclusions  in  16Cr ‒14Ni ‒Si  stainless  steel  melts. Metall Mater Trans B, 2006, 37(5): 791 [7] Mizuno  K,  Todoroki  H,  Noda  M,  et  al.  Effects  of  Al  and  Ca  in ferrosilicon  alloys  for  deoxidation  on  inclusion  composition  in type 304 stainless steel. Iron Steelmaker, 2001, 28(8): 93 [8] Itoh H, Hino M, Ban-Ya S. Thermodynamics on the formation of non-metallic  inclusion  of  spinel  (MgO·Al2O3 )  in  liquid  steel. Tetsu-to-Hagané, 1998, 84(2): 85 [9] Zhang L F, Thomas B G. State of the art in evaluation and control of steel cleanliness. ISIJ Int, 2003, 43(3): 271 [10] Rackers  K  G,  Thomas  B  G.  Clogging  in  continuous  casting nozzles  //  78th Steelmaking Conference Proceedings.  Nashville, [11] 1995: 723 Ye G Z, Jönsson P, Lund T. Thermodynamics and kinetics of the modification of Al2O3 inclusions. ISIJ Int, 1996, 36(Suppl): S105 [12] Itoh H, Hino M, Ban-Ya S. Thermodynamics on the formation of spinel nonmetallic inclusion in liquid steel. Metall Mater Trans B, 1997, 28(5): 953 [13] Park J H, Lee S B, Kim D S. Inclusion control of ferritic stainless steel  by  aluminum  deoxidation  and  calcium  treatment. Metall Mater Trans B, 2005, 36(1): 67 [14] Li J Y, Cheng G G, Ruan Q, et al. Evolution mechanism of oxide inclusions  in  titanium-stabilized  AISI  443  stainless  steel. Metall Mater Trans B, 2018, 49(5): 2357 [15] Li  J  Y,  Cheng  G  G,  Ruan  Q,  et  al.  Evolution  mechanism  of inclusions  in  Al-killed,  Ti-bearing  11Cr  stainless  steel  with  Ca treatment. ISIJ Int, 2018, 58(6): 1042 [16] Wang  X  Y,  Qiu  S  T,  Zou  Z  S,  et  al.  Study  on  steel  deoxidation with Al−Ca compound alloy. Chin J Eng, 2017, 39(5): 702 (王晓英, 仇圣桃, 邹宗树, 等. Al−Ca复合合金钢水脱氧机理的 研究. 工程科学学报, 2017, 39(5):702 ) [17] Goto H, Miyazawa K I, Yamada W, et al. Effect of cooling rate on composition  of  oxides  precipitated  during  solidification  of  steels. ISIJ Int, 1995, 35(6): 708 [18] Nurmi S, Louhenkilpi S, Holappa L. Thermodynamic evaluation of inclusions  formation  and  behaviour  in  steels  during  casting  and solidification. Steel Res Int, 2009, 80(6): 436 [19] Choi J Y, Kim S K, Kang Y B, et al. Compositional evolution of oxide  inclusions  in  austenitic  stainless  steel  during  continuous casting. Steel Res Int, 2015, 86(3): 284 [20] Okuyama  G,  Yamaguchi  K,  Takeuchi  S,  et  al.  Effect  of  slag composition  on  the  kinetics  of  formation  of  Al2O3−MgO inclusions in aluminum killed ferritic stainless steel. ISIJ Int, 2000, 40(2): 121 [21] Park  J  H,  Kim  D  S.  Effect  of  CaO−Al2O3−MgO  slags  on  the formation  of  MgO−Al2O3 inclusions  in  ferritic  stainless  steel. Metall Mater Trans B, 2005, 36(4): 495 [22] Park  J  H.  Thermodynamic  investigation  on  the  formation  of inclusions containing MgAl2O4 spinel during 16Cr-14Ni austenitic stainless  steel  manufacturing  processes. Mater Sci Eng A,  2008, 472(1-2): 43 [23] · 1574 · 工程科学学报,第 41 卷,第 12 期
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