张浩等：改性多孔钢渣/橡胶复合材料的制备及其性能 .95· 并且在其表面进行键合作用，改善钢渣的表面结构. Mater,2012,207-208:21 (3)适量的促进剂/硫磺质量比可以最大限度 [7]Saria L,Shimaoka T,Miyawaki K.Leaching of heavy metals in 地消除硫磺形成的内硫环，减少无效交联键中的硫 acid mine drainage.Waste Manage Res,2006,24(2):134 [8]Navarro M C,Perez-Sirvent C,Martinez-Sanchez M J,et al. 原子数：适量的硬脂酸/氧化锌质量比，可以改善钢 Abandoned mine sites as a source of contamination by heavy met- 渣的表面结构，有效减少无效交联键的硫原子数，促 als:a case study in a semi-arid zone.J Geochem Explor,2008,96 使橡胶交联键稳定 (2-3):183 (4)改性多孔钢渣/橡胶复合材料中改性多孔 [9]Zhuang P,McBride M B,Xia H P,et al.Health risk from heavy 钢渣与橡胶之间以物理方式进行复合，适量的改性 metals via consumption of food crops in the vicinity of Dabaoshan mine,South China.Sci Total Environ,2009,407(5):1551 多孔钢渣/炭黑质量比促使改性多孔钢渣与橡胶形 [10]Yang JT,Fan H,Bu Z Y,et al.Montmorillonite reinforced 成良好的包裹结构 SBR and effect on the vulcanization of rubber.Acta Mater Com- pos Sin,2005,22(2):38 参考文献 (杨晋涛，范宏，卜志扬，等。蒙脱土填充补强丁苯橡胶及 对橡胶硫化特性的影响.复合材料学报，2005,22(2)：38) [1]Sun P.Guo ZC.Sintering preparation of porous sound-absorbing [11]Raza M A,Westwood A,Brown A,et al.Characterisation of materials from steel slag.Trans Nonferrous Met Soc China,2015, graphite nanoplatelets and the physical properties of graphite nan 25(7):2230 oplatelet/silicone composite for thermal interface applications. [2]Zhang Y J.Kang L,Liu L C.et al.Synthesis of a novel alkali-ac- Carbon,2011,49(13):4269 tivated magnesium slag-based nanostructural composite and its pho- [12]Chen L,Lu L,Wu D J,et al.Slicone rubber/graphite nanoshe- tocatalytic performance.Appl Surf Sci,2015,331:399 et electrically conducting nanocomposite with a low percolation [3]Xiang L,Xiang Y.Wang Z G,et al.Influence of chemical addi- threshold.Polym Compos,2007,28(4):493 tives on the formation of super-fine calcium carbonate.Porder [13]Li C X,Liu J,Ren R C.Study on fly ash modification and rein- Technol,.2002,126(2):129 force-reagent mechanism of rubber.Non-Metallic Mines,2012, [4]Morel F,Bounor-Legare V,Espuche E,et al.Surface modifica- 35(5):48 tion of calcium carbonate nanofillers by fluoro-and alkyl-alkoxysi- (李彩霞，刘健，任瑞晨.粉煤灰改性及作橡胶补强填料机 lane:consequences on the morphology,thermal stability and gas 理研究.非金属矿，2012,35(5)：48) barrier properties of polyvinylidene fluoride nanocomposites.Eur [14]Yang Z,Zhang X.Application of a preliminary study on fly ash PamJ,2012,48(5):919 in natural rubber.Technol Market,2011,18(7):27 [5]Binici H,Temiz H,Kose MM.The effect of fineness on the prop- (杨昭，张馨.粉煤灰在天然橡胶中的应用初探.技术与市 erties of the blended cements incorporating ground granulated blast 场，2011,18(7)：27) furnace slag and ground basaltic pumice.Constr Build Mater, [15]Tang Z F,Zhou X L,Lin HT,et al.Study on mechanical prop- 2007,21(5):1122 erties of cenosphere/caoutchouc composite materials.Non-Metal- [6]Makela M,Watkins G,Poykio R,et al.Utilization of steel,pulp lic Mines,.2008,31(2):6 and paper industry solid residues in forest soil amendment:relevant (唐忠锋，周小柳，林海涛，等.漂珠/天然橡胶复合材料的 physicochemical properties and heavy metal availability.Hazard 力学性能研究.非金属矿，2008,31(2)：6)张 浩等: 改性多孔钢渣/ 橡胶复合材料的制备及其性能 并且在其表面进行键合作用,改善钢渣的表面结构. (3)适量的促进剂/ 硫磺质量比可以最大限度 地消除硫磺形成的内硫环,减少无效交联键中的硫 原子数;适量的硬脂酸/ 氧化锌质量比,可以改善钢 渣的表面结构,有效减少无效交联键的硫原子数,促 使橡胶交联键稳定. (4)改性多孔钢渣/ 橡胶复合材料中改性多孔 钢渣与橡胶之间以物理方式进行复合,适量的改性 多孔钢渣/ 炭黑质量比促使改性多孔钢渣与橡胶形 成良好的包裹结构. 参 考 文 献 [1] Sun P, Guo Z C. Sintering preparation of porous sound鄄absorbing materials from steel slag. Trans Nonferrous Met Soc China, 2015, 25(7): 2230 [2] Zhang Y J, Kang L, Liu L C. et al. Synthesis of a novel alkali鄄ac鄄 tivated magnesium slag鄄based nanostructural composite and its pho鄄 tocatalytic performance. Appl Surf Sci, 2015, 331: 399 [3] Xiang L, Xiang Y, Wang Z G, et al. Influence of chemical addi鄄 tives on the formation of super鄄fine calcium carbonate. Powder Technol, 2002, 126(2): 129 [4] Morel F, Bounor鄄Legar佴 V, Espuche E, et al. Surface modifica鄄 tion of calcium carbonate nanofillers by fluoro鄄 and alkyl鄄alkoxysi鄄 lane: consequences on the morphology, thermal stability and gas barrier properties of polyvinylidene fluoride nanocomposites. Eur Polym J, 2012, 48(5): 919 [5] Binici H, Temiz H, Kose M M. The effect of fineness on the prop鄄 erties of the blended cements incorporating ground granulated blast furnace slag and ground basaltic pumice. Constr Build Mater, 2007, 21(5): 1122 [6] Makela M, Watkins G, Poykio R, et al. Utilization of steel, pulp and paper industry solid residues in forest soil amendment:relevant physicochemical properties and heavy metal availability. J Hazard Mater, 2012, 207鄄208: 21 [7] Saria L, Shimaoka T, Miyawaki K. Leaching of heavy metals in acid mine drainage. Waste Manage Res, 2006, 24(2): 134 [8] Navarro M C, P佴rez鄄Sirvent C, Mart侏nez鄄S佗nchez M J, et al. Abandoned mine sites as a source of contamination by heavy met鄄 als: a case study in a semi鄄arid zone. J Geochem Explor, 2008, 96 (2鄄3): 183 [9] Zhuang P, McBride M B, Xia H P, et al. Health risk from heavy metals via consumption of food crops in the vicinity of Dabaoshan mine, South China. Sci Total Environ, 2009, 407(5): 1551 [10] Yang J T, Fan H, Bu Z Y, et al. Montmorillonite reinforced SBR and effect on the vulcanization of rubber. Acta Mater Com鄄 pos Sin, 2005, 22(2): 38 (杨晋涛, 范宏, 卜志扬, 等. 蒙脱土填充补强丁苯橡胶及 对橡胶硫化特性的影响. 复合材料学报, 2005, 22(2): 38) [11] Raza M A, Westwood A, Brown A, et al. Characterisation of graphite nanoplatelets and the physical properties of graphite nan鄄 oplatelet / silicone composite for thermal interface applications. Carbon, 2011, 49(13): 4269 [12] Chen L, Lu L, Wu D J, et al. Slicone rubber/ graphite nanoshe鄄 et electrically conducting nanocomposite with a low percolation threshold. Polym Compos, 2007, 28(4): 493 [13] Li C X, Liu J, Ren R C. Study on fly ash modification and rein鄄 force鄄reagent mechanism of rubber. Non鄄Metallic Mines, 2012, 35(5): 48 (李彩霞, 刘健, 任瑞晨. 粉煤灰改性及作橡胶补强填料机 理研究. 非金属矿, 2012, 35(5): 48) [14] Yang Z, Zhang X. Application of a preliminary study on fly ash in natural rubber. Technol Market, 2011, 18(7): 27 (杨昭, 张馨. 粉煤灰在天然橡胶中的应用初探. 技术与市 场, 2011, 18(7): 27) [15] Tang Z F, Zhou X L, Lin H T, et al. Study on mechanical prop鄄 erties of cenosphere / caoutchouc composite materials. Non鄄Metal鄄 lic Mines, 2008, 31(2): 6 (唐忠锋, 周小柳, 林海涛, 等. 漂珠/ 天然橡胶复合材料的 力学性能研究. 非金属矿, 2008, 31(2): 6) ·95·