G H. Min et al. /Ceramics International 29(2003)323-326 interlocking of delamination is attributed to the hetero- [2]D Kovar, B.H. King, J W. Holloran, Fibrous monolithic cera- geneous Sic interlayer [12]. During the middle and later mics, J. Am. Ceram Soc. 80(1997)2471 stages of the bending test, the interaction occurs among [3] R W. Trice J.W. Halloran, Influence of microstructure and tem- various propagating cracks, and the bridging is a domi erature on the interfacial fracture energy of silicon nitride/boron nant mechanism as in Fig. 4B. Finally, the sliding of nitride fibrous monolithic ceramics, J. Am. Ceram Soc. 82(1999) adjacent cells or/and cellular layers lasts a longer dis- [4] R.W. Trice, J.W. Halloran, Effect of sintering aid composition on placement at lower load-carrying. Thus, the fracture the processing of Si3N4/BN fibrous monolithic ceramics, J.Am behavior of the prismatic ceramics lies between multi Ceram.Soc.82(1999)2943 layered ceramics and fiber reinforced ceramic composites [ S.Y. Lienard, J.w.Halloran, Texture development of s nitride/boron nitride fibrous monolithic ceramics, J. Mater [6K. Ueno, Fabricating method for a prismatic ceramic compo- 4. Conclusion ites. JP Patent No 9-318910 [ K. Ueno, Prismatic structures ceramic, J. Soc. Mater. Sci. Japan By means of structure-controlled processing, pri [8 matic ceramic composites of the Al2O3/SiC system have mechanical properties of Si3 N4-based prismatic materials, in been prepared with a distinct prismatic texture of alu Proc. 16th Japan-Korea International Seminar on Ceramics mina-based cells, which are separated in three dimen 1999,pp.285-28 sions by thin Sic cell boundaries. 9J. She, T. Inoue, Mechanical properties and fracture behavior of The fracture toughness of the composites was AlO /SiC fibrous ceramics, J. Eur. Ceram Soc. 20(2000)1887 improved significantly. However, the bending strength [10 T. Inoue, K. Ueno, Mechanical properties and fracture beha- vior of SiTico fibre SiAlON composites, Ceram. Int. 24(1998) was decreased due to the reduced effective cross-section by weaker boundaries. When the thickness of Sic [l] s. Cai, Y. Huang, Infiuence of interface characteristic on the interphase is 9.3-15.6 um, a fracture work of 1221.4- echanical properties of multiplayer Si]N4 ceramics, Acta Com 81.6 J/m- was obtained with good combination of positie Sinica 16(1999)11( [2] J. She, T. Inoue, Fabrication and characterization of multiplayer bending strength and toughness umina-based composites with improved fracture behavi Generally, the composites fractured in a non-brittle Mater.Let.42(2000)155. manner. a crack deflecting and delimitating are con [3S. Baskaran, J. Holloran, Fibrous monolithic cer sidered as two main contributions for the improved mechanical properties and oxidation behavior of the silicon fracture energy, and frictional sliding of adjacent carbide/boron nitride system, J. Am. Ceram. Soc. 77(1994) rous ce lls becomes more dominant after cracking [14) J. She, T. Inoue, Fracture behavior and mechanical properties of occurs, especially at lower load condition. fracture char- acteristics of the prismatic ceramics lies between those of thickness, Mater. Sci. Lett. 19(2000)4 the multilayered ceramics and fiber reinforced ceramic [5] J. She, T. Inoue, Multilayered Al2O3/ SiC ceramics with composites due to three-dimensional controlled structure improved mechanical behavior, J. Eur. Ceram. Soc. 20(2000) [16 J. She, T. Inoue, Mechanical properties and fracture behavior of References AlO3 laminates with different architectures, Mater. Lett. 46 [S. Baskaran, S.D. Dunn, J.W. Holloran, Fibrous monolithic [17 G.H. Min, R. LiNon-catastrophic fracture of alumina-based ceramics: fabrication microstructure and indentation behavior. J. prismatic ceramic composites, Chinese J. Mater. Res. 15(16) Am. Ceran.Soc.76(1993)2209 2001)693-698interlocking of delamination is attributed to the heterogeneous SiC interlayer [12]. During the middle and later stages of the bending test, the interaction occurs among various propagating cracks, and the bridging is a dominant mechanism as in Fig. 4B. Finally, the sliding of adjacent cells or/and cellular layers lasts a longer displacement at lower load-carrying. Thus, the fracture behavior of the prismatic ceramics lies between multilayered ceramics and fiber reinforced ceramic composites. 4. Conclusion By means of structure-controlled processing, prismatic ceramic composites of the Al2O3/SiC system have been prepared with a distinct prismatic texture of alumina-based cells, which are separated in three dimensions by thin SiC cell boundaries. The fracture toughness of the composites was improved significantly. However, the bending strength was decreased due to the reduced effective cross-section by weaker boundaries. When the thickness of SiC interphase is 9.3–15.6 mm, a fracture work of 1221.4– 1481.6 J/m2 was obtained with good combination of bending strength and toughness. Generally, the composites fractured in a non-brittle manner, and crack deflecting and delimitating are considered as two main contributions for the improved fracture energy, and frictional sliding of adjacent fibrous cells becomes more dominant after cracking occurs, especially at lower load condition. Fracture characteristics of the prismatic ceramics lies between those of the multilayered ceramics and fiber reinforced ceramic composites due to three-dimensional controlled structure. References [1] S. Baskaran, S.D. Dunn, J.W. Holloran, Fibrous monolithic ceramics: fabrication, microstructure and indentation behavior, J. Am. Ceram. Soc. 76 (1993) 2209. [2] D. Kovar, B.H. King, J.W. Holloran, Fibrous monolithic ceramics, J. Am. Ceram. Soc. 80 (1997) 2471. [3] R.W. Trice, J.W. Halloran, Influence of microstructure and temperature on the interfacial fracture energy of silicon nitride/boron nitride fibrous monolithic ceramics, J. Am. Ceram. Soc. 82 (1999) 2502. [4] R.W. Trice, J.W. Halloran, Effect of sintering aid composition on the processing of Si3N4/BN fibrous monolithic ceramics, J. Am. Ceram. Soc. 82 (1999) 2943. [5] S.Y. Lienard, J.W. Halloran, Texture development of silicon nitride/boron nitride fibrous monolithic ceramics, J. Mater. Sci. 35 (2000) 3365. [6] K. Ueno, Fabricating method for a prismatic ceramic composites, JP Patent No 9–318910. [7] K. Ueno, Prismatic structures ceramic, J. Soc. Mater. Sci. Japan 47 (6) (1998) 644. [8] T. Inoue, M.Suzuki, S. Sodeoka, K. Ueno, Fabrication and mechanical properties of Si3N4-based prismatic materials, in: Proc. 16th Japan–Korea International Seminar on Ceramics, 1999, pp. 285–288. [9] J. She, T. Inoue, Mechanical properties and fracture behavior of Al2O3/SiC fibrous ceramics, J. Eur. Ceram. Soc. 20 (2000) 1887. [10] T. Inoue, K. Ueno, Mechanical properties and fracture behavior of SiTiCO fibre/SiAlON composites, Ceram. Int. 24 (1998) 565. [11] S. Cai, Y. Huang, Influence of interface characteristic on the mechanical properties of multiplayer Si3N4 ceramics, Acta Compositie Sinica 16 (1999) 110. [12] J. She, T. Inoue, Fabrication and characterization of multiplayer alumina-based composites with improved fracture behavior, Mater. Lett. 42 (2000) 155. [13] S. Baskaran, J. Holloran, Fibrous monolithic ceramics: mechanical properties and oxidation behavior of the silicon carbide/boron nitride system, J. Am. Ceram. Soc. 77 (1994) 1249. [14] J. She, T. Inoue, Fracture behavior and mechanical properties of multiplayered alumina-based composites with different layer thickness, Mater. Sci. Lett. 19 (2000) 45. [15] J. She, T. Inoue, Multilayered Al2O3/SiC ceramics with improved mechanical behavior, J. Eur. Ceram. Soc. 20 (2000) 1771. [16] J. She, T. Inoue, Mechanical properties and fracture behavior of Al2O3 laminates with different architectures, Mater. Lett. 46 (2000) 65. [17] G.H. Min, R. LiNon-catastrophic fracture of alumina-based prismatic ceramic composites, Chinese J. Mater. Res. 15 (16) (2001) 693–698. 326 G.H. Min et al. / Ceramics International 29 (2003) 323–326