Chap 3 Property Relations S.J.T.U. Phase Transformation and Applications The First Objective:to explore the variation of the energy functions(U and H) with temperature and pressure. The heat capacities(Cp and Cv)give the change of U and H with temperature, at constant volume and constant pressure,respectively. The Second Objective:to examine the dependence of properties,such as the internal energy,enthalpy,entropy,and other thermodynamic functions,on temperature,pressure,specific volume,and other intensive variables 器 V P SJTU Physical Chemistry of Materials Spring 2005 ©X.J.Jin Lecture 5 property relationPhase Transformation and Applications S. J. T. U. SJTU Physical Chemistry of Materials Spring 2005 © X. J. Jin Lecture 5 property relation Chap 3 Property Relations The First Objective: to explore the variation of the energy functions (U and H) with temperature and pressure. The heat capacities (Cp and Cv) give the change of U and H with temperature, at constant volume and constant pressure, respectively. The Second Objective: to examine the dependence of properties, such as the internal energy, enthalpy, entropy, and other thermodynamic functions, on temperature, pressure, specific volume, and other intensive variables. 2 1 B A V T T V U ⎟⎟⎠⎞ ⎜⎜⎝⎛ ∂∂ T V U ⎟⎠⎞ ⎜⎝⎛ ∂∂ 2 1 B A P T P T H ⎟⎠⎞ ⎜⎝⎛ ∂∂ T P H ⎟⎠⎞ ⎜⎝⎛ ∂∂