Contents 25LP1D51200 201200 ides 120 25-5 paponi holipids 1208 f Fats and Oils:Soaps and Detergents 1205 25-6 Sterpids 1210 25-7 Prostaglandios 1213 25-8 Terpenes 1214 Chapter 25 Glossary 1217 Study Problems 1219 26 SYNTHETIC POLYMERS 1222 1223 hers 1229 26-4 Ziegler-Natt Catalysts 1230 26-5 Natural and Synthetic Rubbers 1230 26-6 Copolymers of Two or More Monomers 1232 26-7 Condensation Polymers 1232 26-8 Polymer Structure and Properies 1236 APPENDICES 1243 1A Spin-Spin Coupling Constants 1246 C Chemical Shifts in Organie Compounds 1247 Characteristic Infrared Group Frequencie 124 3 UV:The Woodward-Fieser Rules for Predicting UV-Visible Spectra 1253 Methods and Suggestions for Proposing Mechanisms 1257 Suggesticns for Developing Multistep Syntheses 1260 5 pK Values for Representative Compounds 126 Answers to Selected Problems A1 Photo Credits PC1 Index 11 xviii Contents 25 LIPIDS 1200 25-1 Introduction 1200 25-2 VVaxes 1200 25-3 Triglycerides 1201 25-4 Saponification of Fats and Oils; Soaps and Detergents 1205 25-5 Phospholipids 1208 25-6 Steroids 1210 25-7 Prostaglandins 1213 25-8 Terpenes 1214 Chapter 25 Glossary 1217 Study Problems 1219 26 SYNTHETIC POLYMERS 1222 26-1 Introduction 1222 26-2 Addition Polymers 1223 26-3 Stereochemistry of Polymers 1229 26-4 Stereochemical Control of Polymerization; Ziegler-Natta Catalysts 1230 26-5 Natural and Synthetic Rubbers 1230 26-6 Copolymers of Two or More Monomers 1232 26-7 Condensation Polymers 1232 26-8 Polymer Structure and Properties 1236 Chapter 26 Glossary 1238 Study Problems 1239 APPENDICES 1243 1A NMR Absorption Positions of Protons in Various Structural Environments 1244 1B Spin-Spin Coupling Constants 1246 1C 13C Chemical Shifts in Organic Compounds 1247 2A Characteristic Infrared Group Frequencies 1248 2B IR: Characteristic Infrared Absorptions of Functional Groups 1251 3 UV: The VVoodward-Fieser Rules for Predicting UV-Visible Spectra 1253 4A Methods and Suggestions for Proposing Mechanisms 1257 4B Suggestions for Developing Multistep Syntheses 1260 5 pKa Values for Representative Compounds 1261 Answers to Selected Problems A 1 Photo Credits PC1 Index 11