第3期 董虎林等：热处理对电沉积NF合金箔微观结构和磁性能的影响 ·361。 最大可及10m. Prs5,2004:203 (2)经过热处理后，合金箔存在有不同程度的 (宋维锡.金属学.北京：治金工业出版社，2004：203) [6 Nakamura K,Umetani M,HayashiT.Electrodeposition of imo 择优取向，1150℃保温5h热处理后，(111)晶面完 rich Ni-Fe alloys from sulphate and chloride baths.Surf Technol. 全择优取向，且经过热处理后坡莫合金箔得到纯化. 1985.25:111 (3)1150℃热处理后，合金箔的直流磁性能达 [7 Egberts P.Brodersen P,Hibbard G D.Mesoscale structure in 到最好，Bs0m达到1.51T,H。降至109Am1, electrodeposited nanocrystalline Ni-Fe alloys.Mater Sci Eng A. as和“m分别升至3.9mH·m-1和47.0mH· 2006.441:336 [8 EHSharif M R,Chisholm C U,Watson A.Microstructure of m1,这归因于晶粒增大、合金箔纯化和合金(111) electrodeposited chromium and chromium alloys.Eurocorrosion, 方向择优取向. 1991(1):234 [9 Banovic S W.Barmak K,Marder A R.Microstructural charac 参考文献 terization and hardess of electrodeposited nickel coatings from a [1]Leith S D.RamliS,Schwartz D T.Characterization of Ni,Fe- sulphamate bath.J Mater Sci,1998.33:639 (00K<0 95)electrodeposition from a family of sulfamate- [10 Gu M.Yang F Z.Huarg L.et al.The formation of copper chloride electroly tes.J E lectrodem Soc,1999,146(6):1431 electrodeposits w ith highly preferred orientation and their su rface [2]Guo Z C.Liu Y X.Liu M F,et al.Magnetic properties and mi- momphology.Acta Phys Chim Sin.2002.18(11):973 cmstructure of electrodeposited Fe and Ni alby foil.Chin/Non- (辜敏，杨防祖，黄令，等.高择优取向铜镀层的电化学形成及 ferrous M,2004,14H2):273 其表面形貌.物理化学学报，2002.18(11)：973) (郭占成，刘星宇，刘美风，等.电沉积F、Ni基合金箔的组织 [11]Huang L.Xu S K,Tang JC.et al.Effect of Ndt ion on pre- 形貌及磁性能.中国有色金属学报.2004.14(2)：273) ferred orientation of elect mdeposited nickel and its properties.J [3]Lu W C.Xu Y L.Zhao Y,et al.The Way of Making Pure Fe Xiamen Univ Nat Sci,1996,35(6):907 Foil by E kctrodeposition.Chinese Patent,ZL91102934 1994- (黄令，许书楷，汤皎宁，等钕离子对镍电沉积层择优取向及 04-22 其性能的影响.厦门大学学报：自然科学版.1996,36：907 (卢维昌，徐运兰，赵蕴，等.电解成型制备纯铁箔的方法.中 [12]Bugaychuk S M,Nadutov V M,Karpets M V,et al.Effect of 国专利.ZL91102934.199404一22) dectron irradation on texturing in electmdeposited nanocrys 4 Zhou SM.Principles and Research Methods of Electrodeposition taline alby Fe-78%Ni.Scripta Mater,2007,57:1028 Metals.Shanghai:Shanghai Science and Technology Press, [13 Feng D.Metal Physics,Vol.4:Electric Pmoperties and Mag- 1987:243 netic Properties of Superonductive Materia ls.Beijing Science (周绍民.金属电沉积原理与研究方法.上海：上海科学技术 Pe55,1998:580 出版社，1987：243) (冯端。金属物理学，第四卷：超导电性和磁性.北京：科学出 [5]Son W X.Metallography.Beijing:Metallungical Industry 版社，1998：580)最大可及 10 μm . (2) 经过热处理后, 合金箔存在有不同程度的 择优取向, 1 150 ℃保温 5 h 热处理后, ( 111) 晶面完 全择优取向, 且经过热处理后坡莫合金箔得到纯化 . ( 3) 1 150 ℃热处理后, 合金箔的直流磁性能达 到最好, B800 达到 1.51 T, Hc 降至 10.9 A ·m -1 , μ0.08和 μm 分别升至 3.9 mH·m -1和 47.0 mH· m -1 , 这归因于晶粒增大、合金箔纯化和合金( 111) 方向择优取向. 参 考 文 献 [ 1] Leith S D, Ramli S, Schwartz D T .Charact erization of Ni xFe1 -x ( 0.01<x <0.95) electrodeposition from a family of sulf amate￾chloride electroly tes.J E lectrochem Soc, 1999, 146( 6) :1431 [ 2] Guo Z C, Liu Y X, Liu M F, et al.Magnetic properties and mi￾crostructure of electrodeposited Fe and Ni alloy f oil.Chin J Non￾f errous Met, 2004, 14( 2) :273 ( 郭占成, 刘星宇, 刘美凤, 等.电沉积 Fe 、Ni 基合金箔的组织 形貌及磁性能.中国有色金属学报, 2004, 14( 2) :273) [ 3] Lu W C, Xu Y L, Zhao Y, et al.The Way of Making Pure Fe Foil by E lectrodeposition .Chinese Pat ent, ZL91102934.1994- 04-22 ( 卢维昌, 徐运兰, 赵蕴, 等.电解成型制备纯铁箔的方法.中 国专利, ZL91102934.1994-04-22) [ 4] Zhou S M .Principles and Research Methods of Electrodeposition Meta ls.Shanghai:S hanghai S cience and Technology Press, 1987:243 ( 周绍民.金属电沉积原理与研究方法.上海:上海科学技术 出版社, 1987:243) [ 5] Song W X.Metallography .Beijing :Metallurgical Industry Press, 2004:203 ( 宋维锡.金属学.北京:冶金工业出版社, 2004:203) [ 6] Nakamura K, Umetani M, Hayashi T .Electrodeposition of iron￾rich Ni-Fe alloys from sulphate and chloride baths.S urf Technol, 1985, 25:111 [ 7] Egberts P, Brodersen P, Hibbard G D.Mesoscale structure in electrodeposit ed nanocryst alline Ni-Fe alloys.Mater S ci Eng A , 2006, 441:336 [ 8] El-S harif M R, Chisholm C U, Watson A .Mi crostructu re of electrodeposit ed chromium and chromium alloys.Eurocorrosion , 1991( 1) :234 [ 9] Banovic S W, Barmak K, Marder A R.Microstructural charac￾terization and hardness of electrodeposit ed nickel coatings from a sulphamat e bath.J Mater Sci, 1998, 33:639 [ 10] Gu M, Yang F Z, Huang L, et al.The formation of copper electrodeposits w ith highly preferred orientation and their su rf ace morphology .Acta Phys Chim S in, 2002, 18( 11) :973 ( 辜敏, 杨防祖, 黄令,等.高择优取向铜镀层的电化学形成及 其表面形貌.物理化学学报, 2002, 18( 11) :973) [ 11] Huang L, Xu S K, Tang J C, et al.Effect of Nd +i on on pre￾ferred orientation of electrodeposited nickel and its properties.J X iamen Uni v Nat Sci, 1996, 35( 6) :907 ( 黄令, 许书楷, 汤皎宁, 等.钕离子对镍电沉积层择优取向及 其性能的影响.厦门大学学报:自然科学版, 1996, 35( 6) :907) [ 12] Bugaychuk S M, Nadutov V M , Karpets M V, et al.Eff ect of electron irradiation on t exturing in electrodeposited nanocrys￾talline alloy Fe-78%Ni.Scripta Mat er, 2007, 57:1028 [ 13] Feng D .Meta l Physics, Vol .4 :Electric Properties and Mag￾netic Properties of Su percond ucti ve Mat eria ls.Beijing:S cience Press, 1998:580 ( 冯端.金属物理学, 第四卷:超导电性和磁性.北京:科学出 版社, 1998:580) 第 3 期 董虎林等:热处理对电沉积 Ni-Fe合金箔微观结构和磁性能的影响 · 361 ·