2.2气体 例1.一学生在实验室中,在73.3kPa和25C下收集得250mL某气体。在分析天 平上称量,得气体净质量为0.118克。求这种气体的物质的量和摩尔质量。 解:设此气体为理想气体 p=7.33×104Pa V=250mL×10-6m3.mL-1=2.50×10-4m3 PV=nRT n=p业 RT 7.33×104Pa×2.50×10-4m3 n= =7.39×10-3mol 8.314J.mol-1.k-×(273.15+25)K M。="ma-0.118g/7.39×10-3mol=16.0g/mol n 冈例1. 一学生在实验室中,在73.3kPa和25oC下收集得250 mL某气体。在分析天 平上称量,得气体净质量为0.118 克。求这种气体的物质的量和摩尔质量。 0118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (27315 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 Pa B 3 B 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . = = = = + = = = = = = − − − − − − − − 解:设此气体为理想气体 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (27315 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 B 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (27315 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 B 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 0 118g 7 39 10 mol 16 0g/mol 7 39 10 mol 8 314J mol k (273 15 25)K 7 33 10 Pa 2 50 10 m 250mL 10 m mL 2 50 10 m 7 33 10 3 3 1 1 4 4 3 6 3 1 4 3 4 . / . . n m M . . . . . n RT pV pV nRT n V . p . Pa B B = = = = + = = = = = = − − − − − − − − 2.2 气体