康金星等：Acidithiobacillus ferrooxidans对软锰矿浸出的影响 ·599· (12):2192 ores and semi-industrial scale practice.Acta Microbiol Sinica, (付勇，徐志刚，裴浩翔，等中国锰矿成矿规律初探。地质 1990,30(3):228 学报，2014,88(12)：2192) (钟慧芳，蔡文六，李雅芹细菌浸锰及其半工业性试验.微 [3]He F,Chen H F,Chen G,et al.A new technology of low grade 生物学报，1990,30(3)：228) pyrolusite ore in reduction process.China's Manganese Ind,2017. [13]Guo Y,Zhang D Q,Cao L H,et al.Pyrolusite leaching with dif- 35(6):94 ferent stage of leachate from bio-leaching of different grade pyri- (和飞，陈沪飞，陈菜，等.低品位软锰矿还原新技术和研究 tes.Min Metall Eng,2016.36(5):76 进展.中国锰业，2017,35(6)：94) (郭盈，张德强，曹丽华，等.不同品质黄铁矿生物浸出液 [4]Li Z G,Chen W L,Zhang JJ,et al.Reductive leaching technol- 制剂浸出软锰矿研究.矿冶工程，2016,36(5)：76) ogy of pyrolusite optimized by response surface methodology.Chem [14]Liu X R,Jiang S C,Liu Y J,et al.Biodesulfurization of vanadi- Eng China,2018,46(2):72 um-bearing titanomagnetite concentrates and pH control of bi- (李照刚，陈为亮，张建军，等.响应曲面法优化软锰矿还原 oleaching solution.Int J Miner Metall Mater,2013,20 (10): 浸出的工艺.化学工程，2018,46(2)：72) 925 [5]Hu K J.Study on Breeding of Alkalophilic Bacteria for Bioleaching [15]Fu K B,Lin H,Mo X L,et al.Study on bioleaching of different of Complex Oxidized Copper Ore and Leaching Mechanism Disser- types of chalcopyrite.JUnir Sci Technol Beijing.2011.33(7): tation].Beijing:University of Science and Technology Beijing. 806 2017 (傅开彬，林海，莫晓兰，等.不同类型黄铜矿的生物浸出研 (胡凯建.复杂氧化铜矿碱性浸矿菌种的选育及浸出规律研 究.北京科技大学学报，2011,33(7)：806) 究[学位论文].北京：北京科技大学，2017) [16]Qu B,Deng L,Deng B,et al.Oxidation kinetics of dithionate [6]Huang M Q.Rules of Air Flow and Enhanced Leaching Mechanism compound in the leaching process of manganese dioxide with man by Forced Aeration in Heap Bioleaching of Copper Sulfides [Disser- ganese dithionate.React Kinet Mech Catal,2018,123(2):743 tation].Beijing:University of Science and Technology Beijing, [17]Nazari B,Jorjani E,Hani H,et al.Formation of jarosite and its 2015 effect on important ions for Acidithiobacillus ferrooxidans bacteria. (黄明清.硫化铜矿生物堆浸气体渗流规律及通风强化浸出 Trans Nonferrous Met Soc China,2014,24(4):1152 机制[学位论文].北京：北京科技大学，2015) [18]Chabre Y,Pannetier J.Structural and electrochemical properties [7]Qi F J,Feng Y L,Li H R,et al.Leaching characteristics and re- of the proton/y-Mn0,system.Prog Solid State Chem,1995,23 covery method of nickel from low-grade nickel pyrrhotite.I Unin (1):1 Sci Technol Beijing,2011,33(9):1065 [19]Senanayake G.Acid leaching of metals from deep-sea manganese (齐凤杰，冯雅丽，李浩然，等.低品位镍磁黄铁矿镍浸出特 nodules-a critical review of fundamentals and applications. 性及回收方法.北京科技大学学报，2011,33(9)：1065) Miner Eng,2011,24(13):1379 [8]Peng Z J,Yu R L,Qiu GZ,et al.Really active form of fluorine [20]Walanda D K,Lawrance G A,Donne S W.Hydrothermal toxicity affecting Acidithiobacillus ferrooxidans activity in bioleach- MnO:synthesis,structure,morphology and discharge perform- ing uranium.Trans Nonf errous Met Soc China,2013,23(3): ance.JPower Sour,2005,139(1-2):325 812 [21]Li C T,Cheng X Q,Dong C F,et al.Influence of Cl-on the [9]Choi N C,Cho K H,Kim B J,et al.Enhancement of Au-Ag-Te corrosion electrochemical behavior of Alloy 690.J Unie Sci Tech- contents in tellurium-bearing ore minerals ria bioleaching.Int J nol Beijing,2011,33(4):444 Miner Metall Mater,2018,25(3):262 (李成涛，程学群，董超芳，等.C~对690合金腐蚀电化学 [10]Nanez-Ramirez D M,Solis-Soto A,L6pez-Miranda J,et al.Zinc 行为的影响.北京科技大学学报，2011,33(4)：444) bioleaching from an iron concentrate using Acidithiobacillus ferro- [22]Luo J,Wang Y,Jiang J B,et al.Electrochemistry behavior of oxidans strain from Hercules Mine of Coahuila,Mexico.Int J rebars with different grain size and Mott-Schottky research of pas- Miner Metall Mater,2011,18(5):523 sive films.Acta Chim Sinica,2012,70(10):1213 [11]Cheng FF,Guan J F,Zhang F,et al.A research status of man- (罗检，王毅，蒋继波，等.不同品粒度螺纹钢的电化学行为 ganese ore chemical processing.China's Manganese Ind,2015, 及其钝化膜的Mot-Schottky研究.化学学报，2012,70(10)： 33(4):4 1213) (程飞飞，管俊芳，张帆，等.锰矿化学选矿的研究现状.中 [23]Zhang IQ.Electrochemical Measurement Technology.Beijing: 国锰业，2015,33(4)：4) Chemical Industry Press,2010 [12]Zhong H F,Cai W L,Li Y Q.Bacterial leaching of manganese (张鉴清.电化学测试技术.北京：化学工业出版社，2010)康金星等: Acidithiobacillus ferrooxidans 对软锰矿浸出的影响 (12): 2192 (付勇, 徐志刚, 裴浩翔, 等. 中国锰矿成矿规律初探. 地质 学报, 2014, 88(12): 2192) [3] He F, Chen H F, Chen G, et al. A new technology of low grade pyrolusite ore in reduction process. China蒺s Manganese Ind, 2017, 35(6): 94 (和飞, 陈沪飞, 陈菓, 等. 低品位软锰矿还原新技术和研究 进展. 中国锰业, 2017, 35(6): 94) [4] Li Z G, Chen W L, Zhang J J, et al. Reductive leaching technol鄄 ogy of pyrolusite optimized by response surface methodology. Chem Eng China, 2018, 46(2): 72 (李照刚, 陈为亮, 张建军, 等. 响应曲面法优化软锰矿还原 浸出的工艺. 化学工程, 2018, 46(2): 72) [5] Hu K J. Study on Breeding of Alkalophilic Bacteria for Bioleaching of Complex Oxidized Copper Ore and Leaching Mechanism [Disser鄄 tation]. Beijing: University of Science and Technology Beijing, 2017 (胡凯建. 复杂氧化铜矿碱性浸矿菌种的选育及浸出规律研 究[学位论文]. 北京: 北京科技大学, 2017) [6] Huang M Q. Rules of Air Flow and Enhanced Leaching Mechanism by Forced Aeration in Heap Bioleaching of Copper Sulfides [Disser鄄 tation]. Beijing: University of Science and Technology Beijing, 2015 (黄明清. 硫化铜矿生物堆浸气体渗流规律及通风强化浸出 机制[学位论文]. 北京: 北京科技大学, 2015) [7] Qi F J, Feng Y L, Li H R, et al. Leaching characteristics and re鄄 covery method of nickel from low鄄grade nickel pyrrhotite. J Univ Sci Technol Beijing, 2011, 33(9): 1065 (齐凤杰, 冯雅丽, 李浩然, 等. 低品位镍磁黄铁矿镍浸出特 性及回收方法. 北京科技大学学报, 2011, 33(9): 1065) [8] Peng Z J, Yu R L, Qiu G Z, et al. Really active form of fluorine toxicity affecting Acidithiobacillus ferrooxidans activity in bioleach鄄 ing uranium. Trans Nonf errous Met Soc China, 2013, 23 (3 ): 812 [9] Choi N C, Cho K H, Kim B J, et al. Enhancement of Au鄄鄄Ag鄄鄄Te contents in tellurium鄄bearing ore minerals via bioleaching. Int J Miner Metall Mater, 2018, 25(3): 262 [10] N俨觡ez鄄Ram侏rez D M, Sol侏s鄄Soto A, L佼pez鄄Miranda J, et al. Zinc bioleaching from an iron concentrate using Acidithiobacillus ferro鄄 oxidans strain from Hercules Mine of Coahuila, Mexico. Int J Miner Metall Mater, 2011, 18(5): 523 [11] Cheng F F, Guan J F, Zhang F, et al. A research status of man鄄 ganese ore chemical processing. China蒺s Manganese Ind, 2015, 33(4): 4 (程飞飞, 管俊芳, 张帆, 等. 锰矿化学选矿的研究现状. 中 国锰业, 2015, 33(4): 4) [12] Zhong H F, Cai W L, Li Y Q. Bacterial leaching of manganese ores and semi鄄industrial scale practice. Acta Microbiol Sinica, 1990, 30(3): 228 (钟慧芳, 蔡文六, 李雅芹. 细菌浸锰及其半工业性试验. 微 生物学报, 1990, 30(3): 228) [13] Guo Y, Zhang D Q, Cao L H, et al. Pyrolusite leaching with dif鄄 ferent stage of leachate from bio鄄leaching of different grade pyri鄄 tes. Min Metall Eng, 2016, 36(5): 76 (郭盈, 张德强, 曹丽华, 等. 不同品质黄铁矿鄄生物浸出液 制剂浸出软锰矿研究. 矿冶工程, 2016, 36(5): 76) [14] Liu X R, Jiang S C, Liu Y J, et al. Biodesulfurization of vanadi鄄 um鄄bearing titanomagnetite concentrates and pH control of bi鄄 oleaching solution. Int J Miner Metall Mater, 2013, 20 (10 ): 925 [15] Fu K B, Lin H, Mo X L, et al. Study on bioleaching of different types of chalcopyrite. J Univ Sci Technol Beijing, 2011, 33(7): 806 (傅开彬, 林海, 莫晓兰, 等. 不同类型黄铜矿的生物浸出研 究. 北京科技大学学报, 2011, 33(7): 806) [16] Qu B, Deng L, Deng B, et al. Oxidation kinetics of dithionate compound in the leaching process of manganese dioxide with man鄄 ganese dithionate. React Kinet Mech Catal, 2018, 123(2): 743 [17] Nazari B, Jorjani E, Hani H, et al. Formation of jarosite and its effect on important ions for Acidithiobacillus ferrooxidans bacteria. Trans Nonferrous Met Soc China, 2014, 24(4): 1152 [18] Chabre Y, Pannetier J. Structural and electrochemical properties of the proton / 酌鄄MnO2 system. Prog Solid State Chem, 1995, 23 (1): 1 [19] Senanayake G. Acid leaching of metals from deep鄄sea manganese nodules———a critical review of fundamentals and applications. Miner Eng, 2011, 24(13): 1379 [20] Walanda D K, Lawrance G A, Donne S W. Hydrothermal MnO2 : synthesis, structure, morphology and discharge perform鄄 ance. J Power Sour, 2005, 139(1鄄2): 325 [21] Li C T, Cheng X Q, Dong C F, et al. Influence of Cl - on the corrosion electrochemical behavior of Alloy 690. J Univ Sci Tech鄄 nol Beijing, 2011, 33(4): 444 (李成涛, 程学群, 董超芳, 等. Cl - 对 690 合金腐蚀电化学 行为的影响. 北京科技大学学报, 2011, 33(4): 444) [22] Luo J, Wang Y, Jiang J B, et al. Electrochemistry behavior of rebars with different grain size and Mott鄄Schottky research of pas鄄 sive films. Acta Chim Sinica, 2012, 70(10): 1213 (罗检, 王毅, 蒋继波, 等. 不同晶粒度螺纹钢的电化学行为 及其钝化膜的 Mott鄄Schottky 研究. 化学学报, 2012, 70(10): 1213) [23] Zhang J Q. Electrochemical Measurement Technology. Beijing: Chemical Industry Press, 2010 (张鉴清. 电化学测试技术. 北京: 化学工业出版社, 2010) ·599·