Atomic Orbital Theory 1.1 Photon (Quantum) 、 1.2 Bohr or Planck-Einstein Equation Planck's Constant h 4 Heisenberg Uncertainty Principle Wave(Quantum)Mechanics 16 Standing (or Stationary)Waves Nodal Points(Planes) Wavelength入 11 en 66 (or s 115 p 7 1.15 Orbital (Atomic Orbital) 116 Wave Function 1.17 Wave Equation in One Dimension 1.18 Wave Equation in Three Dimensions 9 1.19 Laplacian Operator 9 1.20 Probability Interpretation of the wave Function 9 12 Schrodinger Equation 22 Eigenfunction dinger Equation for the Hydrogen Atom 12 entum)Quantum NumberI 135 Number m 1 111222 120 antum Number m 120 131 1s Orhital 1212 1.32 2s Orbital 133 n Orhitals 134 Nodal Plane or Surface 1.35 2p Orbitals 1.36 d Orbitals 1.37 fOrbitals 1.38 Atomic Orbitals for Many-Electron Atoms and Co Second Edirion.by Milton Orchin Roger S.Mac r.A and R.Marshall Wilson iley&Sons,Inc1 Atomic Orbital Theory 1.1 Photon (Quantum) 3 1.2 Bohr or Planck–Einstein Equation 3 1.3 Planck’s Constant h 3 1.4 Heisenberg Uncertainty Principle 3 1.5 Wave (Quantum) Mechanics 4 1.6 Standing (or Stationary) Waves 4 1.7 Nodal Points (Planes) 5 1.8 Wavelength λ 5 1.9 Frequency ν 5 1.10 Fundamental Wave (or First Harmonic) 6 1.11 First Overtone (or Second Harmonic) 6 1.12 Momentum (P) 6 1.13 Duality of Electron Behavior 7 1.14 de Broglie Relationship 7 1.15 Orbital (Atomic Orbital) 7 1.16 Wave Function 8 1.17 Wave Equation in One Dimension 9 1.18 Wave Equation in Three Dimensions 9 1.19 Laplacian Operator 9 1.20 Probability Interpretation of the Wave Function 9 1.21 Schrödinger Equation 10 1.22 Eigenfunction 10 1.23 Eigenvalues 11 1.24 The Schrödinger Equation for the Hydrogen Atom 11 1.25 Principal Quantum Number n 11 1.26 Azimuthal (Angular Momentum) Quantum Number l 11 1.27 Magnetic Quantum Number ml 12 1.28 Degenerate Orbitals 12 1.29 Electron Spin Quantum Number ms 12 1.30 s Orbitals 12 1.31 1s Orbital 12 1.32 2s Orbital 13 1.33 p Orbitals 14 1.34 Nodal Plane or Surface 14 1.35 2p Orbitals 15 1.36 d Orbitals 16 1.37 f Orbitals 16 1.38 Atomic Orbitals for Many-Electron Atoms 17 The Vocabulary and Concepts of Organic Chemistry, Second Edition, by Milton Orchin, Roger S. Macomber, Allan Pinhas, and R. Marshall Wilson Copyright © 2005 John Wiley & Sons, Inc. 1 c01.qxd 5/17/2005 5:12 PM Page 1