。462 北京科技大学学报 第31卷 吸氢规律遵循Sievert's定律，与致密体相一致. 128 (2)多孔钛合金吸氢量随置氢时间的延长而增 (黄刚，曹小华，龙兴贵，等.钛氢体系的物理化学性质.材料 导报.2006.20(10)：128) 加，即符合CH= -C十C+4GL的关系. [8 Huang P Y.Powder Metallurgy Principle.Beijing Metallurgical 2C1 Industry Press,2004:133 (3)多孔钛合金吸氢量随相对密度的减小而增 (黄培云.粉末治金原理.北京：治金工业出版社，2004：133) 9Shi L.Thermodynam ics of Metals and Alloy.Beijing:China 加，即符合C= +B 十C的关系 Machine Press.1992:164 (石霖.合金热力学.北京：机械工业出版社，1992：164) 参考文献 [10 Wan J P.Peng S M.Hao W L.ct al Investigation on absorption [1]Hou H L,Li ZQ,Wang Y J.et al.Technology of hydmogen treat- of hydrogen by titarium-vanadium alloy.J Nucl Radiochem ment for titanium alby and its application prospect.Chin/Non- 2004.26(3):141 ferrous Met,2003.13(3):533 (万竞平，彭述明，郝万立，等.T一V合金吸氢性能研究。核 (侯红亮，李志强，王亚军，等。钛合金热氢处理技术及其应用 化学与放射化学，2004,26(3)：141) 前景.中国有色金属学报.2003,13(3)：533) [11]Vasut F.Bidica N.Stefarescu.ct al.Study about sorption in [2]SenkovON,Frones F H.Thermobydrogen processing of tit anium sponge and pow der tit anium of hydrogen isotopes obtained fom a albys.IntJ Hydrogen Energy,1999.24 (6):565 cryogenic distillation process.Renewable Energy,2008.33(2): [3]Eliaz N.Eliezer D.Olson D L.Hydrogen assisted processing of 216 materials.Mater Sci Eng A,2000,289:41 12]Cao X M,Zhao Y Q,Xi Z P.et al.Application of thermohy- [4]Zhao J Q,Nan H,Huang D.Progress in technologies for prepa drogen treatment for casting titanium alloys Foundry,2005,54 ration of Ti alby and Ti alloy parts w ith Ti alloy pow der by hydm- (5):391 gen albying,Spec Cast Non ferraus Albys,2007,27(8):593 (曹兴民，赵永庆，奚正平.热氢处理在铸造钛合金中的应用. (赵嘉琪，南海，黄东。氢合金化钛合金粉末成形制件技术的发 铸造，2005.54(5)：391) 展.特种铸造及有色合金，2007,27(8)：593) 13 Warg TT.Wang S M.Huang Z et al.Hydrogen storage prop [5]Azevedo C R F.Rodrigues D.Beneduce N F.TiAbV pow der erties of catalzed sodium alanates.Chin J Nonferrous Met, metallgy (PM)via hydrogenationrdehyd mogenat ion HDH)pm- 2006.16(8):1429 cess.J Alloys Com pd,2003.353:217 (王同涛，王树茂，黄卓等.钛催化氢化铝钠的贮氢性能.中 [6]Cui C J.Peng Q.Study on hydrogen permeation process in titani- 国有色金属学报，2006.16(8)：1429 um and Tialbys.Rare Met Mater Eng.2003,32(12):1011 14 Zheng X P,Ao H.Li P.et al.Research trend in electrochemical (崔昌军，彭乔.钛及钛合金的氢渗过程研究.稀有金属材料 properties of rare-earth-based hydmgen storage alloys.Ord- 与工程，2003,32(12)：1011) nance Mater Sci Eng.2006,26(5):76 [7]Huang G.Cao X H.Long X G.et al Physical and chemical pmp- (郑雪萍，敖晖，李平，等.稀土系储氢合金电化学性能的研究 erties of titanium-hydrogen system.Mater Rev,2006,20(10): 现状.兵器材料科学与工程，2006.26(5)：76吸氢规律遵循 Sievert' s 定律, 与致密体相一致 . ( 2) 多孔钛合金吸氢量随置氢时间的延长而增 加, 即符合 C H = -C2 + C 2 2 +4C1 t 2C1 的关系. ( 3) 多孔钛合金吸氢量随相对密度的减小而增 加, 即符合 C H =A 1 d -1 2 3 +B 1 d +C 的关系. 参 考 文 献 [ 1] Hou H L, Li Z Q, Wang Y J, et al.Technology of hydrogen treat￾ment for titanium alloy and its application prospect .Chin J Non￾f errous Met, 2003, 13( 3) :533 ( 侯红亮, 李志强, 王亚军, 等.钛合金热氢处理技术及其应用 前景.中国有色金属学报, 2003, 13( 3) :533) [ 2] Senkov O N, Frones F H .T hermohydrogen processing of tit anium alloys.In t J Hydrogen Energy , 1999, 24 ( 6) :565 [ 3] Eliaz N, Eliezer D, Olson D L .Hydrogen assist ed processing of materials.Mater Sci Eng A, 2000, 289:41 [ 4] Zhao J Q, Nan H, Huang D.Progress in t echnologies for prepa￾ration of Ti alloy and Ti alloy parts w ith Ti alloy pow der by hydro￾gen alloying.Spec Cast Non ferrous Alloys, 2007, 27(8) :593 ( 赵嘉琪, 南海, 黄东.氢合金化钛合金粉末成形制件技术的发 展.特种铸造及有色合金, 2007, 27( 8) :593) [ 5] Azevedo C R F, Rodrigues D, Beneduce N F.Ti-Al-V pow der metallu rgy ( PM) via hydrogenation-dehyd rogenation ( HDH) pro￾cess.J Alloys Com pd , 2003, 353:217 [ 6] Cui C J, Peng Q .Study on hydrogen permeation process in tit ani￾um and Ti alloys.Rare Met Mater E ng, 2003, 32( 12) :1011 ( 崔昌军, 彭乔.钛及钛合金的氢渗过程研究.稀有金属材料 与工程, 2003, 32( 12) :1011) [ 7] Huang G, Cao X H, Long X G, et al.Physi cal and chemical prop￾erties of tit anium-hydrogen system .Mater Rev, 2006, 20 ( 10) : 128 ( 黄刚, 曹小华, 龙兴贵, 等.钛-氢体系的物理化学性质.材料 导报, 2006, 20( 10) :128) [ 8] Huang P Y .Powder Meta llurgy Principle .Beijing:Metallurgical Industry Press, 2004:133 ( 黄培云.粉末冶金原理.北京:冶金工业出版社, 2004:133) [ 9] Shi L.Thermodynam ics of Metals and Alloy .Beijing :China Machine Press, 1992:164 ( 石霖.合金热力学.北京:机械工业出版社, 1992:164) [ 10] Wan J P, Peng S M, Hao W L, et al.Investigation on absorption of hydrogen by titanium-vanadium alloy .J Nucl Radiochem , 2004, 26( 3) :141 ( 万竟平, 彭述明, 郝万立, 等.Ti-V 合金吸氢性能研究.核 化学与放射化学, 2004, 26( 3) :141) [ 11] Vasut F, Bidica N, S tefanescu, et al.Study about sorption in sponge and pow der tit anium of hydrogen isot opes obtained from a cryogenic distillation process.Renewable Energy , 2008, 33( 2 ) : 216 [ 12] Cao X M, Zhao Y Q, Xi Z P, et al.Application of thermohy￾drogen treatment for casting tit anium alloys.Foundry , 2005, 54 ( 5) :391 ( 曹兴民, 赵永庆, 奚正平.热氢处理在铸造钛合金中的应用. 铸造, 2005, 54( 5) :391) [ 13] Wang T T, Wang S M, Huang Z, et al.Hydrogen storage prop￾erties of catalyzed sodium alanates.Chin J Non f errous Met , 2006, 16( 8) :1429 ( 王同涛, 王树茂, 黄卓, 等.钛催化氢化铝钠的贮氢性能.中 国有色金属学报, 2006, 16( 8) :1429) [ 14] Zheng X P,Ao H, Li P, et al.Research trend in electrochemical properties of rare-earth-based hydrogen storage alloys.Or d￾nance Mater Sci E ng, 2006, 26( 5) :76 ( 郑雪萍, 敖晖, 李平,等.稀土系储氢合金电化学性能的研究 现状.兵器材料科学与工程, 2006, 26( 5) :76) · 462 · 北 京 科 技 大 学 学 报 第 31 卷