(1)NaSO4(2)NaSO;然后加NaCN(3)C6 HmGr,然后加H2O(4)OH,H2O (5)OH,H2O然后加热(6)HOCH2CH2OHH(7Ag(NH3)2OH(8LiAH4,然后加热 (9)</NH-NH (10)HCHO,稀 解:构造式为 OH (1)CH3 CH, CH-SO3 Na(2)CH3CH, CH/OH (3)CH3 CH2-CH-C6H5 CN OH o-CH (4)CHaCH2CH-CH-SO,Na (5)CH3CH2CH=C-CHO(6)CH CH2CHO OH C H (7)CH3CH2COONH+ Ag,(8)CH,3 CH2CH2OH(9)CH, CH2 CH=NNHC6Hs (10)cH3CH—CHo H2OH 和 CH3-C—cHo CH? H2 OI 9.5写出下列反应中生成的主要产物。 (1)苯乙酮+浓HNO3 (2)苯乙酮+Cl2(过量) (A)+(B) 无水乙醚 (3)苯乙酮+NaBH (4)苯乙酮+ CH3MgBr (B) coo 答:(1(A) O H CH H 3 (4)(A) C-OMg Br C-OH CH CH 96完成下列各反应式(1)NaHSO4 (2)NaHSO3;然后加 NaCN (3)C6H5MgBr,然后加 H2O (4)OH－,H2O (5)OH－ ,H2O;然后加热 (6)HOCH2CH2OH,H+ (7)Ag(NH3)2OH (8)LiAlH4,然后加热 NH-NH2 (9) （10）HCHO, 稀 NaOH 解:构造式为 CH3CH2CH-SO3Na OH CH3CH2CH CN OH CH3CH2-CH-C6H5 OH CH3CH2CH-CH-SO3Na OH CH3 CH3 CH3CH2CH O O CH3 CH3 CH3CH2COONH4 Ag CH3CH2CH2OH CH3CH2CH=NNHC6H5 CH3 CH CHO CH2OH CH3 C CH2OH CHO CH2OH (1) (2) (3) (4) (5)CH3CH2CH=C-CHO (6) (7) + (8) (9) (10) 和 9.5 写出下列反应中生成的主要产物。 (1)苯乙酮+浓 HNO3 H2 SO4 (A) (2)苯乙酮+Cl2(过量) OH (A)+ (B) （3）苯乙酮+NaBH4 H2O (A) (4)苯乙酮+CH3MgBr H2O (B) 无水乙醚 (A) OMgBr NO2 COCH3 COO CHCl3 CH CH3 OH C CH3 CH3 C OH CH3 CH3 答：(1)(A) (2)(A) (B) ; (3)(A) (4)(A) ; (B) 9.6 完成下列各反应式