郭志成等：氧化石墨烯掺杂量与pH值对石墨烯气凝胶储能性能的影响 247· aerogels with superelasticity and tunable Poisson's ratio.Adv characteristics of resorcinol -formaldehyde carbon aerogel. Mater,2016,28(41):9223 Carbon,2004,42(8-9):1625 [16]Gonzalez M,Baselga J,Pozuelo J.Modulating the electromagnetic [26]Feng Y N,Wang J,Ge L,et al.Pore size controllable preparation shielding mechanisms by thermal treatment of high porosity for low density porous nano-carbon.J Nanosci Nanotechnol,2013, graphene aerogels.Carbon,2019,147:27 13(10):7012 [17]Xue Q.Ding Y,Xue Y Y,et al.3D nitrogen-doped graphene [27]Rey-Raap N,Menendez J A,Arenillas A.Simultaneous adjustment aerogels as efficient electrocatalyst for the oxygen reduction of the main chemical variables to fine-tune the porosity of carbon reaction.Carbon,2018,139:137 xerogels.Carbon,2014,78:490 [18]Chu H,Zhang FF,Pei L Y,et al.Ni,Co and Mn doped SnS2- [28]Elkhatat A M,Al-Muhtaseb S A.Advances in tailoring resorcinol- graphene aerogels for supercapacitors.JAlloys Compd,2018,767: formaldehyde organic and carbon gels.Ady Mater,2011,23(26): 583 2887 [19]Ates M,Caliskan S,Ozten E.Preparation of rGO/Ag/PEDOT [29]Gallegos-Suarez E,Perez-Cadenas A F,Maldonado-Hodar F J,et nanocomposites for supercapacitors.Mater Technol,2018. al.On the micro-and mesoporosity of carbon aerogels and 33(14:872 xerogels.The role of the drying conditions during the synthesis [20]Yang Y,Xi Y L,Li J Z,et al.Flexible supercapacitors based on processes.Chem Eng J,2012,181-182:851 polyaniline arrays coated graphene aerogel electrodes.Nanoscale [30]Al-Muhtaseb S A,Ritter J A.Preparation and properties of Res Lett,2017,12:394 resorcinol-formaldehyde organic and carbon gels.Ady Mater, [21]Liu L,Tian G Y,Ma R,et al.Preparation and electrosorption 2003,15(2:101 performance of graphene Xerogel.ECS Solid State Lett,2015, [31]Matos I,Fernandes S,Guerreiro L,et al.The effect of surfactants 4(6):M9 on the porosity of carbon xerogels.Microporous Mesoporous [22]Nagy B,Bakos I,Bertoti I,et al.Synergism of nitrogen and Maer,2006,92(1-3:38 reduced graphene in the electrocatalytic behavior of resorcinol- [32]Rey-Raap N,Menendez J A,Arenillas A.RF xerogels with Formaldehyde based carbon aerogels.Carbon,2018,139:872 tailored porosity over the entire nanoscale.Microporous [23]Rey-Raap N,Arenillas A,Menendez J A.A visual validation of Mesoporous Mater,2014.195:266 the combined effect of pH and dilution on the porosity of carbon [33]Xia X H,Zhang X F,Yi S Q,et al.Preparation of high specific xerogels.Microporous Mesoporous Mater,2016,223:89 surface area composite carbon cryogels from self-assembly of [24]Garcia-Bordeje E,Victor-Roman S,Sanahuja-Parejo O,et al graphene oxide and resorcinol monomers for supercapacitors.J Control of the microstructure and surface chemistry of graphene Solid State Electrochem,2016,20(6):1793 aerogels via pH and time manipulation by a hydrothermal method. [34]Wu Z S,Ren W C,Wang D W,et al.High-energy MnOz Nanoscale,.2018,10(7):3526 nanowire/graphene and graphene asymmetric electrochemical [25]Horikaw T,Hayashi J,Muroyama K.Controllability of pore capacitors.ACS Nano,2010,4(10):5835aerogels  with  superelasticity  and  tunable  Poisson ’s  ratio. Adv Mater, 2016, 28（41）: 9223 González M, Baselga J, Pozuelo J. Modulating the electromagnetic shielding  mechanisms  by  thermal  treatment  of  high  porosity graphene aerogels. Carbon, 2019, 147: 27 [16] Xue  Q,  Ding  Y,  Xue  Y  Y,  et  al.  3D  nitrogen-doped  graphene aerogels  as  efficient  electrocatalyst  for  the  oxygen  reduction reaction. Carbon, 2018, 139: 137 [17] Chu  H,  Zhang  F  F,  Pei  L  Y,  et  al.  Ni,  Co  and  Mn  doped  SnS2- graphene aerogels for supercapacitors. J Alloys Compd, 2018, 767: 583 [18] Ates  M,  Caliskan  S,  Ozten  E.  Preparation  of  rGO/Ag/PEDOT nanocomposites  for  supercapacitors. Mater Technol,  2018, 33（14）: 872 [19] Yang Y, Xi Y L, Li J Z, et al. Flexible supercapacitors based on polyaniline  arrays  coated  graphene  aerogel  electrodes. Nanoscale Res Lett, 2017, 12: 394 [20] Liu  L,  Tian  G  Y,  Ma  R,  et  al.  Preparation  and  electrosorption performance  of  graphene  Xerogel. ECS Solid State Lett,  2015, 4（6）: M9 [21] Nagy  B,  Bakos  I,  Bertoti  I,  et  al.  Synergism  of  nitrogen  and reduced  graphene  in  the  electrocatalytic  behavior  of  resorcinol  - Formaldehyde based carbon aerogels. Carbon, 2018, 139: 872 [22] Rey-Raap  N,  Arenillas  A,  Menendez  J  A.  A  visual  validation  of the combined effect of pH and dilution on the porosity of carbon xerogels. Microporous Mesoporous Mater, 2016, 223: 89 [23] Garcia-Bordeje  E,  Victor-Roman  S,  Sanahuja-Parejo  O,  et  al. Control  of  the  microstructure  and  surface  chemistry  of  graphene aerogels via pH and time manipulation by a hydrothermal method. Nanoscale, 2018, 10（7）: 3526 [24] [25] Horikaw  T,  Hayashi  J,  Muroyama  K.  Controllability  of  pore characteristics  of  resorcinol –formaldehyde  carbon  aerogel. Carbon, 2004, 42（8-9）: 1625 Feng Y N, Wang J, Ge L, et al. Pore size controllable preparation for low density porous nano-carbon. J Nanosci Nanotechnol, 2013, 13（10）: 7012 [26] Rey-Raap N, Menendez J A, Arenillas A. Simultaneous adjustment of the main chemical variables to fine-tune the porosity of carbon xerogels. Carbon, 2014, 78: 490 [27] Elkhatat A M, Al-Muhtaseb S A. Advances in tailoring resorcinol￾formaldehyde organic and carbon gels. Adv Mater, 2011, 23（26）: 2887 [28] Gallegos-Suarez E, Perez-Cadenas A F, Maldonado-Hodar F J, et al.  On  the  micro-  and  mesoporosity  of  carbon  aerogels  and xerogels.  The  role  of  the  drying  conditions  during  the  synthesis processes. Chem Eng J, 2012, 181-182: 851 [29] Al-Muhtaseb  S  A,  Ritter  J  A.  Preparation  and  properties  of resorcinol –formaldehyde  organic  and  carbon  gels. Adv Mater, 2003, 15（2）: 101 [30] Matos I, Fernandes S, Guerreiro L, et al. The effect of surfactants on  the  porosity  of  carbon  xerogels. Microporous Mesoporous Mater, 2006, 92（1-3）: 38 [31] Rey-Raap  N,  Menendez  J  A,  Arenillas  A.  RF  xerogels  with tailored  porosity  over  the  entire  nanoscale. Microporous Mesoporous Mater, 2014, 195: 266 [32] Xia X H, Zhang X F, Yi S Q, et al. Preparation of high specific surface  area  composite  carbon  cryogels  from  self-assembly  of graphene  oxide  and  resorcinol  monomers  for  supercapacitors. J Solid State Electrochem, 2016, 20（6）: 1793 [33] Wu  Z  S,  Ren  W  C,  Wang  D  W,  et  al.  High-energy  MnO2 nanowire/graphene  and  graphene  asymmetric  electrochemical capacitors. ACS Nano, 2010, 4（10）: 5835 [34] 郭志成等： 氧化石墨烯掺杂量与 pH 值对石墨烯气凝胶储能性能的影响 · 247 ·