Reaction with Nitrous acid 脂肪伯胺 RNH HO-N=O HO R-N三N N2↑+醇烯烃的混合物 OH CH3(CH2)3OH CH3 CH2 CHCH3 13% CH3(CH2)3NH2 NaNO2/HCI(aq 25% CH3 (CH2)3Cl CH3 CH2 CHCH3 25C 5% 3% H CH CH3 CH3 CH,CH=CH, CH3 26% 3% 7% CH3CH2 CH2 CH2N2 CI CH3 CH2CH2CI t rearrangement CH3 CH2CHCH脂肪伯胺 e.g. CH3 (CH2 )3NH2 NaNO2 /HCl(aq.) 25 C o CH3(CH2)3OH CH3CH2CHCH3 OH CH3(CH2)3Cl CH3CH2CHCH3 Cl CH3CH2CH=CH2 CH3 C C CH3 H H CH3 C C CH3 H H 26% 3% 7% 5% 3% 13% 25% Reaction with Nitrous Acid -N2 Rearrangement RNH2 HO N=O R N N + H2O N2 + 醇, 烯烃的混合物 CH3CH2CH2CH2N2 + Cl - CH3CH2CH2CH2 + CH3CH2CHCH3