.744 工程科学学报,第43卷.第6期 and characterisation of hierarchical biomimetic superhydrophobic [82]Qu H M,Zhang J,Ma Y X,et al.Phase-selective gelators based on structures.RSC Adv,2014,4(42):22053 p-alkoxybenzoyl for oil spill recovery and dye removal.Trans [69]Si Y F,Guo Z G.Superhydrophobic nanocoatings:from materials Tianjin Univ,.2019,25(6):586 to fabrications and to applications.Nanoscale,2015,7(14):5922 [83]Kota A K,Kwon G,Choi W,et al.Hygro-responsive membranes [70]Chu Z L,Seeger S.Superamphiphobic surfaces.Chem Soc Rev, for effective oil-water separation.Nat Commun,2012,3:1025 2014.43(8):2784 [84]Xue Z X,Wang S T,Lin L,et al.A novel superhydrophilic and [71]Sun Y H,Guo Z G.A scalable,self-healing and hot liquid underwater superoleophobic hydrogel-coated mesh for oil/water repelling superamphiphobic spray coating with remarkable separation.Ady Mater,2011,23(37):4270 mechanochemical robustness for real-life applications.Nanoscale, [85]Gupta R K,Dunderdale G J,England M W,et al.Oil/water 2019,11(29):13853 separation techniques:a review of recent progresses and future [72]Tie L,Li J,Guo Z G,et al.Controllable preparation of multiple directions.J Mater Chem A.2017,5(31):16025 superantiwetting surfaces:from dual to quadruple superlyo [86]Zhao X J,Luo YY,Tan P X,et al.Hydrophobically modified phobicity.Chem Eng J,2019,369:463 chitin/halloysite nanotubes composite sponges for high efficiency [73]Wang H J,Zhang Z H,Wang Z K,et al.Multistimuli-responsive oil-water separation.Int/Biol Macromol,019,132:406 microstructured superamphiphobic surfaces with large-range, [87]Guo D Y,Chen J H,Hou K,et al.A facile preparation of reversible switchable wettability for oil.ACS Appl Mater superhydrophobic halloysite-based meshes for efficient oil-water Interfaces,2019,11(31):28478 separation.Appl Clay Sci,2018,156:195 [74]Zhang J P,Yu B,Wei Q Y,et al.Highly transparent [88]Ma Q L,Cheng H F,Fane A G,et al.Recent development of superamphiphobic surfaces by elaborate microstructure regulation. advanced materials with special wettability for selective oil/water J Colloid Interface Sci,2019,554:250 separation.Small,2016,12(16):2186 [75]Arcudi F,Cavallaro G,Lazzara G,et al.Selective functionalization [89]Aguzzi C,Cerezo P,Viseras C,et al.Use of clays as drug delivery of halloysite cavity by click reaction:structured filler for systems:possibilities and limitations.Appl Clay Sci,2007,36(1- enhancing mechanical properties of bionanocomposite films.J 3):22 Phys Chem C,2014,118(27:15095 [90]Kumar-Krishnan S,Hernandez-Rangel A,Pal U,et al.Surface [76]Wu H,Watanabe H,Ma W,et al.Robust liquid marbles stabilized functionalized halloysite nanotubes decorated with silver with surface-modified halloysite nanotubes.Langmuir,2013, 29(48):14971 nanoparticles for enzyme immobilization and biosensing.Mater [77]Liu M X,Jia Z X,Liu F,et al.Tailoring the wettability of Chem B,2016,4(15上:2553 [91]Goran J M,Mantilla S M,Stevenson K J.Influence of surface polypropylene surfaces with halloysite nanotubes.J Colloid Interface Sci,2010,350(1):186 adsorption on the interfacial electron transfer of flavin adenine [78]Jin Z L,Zhang Y Q,Wei S,et al.Molding of molecular sieve dinucleotide and glucose oxidase at carbon nanotube and nitrogen- residues and their application in cleaning oily wastewater.Trans doped carbon nanotube electrodes.Anal Chem,2013,85(3):1571 Tianjin Univ,.2019,25(6):631 [92]Lun H L,Ouyang J,Yang H M.Natural halloysite nanotubes [79]Dong L H,Zhang H J,Zhang J,et al.Carbon nanotube modified modified as an aspirin carrier.RSCAdv,2014,4(83):44197 sepiolite porous ceramics for high-efficient oil/water separation.J [93]Lisuzzo L,Cavallaro G,Parisi F,et al.Colloidal stability of mor8Maer,2020,35(6):689 halloysite clay nanotubes.Ceram Int,2019,45(2):2858 (董龙浩,张海军,张俊,等.碳纳米管改性海泡石多孔陶瓷及其 [94]Riela S,Massaro M,Colletti C G,et al.Development and 高效油水分离性能研究.无机材料学报,2020,35(6):689) characterization of co-loaded curcumin/triazole-halloysite systems [80]Zhang Y,Zhang Q.Zhang R Y,et al.Preparation of and evaluation of their potential anticancer activity.IntJ Pharm, superhydrophobic composites sponge and its application in oil- 2014.475(1-2):613 water separation.J/norg Mater,2020,35(4):475 [95]Cavallaro G,Lazzara G,Milioto S,et al.Hydrophobically (张颖,张骞,张瑞阳,等.超疏水复合海绵材料的制备及在油水 modified halloysite nanotubes as reverse micelles for water-in-oil 分离的应用.无机材料学报,2020,35(4):475) emulsion.Langmuir,2015,31(27):7472 [81]Chen C L,Weng D,Mahmood A,et al.Separation mechanism and [96]Li H,Zhu X H,Zhou H,et al.Functionalization of halloysite construction of surfaces with special wettability for oil/water nanotubes by enlargement and hydrophobicity for sustained release separation.ACS Appl Mater Interfaces,2019,11(11):11006 of analgesic.Colloids SurfA,2015,487:154and characterisation of hierarchical biomimetic superhydrophobic structures. RSC Adv, 2014, 4(42): 22053 Si Y F, Guo Z G. Superhydrophobic nanocoatings: from materials to fabrications and to applications. Nanoscale, 2015, 7(14): 5922 [69] Chu Z L, Seeger S. Superamphiphobic surfaces. Chem Soc Rev, 2014, 43(8): 2784 [70] Sun Y H, Guo Z G. A scalable, self-healing and hot liquid repelling superamphiphobic spray coating with remarkable mechanochemical robustness for real-life applications. Nanoscale, 2019, 11(29): 13853 [71] Tie L, Li J, Guo Z G, et al. Controllable preparation of multiple superantiwetting surfaces: from dual to quadruple superlyophobicity. Chem Eng J, 2019, 369: 463 [72] Wang H J, Zhang Z H, Wang Z K, et al. Multistimuli-responsive microstructured superamphiphobic surfaces with large-range, reversible switchable wettability for oil. ACS Appl Mater Interfaces, 2019, 11(31): 28478 [73] Zhang J P, Yu B, Wei Q Y, et al. Highly transparent superamphiphobic surfaces by elaborate microstructure regulation. J Colloid Interface Sci, 2019, 554: 250 [74] Arcudi F, Cavallaro G, Lazzara G, et al. Selective functionalization of halloysite cavity by click reaction: structured filler for enhancing mechanical properties of bionanocomposite films. J Phys Chem C, 2014, 118(27): 15095 [75] Wu H, Watanabe H, Ma W, et al. Robust liquid marbles stabilized with surface-modified halloysite nanotubes. Langmuir, 2013, 29(48): 14971 [76] Liu M X, Jia Z X, Liu F, et al. Tailoring the wettability of polypropylene surfaces with halloysite nanotubes. J Colloid Interface Sci, 2010, 350(1): 186 [77] Jin Z L, Zhang Y Q, Wei S, et al. Molding of molecular sieve residues and their application in cleaning oily wastewater. Trans Tianjin Univ, 2019, 25(6): 631 [78] Dong L H, Zhang H J, Zhang J, et al. Carbon nanotube modified sepiolite porous ceramics for high-efficient oil/water separation. J Inorg Mater, 2020, 35(6): 689 (董龙浩, 张海军, 张俊, 等. 碳纳米管改性海泡石多孔陶瓷及其 高效油水分离性能研究. 无机材料学报, 2020, 35(6):689) [79] Zhang Y, Zhang Q, Zhang R Y, et al. Preparation of superhydrophobic composites sponge and its application in oilwater separation. J Inorg Mater, 2020, 35(4): 475 (张颖, 张骞, 张瑞阳, 等. 超疏水复合海绵材料的制备及在油水 分离的应用. 无机材料学报, 2020, 35(4):475) [80] Chen C L, Weng D, Mahmood A, et al. Separation mechanism and construction of surfaces with special wettability for oil/water separation. ACS Appl Mater Interfaces, 2019, 11(11): 11006 [81] Qu H M, Zhang J, Ma Y X, et al. Phase-selective gelators based on p-alkoxybenzoyl for oil spill recovery and dye removal. Trans Tianjin Univ, 2019, 25(6): 586 [82] Kota A K, Kwon G, Choi W, et al. Hygro-responsive membranes for effective oil-water separation. Nat Commun, 2012, 3: 1025 [83] Xue Z X, Wang S T, Lin L, et al. A novel superhydrophilic and underwater superoleophobic hydrogel-coated mesh for oil/water separation. Adv Mater, 2011, 23(37): 4270 [84] Gupta R K, Dunderdale G J, England M W, et al. Oil/water separation techniques: a review of recent progresses and future directions. J Mater Chem A, 2017, 5(31): 16025 [85] Zhao X J, Luo Y Y, Tan P X, et al. Hydrophobically modified chitin/halloysite nanotubes composite sponges for high efficiency oil-water separation. Int J Biol Macromol, 2019, 132: 406 [86] Guo D Y, Chen J H, Hou K, et al. A facile preparation of superhydrophobic halloysite-based meshes for efficient oil–water separation. Appl Clay Sci, 2018, 156: 195 [87] Ma Q L, Cheng H F, Fane A G, et al. Recent development of advanced materials with special wettability for selective oil/water separation. Small, 2016, 12(16): 2186 [88] Aguzzi C, Cerezo P, Viseras C, et al. Use of clays as drug delivery systems: possibilities and limitations. Appl Clay Sci, 2007, 36(1- 3): 22 [89] Kumar-Krishnan S, Hernandez-Rangel A, Pal U, et al. Surface functionalized halloysite nanotubes decorated with silver nanoparticles for enzyme immobilization and biosensing. J Mater Chem B, 2016, 4(15): 2553 [90] Goran J M, Mantilla S M, Stevenson K J. Influence of surface adsorption on the interfacial electron transfer of flavin adenine dinucleotide and glucose oxidase at carbon nanotube and nitrogendoped carbon nanotube electrodes. Anal Chem, 2013, 85(3): 1571 [91] Lun H L, Ouyang J, Yang H M. Natural halloysite nanotubes modified as an aspirin carrier. RSC Adv, 2014, 4(83): 44197 [92] Lisuzzo L, Cavallaro G, Parisi F, et al. Colloidal stability of halloysite clay nanotubes. Ceram Int, 2019, 45(2): 2858 [93] Riela S, Massaro M, Colletti C G, et al. Development and characterization of co-loaded curcumin/triazole-halloysite systems and evaluation of their potential anticancer activity. Int J Pharm, 2014, 475(1-2): 613 [94] Cavallaro G, Lazzara G, Milioto S, et al. Hydrophobically modified halloysite nanotubes as reverse micelles for water-in-oil emulsion. Langmuir, 2015, 31(27): 7472 [95] Li H, Zhu X H, Zhou H, et al. Functionalization of halloysite nanotubes by enlargement and hydrophobicity for sustained release of analgesic. Colloids Surf A, 2015, 487: 154 [96] · 744 · 工程科学学报,第 43 卷,第 6 期