D.a,b,g and d elimination reactions Chapter 7.Electrophilic and Nucleophilic Addition and Abstraction 【教学要求】 掌握金属有机化学反应中的亲核、亲电反应机理及相关的反应。 【教学内容】 A.Introduction B.Nucleophilic addition to CO and CNR C.Nucleophilic addition to olefins and acetylenes D.Nucleophilic abstraction E.Electrophilic addition F.Electrophilic abstraction Chapter 8.Carbene and Carbyne Complexes 【教学要求】 掌握金属卡宾、卡炔化合物的成键特征、基本性质和相关反应。 【教学内容】 Introduction to M-C multiple bonds Common synthetic routes to carbene complexes Reactivity of carbene complexes Common synthetic routes to carbyne complexes Reactivity of carbyne complexes 三、本课程考核方法 期末闭卷考试(100分) 四、教材和主要参考书 1)Recommended text: The Organometallic Chemistry of the Transition Metals,Robert H.Crabtree,John Wiley Sons:New York,3rd Edition,2001 2)Other References: a)Organometallic Chemistry,G.O.Spessard,G.L.G.L.Miessler,Prentice-Hall:New Jersey,1997. b)Advanced Inorganic Chemistry,F.A.Cotton,G.Wilkinson,C.A.Murillo,M.Bochmann,John Wiley Sons,6th ed.1999. c)Organotransition Metal Chemistry,Akio Yamamoto,John Wiley Sons:New York,1986. d)Concepts and Models of Inorganic Chemistry,B.Douglas,D.MacDaniel,J.Alexander,John Wiley Sons: New York,3rd ed.1993. e)G.L.Miessler,D.A.Tarr:Inorganic Chemistry,G.L.Miessler,D.A.Tarr,Prentice Hall:Englewood Cliffs.1991 f)Any other books on Organometallic ChemistryD. a, b, g and d elimination reactions Chapter 7. Electrophilic and Nucleophilic Addition and Abstraction 【教学要求】 掌握金属有机化学反应中的亲核、亲电反应机理及相关的反应。 【教学内容】 A. Introduction B. Nucleophilic addition to CO and CNR C. Nucleophilic addition to olefins and acetylenes D. Nucleophilic abstraction E. Electrophilic addition F. Electrophilic abstraction Chapter 8. Carbene and Carbyne Complexes 【教学要求】 掌握金属卡宾、卡炔化合物的成键特征、基本性质和相关反应。 【教学内容】 Introduction to M-C multiple bonds Common synthetic routes to carbene complexes Reactivity of carbene complexes Common synthetic routes to carbyne complexes Reactivity of carbyne complexes 三、本课程考核方法 期末闭卷考试（100分） 四、教材和主要参考书 1) Recommended text: The Organometallic Chemistry of the Transition Metals, Robert H. Crabtree, John Wiley & Sons: New York, 3rd Edition, 2001. 2) Other References: a) Organometallic Chemistry, G. O. Spessard, G. L. G. L. Miessler, Prentice-Hall: New Jersey, 1997. b) Advanced Inorganic Chemistry, F. A. Cotton, G. Wilkinson, C. A. Murillo, M. Bochmann, John Wiley & Sons, 6th ed. 1999. c) Organotransition Metal Chemistry, Akio Yamamoto, John Wiley & Sons: New York, 1986. d) Concepts and Models of Inorganic Chemistry, B. Douglas, D. MacDaniel, J. Alexander, John Wiley & Sons: New York, 3rd ed. 1993. e) G. L. Miessler, D. A. Tarr: Inorganic Chemistry, G. L. Miessler, D. A. Tarr, Prentice Hall: Englewood Cliffs, 1991. f) Any other books on Organometallic Chemistry