第15章羧酸及其衍生物 15-1 (CHCHCHCOONCO CHCHCHCOC CHCH.CHaC 0 CH,CH,CHC≤O (4)CH3CH2CH2COOC2Hs (s)CH;CH2CH2CONH2 )CH3(CH2)2CH2OH ()CH(CH2CH,OH(⑧)CH,CH2CH2B汉斯狄克反应)(g）CH,CH2CHCOOH C Io)CH,CHCH,COBr(I)(CH,CH,CH,CO20()CHCH2CH2Br(柯齐反应) 15-2 ()○COONa2)○COONa+Co2+H,0g)⑦-COONa+Co2+H,0 )(○Co0)nCaO②COONH4(6⑦CoNH 6)○c00CH,CH,CH,8(@C020g○coh0 (10)>CH2OH (11)NR (12)NR a)COBr)Ocoa(s)○coC (6)Oc0oH()○c0oH48)○c0oH Br NO2 SO,H (19)NR (20)NR 15-3 (CH:CH-COOH G CHCH:COOC,Hs (o-C.Hs (CH;CHzCONHCHs (CH,CHaCONHC.Hs CHsCHOH OH (7)CH3CH2CHO (s)CHaCH2CCH2CH (C2He C2Hs CH3CH2 cmBcueccad co
15  15-1 O + (1 ) CH3CH2CH2COONa CO2 (2 ) CH3CH2CH2COCl (3 ) CH3CH2CH2C O CH3CH2CH2C O (4 ) CH3CH2CH2COOC2H5 (5 ) CH3CH2CH2CONH2 (6 ) CH3 (CH2 )2CH2OH Br Cl (7) CH3 (CH2 )2CH2OH (8) CH3CH2CH2 (￾✂✁☎✄✝✆✟✞✡✠☞☛✍✌ 9 ☛ CH3CH2CHCOOH (10) CH3CH2CH2COBr (11 ) (CH3CH2CH2CO)2O (12 ) CH3CH2CH2Br(✎✟✏✒✑✔✓ ✕ 15-2 COON + a ✖ 1 ✗ (2 ) COONa CO2 (3) COONa + CO2 + H2O + H2O COO COONH4 (4 ) ( )2Ca (5 ) CONH2 (6 ) (7 ) COOCH2CH2CH3 (8) ( CO)2O (9 ) CO)2O (10) CH2OH (11 ) (12 NR ) NR COB Cl Cl r (13 ) (14 ) CO (15 ) CO Br NO2 SO3H (16 ) COOH (17 ) COOH (18 ) COOH (19) NR (20) NR 15-3 C C2H5 O (1 ) CH3CH2COOH (2 ) CH3CH2COOC2H5 (3) O C2H5CH2 (4 ) CH3CH2CONHCH3 (5 ) CH3CH2CONHC6H5 (6) OH C2H5 C2H5 OH O (7) CH3CH2CHO (8) CH3CH2CCH2CH3 CH3CH2 (9 ) C C2H5 C2H5 CH3 C2H5 O O O O CH2CH2 (10 ) C C C CH3 (11) (12 ) C2H5 O C O O C O