Symmetric Stretch Asymmetric Stretch Symmetric Bend Molecular asymmetry is a requirement for excitation by infrared radiation and asymmetric stretching or bending transitions are possibles region fully symmetric molecules do not display absorbances in th For the purpose of routine organic structure determination, using a battery of spectroscopic me thods, the most important absorptions in the infrared region are the simple stretching vibrations. For simple systems, these can be approximated by considering the atoms as point masses, linked by a' spring having a force constant k and following Hooke's Law. Using this simple approximation, the equation shown below can be utilized to approximate the characteristic stretching frequency (in cm) of two atoms of masses m and ma, linked by a bond with a force constant k: anyU where ?=m, m, /(m, +m, )(termed the reduced mass), and c is the velocity of light. The stretching vibrations of typical organic molecules tend to fall within distinct regions of the infrared spectrum, as shown below 3700-2500 cm": X-H stretching(X=C, N,O, S) 2300-2000 cm: C-X stretching(X=C or N) 1900-1500 cm": C-X stretching(X=C, N, O) 1300-800 cm: C-X stretching(X=C, N, O) Since most organic molecules have single bonds, the region below 1500 cm" can become quite complex and is often referred to as the fingerprint region: that is, if you are dealing with an unknown molecule which has the same fingerprint in this region, that is considered evidence that the two molecules may be identic Because of the complexity of the region below 1500 cm, in this review, we will focus on functional group stretching bands in the higher frequency region. You should note that for many of these bands, the Ir spectrum may give equivocal structural information; quite often the absence of a band is as informative as the presence of a particular band Use the mENU above to view an IR functional group correlation table, or a sample f common ir absorbance peaks.Symmetric Stretch Asymmetric Stretch Symmetric Bend Molecular asymmetry is a requirement for excitation by infrared radiation and fully symmetric molecules do not display absorbances in this region unless asymmetric stretching or bending transitions are possible. For the purpose of routine organic structure determination, using a battery of spectroscopic methods, the most important absorptions in the infrared region are the simple stretching vibrations. For simple systems, these can be approximated by considering the atoms as point masses, linked by a 'spring' having a force constant k and following Hooke's Law. Using this simple approximation, the equation shown below can be utilized to approximate the characteristic stretching frequency (in cm-1) of two atoms of masses m and m2, linked by a bond with a force constant k: where ?= m1m2/(m1+m2) (termed the 'reduced mass'), and c is the velocity of light. The stretching vibrations of typical organic molecules tend to fall within distinct regions of the infrared spectrum, as shown below: • 3700 - 2500 cm-1 : X-H stretching (X = C, N, O, S) • 2300 - 2000 cm-1 : C X stretching (X = C or N) • 1900 - 1500 cm-1 : C X stretching (X = C, N, O) • 1300 - 800 cm-1 : C-X stretching (X = C, N, O) Since most organic molecules have single bonds, the region below 1500 cm-1 can become quite complex and is often referred to as the 'fingerprint region': that is, if you are dealing with an unknown molecule which has the same 'fingerprint' in this region, that is considered evidence that the two molecules may be identical. Because of the complexity of the region below 1500 cm-1, in this review, we will focus on functional group stretching bands in the higher frequency region. You should note that for many of these bands, the IR spectrum may give equivocal structural information; quite often the absence of a band is as informative as the presence of a particular band. Use the MENU above to view an IR functional group correlation table, or a sample of common IR absorbance peaks