[12]Jin H, Park S-E, Lee JM, Ryu SK. The shape selectivity of [24] Prauchner MJ, Pasa VMD, Otani C, Otani S, Pardini LC. activated carbon fibers as a palladium catalyst support Carbon lohallen NDS Structural evolution of eucalyptus tar pitch-based 96:34:429-3 carbons during carbonization. Biomass Bioenergy 2005: 28: 53-61 [3]de la Casa-Lillo MA, Alcaniz-Monge J, Raymundo- Pinero E, [25 Prauchner MJ, Pasa VMD, Otani C, Otani S. Rheological study Cazorla-Amoros D, Linares-Solano A. Molecular sieve properties of eucalyptus tar pitches. J Appl Polym Sci 2002: 84: 900-8 carbon fibres. Carbon 1998: 36: 1353--60 26 Prauchner MJ. Sintese e cara arbonosos [14 Lozano-Castello D, Alcaniz- Monge J, de la Casa-Lillo MA, avanca a partir de piche de alcatrao de Cazorla-Amoros D, Linares-Solano A. Advances in the study of Thesis. Federal University of Minas Gerais, Belo Horizonte methane storage in porous carbonaceous materials. Fuel 2001.p.826. 281:1777-803. 27 Alcaniz-Monge J, Cazorla-Amoros D, Linares-Solano A. Effect of [15]Li CY, Wan YZ, Wang J, Wang YL, Jiang XQ, Han LM. Antibacterial pitch-based activated carbon fiber supporting silver based carbon fibres. Carbon 1994: 32- 1277-83 Carbon l998:36:61-5 28 Thwaites MW, Stewart ML, McNeese BE, Sumner MB. Synthesis [16 Ryu sk, Kim SY, Li z. Jaroniec M. Characterization of silver- and characterization of activated pitch-based carbon fibers. Fue ontaining pitch-based activated carbon fibers. J Colloid Interf Sci Process Technol 1993: 34: 137-45 [29] Bansal RC, Donnet J-B, Stoeckli F. In arbon. New [17 Navarri P, Marchal D, Ginestet A. Activated carbon fiber York: Marcel Dekker, 1988. p. 1-26.[cl materials for VOC removal. Filtrat Separat 2001: 38: 33-40 30] Matsumoto T, Mochida I. A structur on oxidative [18 Carazza F, Okuma AA. Alcatrao de Eucalyptus fonte de aromas e stabilization of mesophase pitch fibers sabores. Extended abstracts XI Seminario Carboquimicos. San Carbon1992;30:1041-6 tos. brazil: asao Brasileira deMetalurgia: 2000. P. 271-9 31] Matsumoto T, Mochida I. Oxygen distribution in oxidatively [19 Chen CA, Pakdel H, Roy C. Separation of phenols from stabilized mesophase pitch fiber Carbon 1993: 31: 143-7. Eucalyptus wood tar Biomass Bioenergy 1997: 13: 25-37 32] Edie DD, Dunham MG. Melt spinning pitch-based carbon fibers. o Statistical Yearbook. Associacao Brasileira de Carvao Vegetal, Carbon198927:647-55 Belo horizonte. brasil. 2000. 33] Weibull w. A statistical distribution function of wide applicabil- 21 Sampaio RS. Producao de metais com biomassa plantada. In: ty. J Appl Mech 1951: 18: 293-7 Mello MG, editor. Biomassa: energia dos tropicos em Minas 34] Stoner EG, Edie DD, Durham SD. An end-effect model for the Gerais. Belo Horizonte- Brasil: Editora UFMG: 2001. p. 163-78 single-filament tensile test. J Mater Sci 1994: 29: 6561-74 [22] Prauchner MJ. Pasa VMD, Otani C, Otani S. Characterization [35] Hayashi J-l, Nakashima M, Kusakabe K, Morooka S, Mitsuda s of eucalyptus tar pitches Rapid stabilization of pitch fiber precursor by multi-step thermal oxidation. Carbon 1995: 33: 1567-71 23 Prauchner MJ, Pasa VMD, Otani C, Otani S, Menezes SMC. [36 Fietzer E, KOnkele F. Today's carbon fibres-a new energy-saving Eucalyptus tar pitch pre-treatment for carbon material processing. and environment-friendly all-round material (a review). High J Appl Polym Sci 2004: 91: 1604-lI Temp High Press 1999: 22: 239-66.[12] Jin H, Park S-E, Lee JM, Ryu SK. The shape selectivity of activated carbon fibers as a palladium catalyst support. Carbon 1996;34:429–31. [13] de la Casa-Lillo MA, Alcan˜iz-Monge J, Raymundo-Pin˜ero E, Cazorla-Amoro´s D, Linares-Solano A. Molecular sieve properties of general-purpose carbon fibres. Carbon 1998;36:1353–60. [14] Lozano-Castello´ D, Alcan˜iz-Monge J, de la Casa-Lillo MA, Cazorla-Amoro´s D, Linares-Solano A. Advances in the study of methane storage in porous carbonaceous materials. Fuel 2002;81:1777–803. [15] Li CY, Wan YZ, Wang J, Wang YL, Jiang XQ, Han LM. Antibacterial pitch-based activated carbon fiber supporting silver. Carbon 1998;36:61–5. [16] Ryu SK, Kim SY, Li ZJ, Jaroniec M. Characterization of silvercontaining pitch-based activated carbon fibers. J Colloid Interf Sci 1999;220:157–62. [17] Navarri P, Marchal D, Ginestet A. Activated carbon fiber materials for VOC removal. Filtrat Separat 2001;38:33–40. [18] Carazza F, Okuma AA. Alcatra˜o de Eucalyptus fonte de aromas e sabores. Extended abstracts XI Semina´rio Carboquı´micos. Santos, Brazil: Associac¸a˜o Brasileira deMetalurgia; 2000. p. 271–9. [19] Chen CA, Pakdel H, Roy C. Separation of phenols from Eucalyptus wood tar. Biomass Bioenergy 1997;13:25–37. [20] Statistical Yearbook. Associac¸a˜o Brasileira de Carva˜o Vegetal, Belo Horizonte, Brasil, 2000. [21] Sampaio RS. Produc¸a˜o de metais com biomassa plantada. In: Mello MG, editor. Biomassa: energia dos tro´picos em Minas Gerais. Belo Horizonte-Brasil: Editora UFMG; 2001. p. 163–78. [22] Prauchner MJ, Pasa VMD, Otani C, Otani S. Characterization and thermal polymerization of eucalyptus tar pitches. Energy Fuels 2001;15:449–54. [23] Prauchner MJ, Pasa VMD, Otani C, Otani S, Menezes SMC. Eucalyptus tar pitch pre-treatment for carbon material processing. J Appl Polym Sci 2004;91:1604–11. [24] Prauchner MJ, Pasa VMD, Otani C, Otani S, Pardini LC, Mohallen NDS. Structural evolution of eucalyptus tar pitch-based carbons during carbonization. Biomass Bioenergy 2005;28:53–61. [25] Prauchner MJ, Pasa VMD, Otani C, Otani S. Rheological study of eucalyptus tar pitches. J Appl Polym Sci 2002;84:900–8. [26] Prauchner MJ. Sı´ntese e caracterizac¸a˜o de materiais carbonosos avanc¸ados a partir de piches de alcatra˜o de eucalyptus. PhD Thesis. Federal University of Minas Gerais, Belo Horizonte Brazil; 2001. p. 82–6. [27] Alcan˜iz-Monge J, Cazorla-Amoro´s D, Linares-Solano A. Effect of the activating gas on tensile strength and pore structure of pitchbased carbon fibres. Carbon 1994;32:1277–83. [28] Thwaites MW, Stewart ML, McNeese BE, Sumner MB. Synthesis and characterization of activated pitch-based carbon fibers. Fuel Process Technol 1993;34:137–45. [29] Bansal RC, Donnet J-B, Stoeckli F. In: Active carbon. New York: Marcel Dekker; 1988. p. 1–26. [chapter 1]. [30] Matsumoto T, Mochida I. A structural study on oxidative stabilization of mesophase pitch fibers derived from coal tar. Carbon 1992;30:1041–6. [31] Matsumoto T, Mochida I. Oxygen distribution in oxidatively stabilized mesophase pitch fiber. Carbon 1993;31:143–7. [32] Edie DD, Dunham MG. Melt spinning pitch-based carbon fibers. Carbon 1989;27:647–55. [33] Weibull W. A statistical distribution function of wide applicability. J Appl Mech 1951;18:293–7. [34] Stoner EG, Edie DD, Durham SD. An end-effect model for the single-filament tensile test. J Mater Sci 1994;29:6561–74. [35] Hayashi J-I, Nakashima M, Kusakabe K, Morooka S, Mitsuda S. Rapid stabilization of pitch fiber precursor by multi-step thermal oxidation. Carbon 1995;33:1567–71. [36] Fietzer E, Ku¨nkele F. Todays carbon fibres—a new energy-saving and environment-friendly all-round material (a review). High Temp High Press 1999;22:239–66. M.J. Prauchner et al. / Carbon 43 (2005) 591–597 597