Notable reactions NiCl/CrCl2-catalyzed coupling reaction between vinyl iodides and aldehydes( nhk coupling). a Pd(0)catalyzed and thallium hydroxide assisted synthesis of cis-trans conjugated dienes from vinyl iodides and vinyl boronic acids a New methods for the construction of N-acyl vinylogous ureasNotable Reactions Notable Reactions NiCl 2/CrCl 2 -catalyzed coupling reaction between catalyzed coupling reaction between vinyl iodides and aldehydes (NHK Coupling). vinyl iodides and aldehydes (NHK Coupling). Pd(0) catalyzed and thallium hydroxide assisted Pd(0) catalyzed and thallium hydroxide assisted synthesis of synthesis of cis -trans conjugated dienes from vinyl conjugated dienes from vinyl iodides and vinyl boronic acids. iodides and vinyl boronic acids. New Methods for the construction of N New Methods for the construction of N -acyl vinylogous ureas vinylogous ureas