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1945 W.PAULI shells of the atom and the general properties of the rare earths. The question, as to why all electrons for an atom in its ground state were not bound in the innermost shell, had already been emphasized by Bohr as a fundamental problem in his earlier works. In his Gottingen lectures he treated particularly the closing of this innermost K-shell in the helium atom and its essential connection with the two non-combining spectra of helium, the ortho-and para-helium spectra However, no convincing explanation for this phenom enon could be given on the basis of classical mechanics. It made a strong impression on me that Bohr at that time and in later discussions was looking for a general explanation which should hold for the closing of every electron shell and in which the number 2 was considered to be as essential as 8 in contrast to Sommerfeld's approach Following Bohrs invitation, I went to Copenhagen in the autumn of 1922 where I made a serious effort to explain the so-called anomalous Zeeman effect >, as the spectroscopists called a type of splitting of the spectral lines in a magnetic field which is different from the normal triplet. On the one hand, the anomalous type of splitting exhibited beautiful and simple laws and Lan- de had already succeeded to find the simpler splitting of the spectroscopic terms from the observed splitting of the lines. The most fundamental of his results thereby was the use of half-integers as magnetic quantum numbers for the doublet-spectra of the alkali metals. On the e anom- alous splitting was hardly understandable from the standpoint of the me- chanical model of the atom, since very general assumptions concerning the electron, using classical theory as well as quantum theory, always led to the same triplet. A closer investigation of this problem left me with the feeling that it was even more unapproachable. We know now that at that time one was confronted with two logically different difficulties simultaneously. One was the absence of a general key to translate a given mechanical model in- to quantum theory which one tried in vain by using classical mechanics to describe the stationary quantum states themselves. The second difficulty was our ignorance concerning the proper classical model itself which could be suited to derive at all an anomalous splitting of spectral lines emit- ted by an atom in an external magnetic field. It is therefore not surprising that i could not find a satisfactory solution of the problem at that time I suc ceeded, however, in generalizing Lande's term analysis for very strong magnetic fields, a case which, as a result of the magneto-optic transforma- tion(Paschen-Back effect), is in many respects simpler. This early work2 8 1945 W.PAUL I shells of the atom and the general properties of the rare earths. The question, as to why all electrons for an atom in its ground state were not bound in the innermost shell, had already been emphasized by Bohr as a fundamental problem in his earlier works. In his Göttingen lectures he treated particularly the closing of this innermost K-shell in the helium atom and its essential connection with the two non-combining spectra of helium, the ortho- and para-helium spectra. However, no convincing explanation for this phenom￾enon could be given on the basis of classical mechanics. It made a strong impression on me that Bohr at that time and in later discussions was looking for a general explanation which should hold for the closing of every electron shell and in which the number 2 was considered to be as essential as 8 in contrast to Sommerfeld’s approach. Following Bohr’s invitation, I went to Copenhagen in the autumn of 1922, where I made a serious effort to explain the so-called « anomalous Zeeman effect », as the spectroscopists called a type of splitting of the spectral lines in a magnetic field which is different from the normal triplet. On the one hand, the anomalous type of splitting exhibited beautiful and simple laws and Lan￾déI had already succeeded to find the simpler splitting of the spectroscopic terms from the observed splitting of the lines. The most fundamental of his results thereby was the use of half-integers as magnetic quantum numbers for the doublet-spectra of the alkali metals. On the other hand, the anom￾alous splitting was hardly understandable from the standpoint of the me￾chanical model of the atom, since very general assumptions concerning the electron, using classical theory as well as quantum theory, always led to the same triplet. A closer investigation of this problem left me with the feeling that it was even more unapproachable. We know now that at that time one was confronted with two logically different difficulties simultaneously. One was the absence of a general key to translate a given mechanical model in￾to quantum theory which one tried in vain by using classical mechanics to describe the stationary quantum states themselves. The second difficulty was our ignorance concerning the proper classical model itself which could be suited to derive at all an anomalous splitting of spectral lines emit￾ted by an atom in an external magnetic field. It is therefore not surprising that I could not find a satisfactory solution of the problem at that time. I suc￾ceeded, however, in generalizing Landé’s term analysis for very strong magnetic fields2 , a case which, as a result of the magneto-optic transforma￾tion (Paschen-Back effect), is in many respects simpler. This early work
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