ORGANIC CHEMISTRY Chapter 8 CCI CI CI 4 ( CH3)3 CCH=CH2 Cl2 (CH3)3CCH—CH Br Br CCI ( CH3) CHCH=CHCH3 Br (CH3)2CHCH—CH2 Relative rate of bromination Compounds CH2-CH2 CH3CH=CH2(CH3)2C=CH2 Relative rate 2 10.4 (CH3h2C=C(CH3 PhCH=CH 14 3.4 Brch=cH CHo-CHCOH <0.04 <0.03 Department of Chemistry, Xiamen UniversityORGANIC CHEMISTRY Department of Chemistry, Xiamen University Chapter 8 (CH3)3CCH CH2 + Cl2 CCl4 5 (CH3)3CCH CH2 Cl Cl (CH3)2CHCH CHCH3 + Br2 CCl4 0 (CH3)2CHCH CH2 Br Br Relative rate of bromination CH2 CH2 CH3CH CH2 (CH3)2C CH2 (CH3)2C C(CH3)2 PhCH CH2 BrCH CH2 CH2 CHCO2H 1 2 10.4 14 3.4 < 0.04 < 0.03 Relative rate Compounds