第7期 傅开彬等：不同类型黄铜矿的生物浸出研究 ·811 个方面：成矿地质特征、常见金属矿物和伴生元素 Miner Process,2001,62(1-4)243 成矿地质特征主要包括成矿岩体和围岩两个方面. 9]C6rdoba E M,Munoz J A,Blazquez M L,et al.Leaching of chal- 成矿岩体、围岩、伴生矿物和元素、成矿温度和压力 copyrite with ferric ion:Part II.Effect of redox potential.Hydro- metallurgy,2008,93(3/4):88 等物理化学条件，都会影响矿物性质，而且它们相 [10]Watling H R.The bioleaching of sulphide minerals with emphasis 互作用使两类黄铜矿结构的不同，导致其晶格能存 on copper sulphides:a review.Hydrometallurgy,2006,84 (1/ 在差异，致使浸出存在很大差别.这些因素对不同 2):81 类型黄铜矿生物浸出的影响将在后续工作中研究. [11]Sand W,Gehrke T,Jozsa PG,et al.Bio)chemistry of bacteri- al leaching:direct vs.indirect bioleaching.Hydrometallurgy, 2001,59(213):159 参考文献 [12]Todd E C.Sherman D M,Purton JA.Surface oxidation of chal- [Guo W K,Chang Y F,Huang C K.Some problems of metallogen- copyrite (CuFeS,)under ambient atmospheric and aqueous (pH esis and distribution of the main copper deposits in china.Acta Ge- 2-10)conditions:Cu,Fe L-and O K-edge X-ray spectroscopy ol Sin,1978(3):169 Geochim Cosmochim Acta,2003,67(12)2137 (郭文魁，常印佛，黄崇轲.我国主要类型铜矿成矿和分布的 [13]Sandstrom A,Shchukarev A,Paul J.XPS characterisation of 某些问题.地质学报，1978(3)：169) chalcopyrite chemically and bio-eached at high and low redox po- 2]Chen Y C.Metallogenic series of ore deposits.Earth Sci Front, tential.Miner Eng,2005,18(5):505 1994,1(3/4):90 [14]Harmer S L,Thomas J E,Forasiero D.The evolution of surface (陈毓川.矿床的成矿系列.地学前缘，1994,1(3/4)：90) layers formed during chalcopyrite leaching.Geochim Cosmochim B]Cordoba E M,Munoz J A,Blazquez M L,et al.Leaching of chal- Acta,2006,70(17):4392 copyrite with ferric ion:Part I.General aspects.Hydrometallur- [15]Lazaro I,Nicol M.The mechanism of the dissolution and passi- ,2008,93(3/4):81 vation of chalcopyrite:an electrochemical study /Hydrometal- 4]Bevilaqua D,Leite A LL C.Garcia O Jr,et al.Oxidation of lurgy 2003:5th International Symposium.Canada,2003:405 chaleopyrite by Acidithiobacillus ferrooxidans and Acidithiobacillus [16]Hiroyoshi N,Miki H,Hirajima T,et al.A model for ferrous- thiooxidans in shake flasks.Process Biochem,2002,38 (4):587 promoted chalcopyrite leaching.Hydrometallurgy,2000,57 [5]Qiu M Q,Xiong S Y,Zhang W M.Efficacy of chalcopyrite bi- (1):31 oleaching using a pure and a mixed bacterium.J Unin Sci Technol [17]Vilcaez J,Inoue C.Mathematical modeling of thermophilic bi- Beijing,2006,13(1):7 oleaching of chalcopyrite.Miner Eng,2009,22(11):951 [6]Karimi G R,Rowson N A,Hewitt C J.Bioleaching of copper via [18]Li C Y.Major Types and Metallogenic Prospect of Copper Deposits iron oxidation from chalcopyrite at elevated temperatures.Food in China.Beijing:Geology Publishing House,2000 Bioprod Process,2010,88(1)21 (李朝阳.中国铜矿主要类型特征及其成矿远景.北京：地 7]Sato H,Nakazawa H,Kudo Y.Effect of silver chloride on the bi- 质出版社，2000) oleaching of chalcopyrite concentrate.Int J Miner Process,2000, [19]Natarajan KA,Wang J.Eelectrochemistry in sulphide bioleach- 59(1):17 ing.Met Ore Dressing Abroad,1997,34(2):44 [8]Gericke M,Pinches A,Van Rooyen J V.Bioleaching of a chal- (兰特拉金KA,王军.硫化矿生物浸出电化学.国外金属选 copyrite concentrate using an extremely thermophilic culture.Int 矿，1997,34(2)：44)第 7 期 傅开彬等: 不同类型黄铜矿的生物浸出研究 个方面: 成矿地质特征、常见金属矿物和伴生元素． 成矿地质特征主要包括成矿岩体和围岩两个方面． 成矿岩体、围岩、伴生矿物和元素、成矿温度和压力 等物理化学条件，都会影响矿物性质，而且它们相 互作用使两类黄铜矿结构的不同，导致其晶格能存 在差异，致使浸出存在很大差别． 这些因素对不同 类型黄铜矿生物浸出的影响将在后续工作中研究． 参 考 文 献 ［1］ Guo W K，Chang Y F，Huang C K． Some problems of metallogen￾esis and distribution of the main copper deposits in china． Acta Ge￾ol Sin，1978( 3) : 169 ( 郭文魁，常印佛，黄崇轲． 我国主要类型铜矿成矿和分布的 某些问题． 地质学报，1978( 3) : 169) ［2］ Chen Y C． Metallogenic series of ore deposits． Earth Sci Front， 1994，1( 3 /4) : 90 ( 陈毓川． 矿床的成矿系列． 地学前缘，1994，1( 3 /4) : 90) ［3］ Córdoba E M，Muoz J A，Blázquez M L，et al． Leaching of chal￾copyrite with ferric ion: Part Ⅰ． General aspects． Hydrometallur￾gy，2008，93( 3 /4) : 81 ［4］ Bevilaqua D，Leite A L L C，Garcia O Jr，et al． Oxidation of chalcopyrite by Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans in shake flasks． Process Biochem，2002，38( 4) : 587 ［5］ Qiu M Q，Xiong S Y，Zhang W M． Efficacy of chalcopyrite bi￾oleaching using a pure and a mixed bacterium． J Univ Sci Technol Beijing，2006，13( 1) : 7 ［6］ Karimi G R，Rowson N A，Hewitt C J． Bioleaching of copper via iron oxidation from chalcopyrite at elevated temperatures． Food Bioprod Process，2010，88( 1) : 21 ［7］ Sato H，Nakazawa H，Kudo Y． Effect of silver chloride on the bi￾oleaching of chalcopyrite concentrate． Int J Miner Process，2000， 59( 1) : 17 ［8］ Gericke M，Pinches A，Van Rooyen J V． Bioleaching of a chal￾copyrite concentrate using an extremely thermophilic culture． Int J Miner Process，2001，62( 1--4) : 243 ［9］ Córdoba E M，Muoz J A，Blázquez M L，et al． Leaching of chal￾copyrite with ferric ion: Part Ⅱ． Effect of redox potential． Hydro￾metallurgy，2008，93( 3 /4) : 88 ［10］ Watling H R． The bioleaching of sulphide minerals with emphasis on copper sulphides: a review． Hydrometallurgy，2006，84 ( 1 / 2) : 81 ［11］ Sand W，Gehrke T，Jozsa P G，et al． ( Bio) chemistry of bacteri￾al leaching: direct vs． indirect bioleaching． Hydrometallurgy， 2001，59( 2 /3) : 159 ［12］ Todd E C，Sherman D M，Purton J A． Surface oxidation of chal￾copyrite ( CuFeS2 ) under ambient atmospheric and aqueous ( pH 2--10) conditions: Cu，Fe L-and O K-edge X-ray spectroscopy． Geochim Cosmochim Acta，2003，67( 12) : 2137 ［13］ Sandstrm ，Shchukarev A，Paul J． XPS characterisation of chalcopyrite chemically and bio-leached at high and low redox po￾tential． Miner Eng，2005，18( 5) : 505 ［14］ Harmer S L，Thomas J E，Fornasiero D． The evolution of surface layers formed during chalcopyrite leaching． Geochim Cosmochim Acta，2006，70( 17) : 4392 ［15］ Lazaro I，Nicol M． The mechanism of the dissolution and passi￾vation of chalcopyrite: an electrochemical study / / Hydrometal￾lurgy 2003: 5th International Symposium． Canada，2003: 405 ［16］ Hiroyoshi N，Miki H，Hirajima T，et al． A model for ferrous￾promoted chalcopyrite leaching． Hydrometallurgy， 2000， 57 ( 1) : 31 ［17］ Vilcáez J，Inoue C． Mathematical modeling of thermophilic bi￾oleaching of chalcopyrite． Miner Eng，2009，22( 11) : 951 ［18］ Li C Y． Major Types and Metallogenic Prospect of Copper Deposits in China． Beijing: Geology Publishing House，2000 ( 李朝阳． 中国铜矿主要类型特征及其成矿远景． 北京: 地 质出版社，2000) ［19］ Natarajan K A，Wang J． Eelectrochemistry in sulphide bioleach￾ing． Met Ore Dressing Abroad，1997，34( 2) : 44 ( 兰特拉金 K A，王军． 硫化矿生物浸出电化学． 国外金属选 矿，1997，34( 2) : 44) ·811·