·180· 工程科学学报，第41卷，第2期 粒间存在引力的主要原因.碳酸钠能够与白钨矿发 国钨业，2015,30(6)：14) 生化学反应，反应后有利于油酸钠吸附，增加白钨矿 [12]Chen X Z.Study on Process and Mechanism Research of Carrier Flotation of Fine Scheelite Used with Hydrophobic Polymers Dis- 表面疏水性，促进白钨矿颗粒间的疏水性团聚，进而 sertation].Changsha:Central South University,2014 能够强化白钨矿的自载体浮选. (陈秀珍.疏水性聚合物对细粒级白钨矿载体浮选工艺和机 理研究[学位论文].长沙：中南大学，2014) 参考文献 [13]Wang J Z,Yin W Z,Li Z.The mechanism and comparison of [1]Liu C,Feng Q M,Zhang G F,et al.Effect of depressants in the flotation behavior of scheelite and calcite.Conservation Util Miner selective flotation of scheelite and calcite using oxidized paraffin Resour,2016(4):37 soap as collector.Int J Miner Process,2016,157:210 (王纪镇，印万忠，李振.白钨矿与方解石浮选行为的差异 [2]Yin W Z,Wang J Z.Effects of particle size and particle interac 及其机理研究.矿产保护与利用，2016(4)：37) tions on scheelite flotation.Trans Nonferrous Met Soc China, [14]Shen H T.Gong Z G.The mechanism and method to eliminate 2014,24(11):3682 the influence of calcite on scheelite flotation.Hunan Nonferrous [3]Rubio J,Capponi F,Rodrigues RT,et al.Enhanced flotation of Met,1996,12(2):36 sulfide fines using the emulsified oil extender technique.Int (沈慧庭，宫中桂.白钨矿浮选中方解石的影响及消除影响 Miner Process,2007,84(14):41 的方法和机理研究.湖南有色金属，1996,12(2)：36) [4]Wang D Z.New Derelopment in Flotation Theory.Beijing:Sci- [15]Chen C.Study on the Influence of Inorganic Anions on the Flota ence Press,1992 tion Behavior of Three Typical Calcium Minerals and Its Mecha (王淀佐.浮选理论的新进展.北京：科学出版社，1992) nism of Action [Dissertation].Changsha:Central South Univer [5]Qiu GZ,Hu Y H,Wang DZ.Interactions betceen Particles and sity,2011 Flotation of Fine Particles.Changsha:Central South University of (陈臣.无机阴离子对三种典型含钙盐类矿物浮选行为影响 Technology Press,1993 及作用机制[学位论文].长沙：中南大学，2011) (邱冠周，胡岳华，王淀佐颗粒间相互作用与细粒浮选.长 [16]Sun W,Chen C,Tang HH.Effects and action mechanism of 沙：中南工业大学出版社，1993) CO-on flotation rate of calcite.J China Univ Min Technol, [6]Koh P T L,Schwarz M P.CFD modeling of bubble-particle colli- 2012,41(1):48 sion rates and deficiencies in a flotation cell.Miner Eng,2003, (孙伟，陈臣，唐鸿鹄.碳酸根对方解石浮选速率的影响及 16(11):1055 机理研究.中国矿业大学学报，2012,41(1)：48) [7]Zhu Y G,Zhang G F,Feng Q M,et al.Autogenous-carrier flota- [17]Marinakis K I,Kelsall G H.The surface chemical properties of tion of fine ilmenite.Chin Nonferrous Met,2009,19(3):554 scheelite (CaWO)I.The scheelite/water interface and CawO (朱阳戈，张国范，冯其明，等.微细粒钛铁矿的自载体浮选 solubility.Colloids Surf,1987,25(24):369 中国有色金属学报.2009,19(3)：554) [18]Zhao Z W,Cao C F,Li H G.Thermodynamics on soda decom- [8]Valderrama L,Rubio J.High intensity conditioning and the carrier position of scheelite.Chin JNonferrous Met,2008,18(2):356 flotation of gold fine particles.Int J Miner Process,1998,52(4): (赵中伟，曹才放，李洪桂.碳酸钠分解白钨矿的热力学分 273 析.中国有色金属学报，2008,18(2)：356) [9]Lange A G,Skinner WM,Smart RS C.Fine:Coarse particle in- [19]Shi Q,Zhang G F.Feng Q M,et al.Effect of solution chemistry teractions and aggregation in sphalerite flotation.Miner Eng. on the flotation system of smithsonite and calcite.Int Miner 1997,10(7):681 Process,2013,119:34 [10]Atesok G,Boylu F,Celik M S.Carrier flotation for desulfuriza- [20]Feng B,Lu Y P,Weng C J.Dispersion mechanism of carbonate tion and deashing of difficult-to-float coals.Miner Eng,2001,14 on flotation system of serpentine and pyrite.J Central S Univ Sci (6):661 Technol.2016.47(4):1085 [11]Xiao J.Chen D X.Flotation of micro-fine scheelite by applying (冯博，卢毅屏，翁存建.碳酸根对蛇纹石/黄铁矿浮选体系 polystyrene as carrier.China Tungsten Ind,2015,30(6):14 的分散作用机理.中南大学学报（自然科学版），2016,47 (肖骏，陈代雄.聚苯乙烯载体浮选微细粒白钨矿研究.中 (4):1085)工程科学学报,第 41 卷,第 2 期 粒间存在引力的主要原因. 碳酸钠能够与白钨矿发 生化学反应,反应后有利于油酸钠吸附,增加白钨矿 表面疏水性,促进白钨矿颗粒间的疏水性团聚,进而 能够强化白钨矿的自载体浮选. 参 考 文 献 [1] Liu C, Feng Q M, Zhang G F, et al. Effect of depressants in the selective flotation of scheelite and calcite using oxidized paraffin soap as collector. Int J Miner Process, 2016, 157: 210 [2] Yin W Z, Wang J Z. Effects of particle size and particle interac鄄 tions on scheelite flotation. Trans Nonferrous Met Soc China, 2014, 24(11): 3682 [3] Rubio J, Capponi F, Rodrigues R T, et al. Enhanced flotation of sulfide fines using the emulsified oil extender technique. Int J Miner Process, 2007, 84(1鄄4): 41 [4] Wang D Z. New Development in Flotation Theory. Beijing: Sci鄄 ence Press, 1992 (王淀佐. 浮选理论的新进展. 北京: 科学出版社, 1992) [5] Qiu G Z, Hu Y H, Wang D Z. Interactions between Particles and Flotation of Fine Particles. Changsha: Central South University of Technology Press, 1993 (邱冠周, 胡岳华, 王淀佐. 颗粒间相互作用与细粒浮选. 长 沙: 中南工业大学出版社, 1993) [6] Koh P T L, Schwarz M P. CFD modeling of bubble鄄particle colli鄄 sion rates and deficiencies in a flotation cell. Miner Eng, 2003, 16(11): 1055 [7] Zhu Y G, Zhang G F, Feng Q M, et al. Autogenous鄄carrier flota鄄 tion of fine ilmenite. Chin J Nonferrous Met, 2009, 19(3): 554 (朱阳戈, 张国范, 冯其明, 等. 微细粒钛铁矿的自载体浮选. 中国有色金属学报, 2009, 19(3): 554) [8] Valderrama L, Rubio J. High intensity conditioning and the carrier flotation of gold fine particles. Int J Miner Process, 1998, 52(4): 273 [9] Lange A G, Skinner W M, Smart R S C. Fine: Coarse particle in鄄 teractions and aggregation in sphalerite flotation. Miner Eng, 1997, 10(7): 681 [10] Ate褘ok G, Boylu F, 覶el佾k M S. Carrier flotation for desulfuriza鄄 tion and deashing of difficult鄄to鄄float coals. Miner Eng, 2001, 14 (6): 661 [11] Xiao J, Chen D X. Flotation of micro鄄fine scheelite by applying polystyrene as carrier. China Tungsten Ind, 2015, 30(6): 14 (肖骏, 陈代雄. 聚苯乙烯载体浮选微细粒白钨矿研究. 中 国钨业, 2015, 30(6): 14) [12] Chen X Z. Study on Process and Mechanism Research of Carrier Flotation of Fine Scheelite Used with Hydrophobic Polymers [Dis鄄 sertation]. Changsha: Central South University, 2014 (陈秀珍. 疏水性聚合物对细粒级白钨矿载体浮选工艺和机 理研究 [学位论文]. 长沙: 中南大学, 2014) [13] Wang J Z, Yin W Z, Li Z. The mechanism and comparison of flotation behavior of scheelite and calcite. Conservation Util Miner Resour, 2016(4): 37 (王纪镇, 印万忠, 李振. 白钨矿与方解石浮选行为的差异 及其机理研究. 矿产保护与利用, 2016(4): 37) [14] Shen H T, Gong Z G. The mechanism and method to eliminate the influence of calcite on scheelite flotation. Hunan Nonferrous Met, 1996, 12(2): 36 (沈慧庭, 宫中桂. 白钨矿浮选中方解石的影响及消除影响 的方法和机理研究. 湖南有色金属, 1996, 12(2): 36) [15] Chen C. Study on the Influence of Inorganic Anions on the Flota鄄 tion Behavior of Three Typical Calcium Minerals and Its Mecha鄄 nism of Action [Dissertation]. Changsha: Central South Univer鄄 sity, 2011 (陈臣. 无机阴离子对三种典型含钙盐类矿物浮选行为影响 及作用机制[学位论文]. 长沙: 中南大学, 2011) [16] Sun W, Chen C, Tang H H. Effects and action mechanism of CO 2 - 3 on flotation rate of calcite. J China Univ Min Technol, 2012, 41(1): 48 (孙伟, 陈臣, 唐鸿鹄. 碳酸根对方解石浮选速率的影响及 机理研究. 中国矿业大学学报, 2012, 41(1): 48) [17] Marinakis K I, Kelsall G H. The surface chemical properties of scheelite (CaWO4 ) I. The scheelite / water interface and CaWO4 solubility. Colloids Surf, 1987, 25(2鄄4): 369 [18] Zhao Z W, Cao C F, Li H G. Thermodynamics on soda decom鄄 position of scheelite. Chin JNonferrous Met, 2008, 18(2): 356 (赵中伟, 曹才放, 李洪桂. 碳酸钠分解白钨矿的热力学分 析. 中国有色金属学报, 2008, 18(2): 356) [19] Shi Q, Zhang G F, Feng Q M, et al. Effect of solution chemistry on the flotation system of smithsonite and calcite. Int J Miner Process, 2013, 119: 34 [20] Feng B, Lu Y P, Weng C J. Dispersion mechanism of carbonate on flotation system of serpentine and pyrite. J Central S Univ Sci Technol, 2016, 47(4): 1085 (冯博, 卢毅屏, 翁存建. 碳酸根对蛇纹石/ 黄铁矿浮选体系 的分散作用机理. 中南大学学报(自然科学版), 2016, 47 (4): 1085) ·180·