The temperature dependence of reaction rates:the Arrhenius parameters,the interpretation of theparameters 2.Accounting for the rate laws Elementary reactions reactions the varation of no with time, step.the steady-state appro on,pre-equilibr riathe kinetic isotope ef Unimolecular reactions:the Lindemann-Hinshelwood mechanism,the activation energy of a composite reaction 3.Tutorial class 12 The kinetics of complex reactions (6hours) I.The Basic Requirements Chain reactions:the rate lawsof chain reactions,explosions Polymerization kinetics:stepwise polymerization,chain polymerization Homogeneous catalysis:features of homogeneous catalysis.enzymes Oscilla in Photochemistry:kinetics of photophysical and photochemical processes,complex photochemica processes II Contents 1 Chain reactions The rate lawsof chain reactions Explosion 2.Polymerization kinetics Stepwise polymerization Chain polymerization Homog Enzyme 4.Oscillating reactions Autocatalysis +Autocatalytic mechanisms ofoscillating reactions Bistability Chemical chao 5.Photochemistry Kinetics of photophysical and photochemical processes:timescales of photophysical processes, the promary quantum yield Complex photochemical pr ses:the overall quantum yield of a photochemical reaction,rate lamwsofcomplexphotochemicalreactiorns,phatosensitizaion 13 The kinetics of complex reactions (4 hours) I.The Basic Requirements Reactive encounters:collision theory,diffusion-controlled reactions,the material-balance > PDF文件使用"pdfFactory Pro”试用版本创建ww,fineprint.com,cn7 Reactions approaching equilibrium: first-order reactions close to equilibrium, relaxation methods The temperature dependence of reaction rates: the Arrhenius parameters, the interpretation of theparameters 2. Accounting for the rate laws Elementary reactions Consecutive elementary reactions: the variation of concentrations with time, the rate-determining step, the steady-state approximation, pre-equilibria, the kinetic isotope effect Unimolecular reactions: the Lindemann-Hinshelwood mechanism, the activation energy of a composite reaction 3. Tutorial class 12 The kinetics of complex reactions（6 hours） I. The Basic Requirements Chain reactions: the rate lawsof chain reactions, explosions Polymerization kinetics: stepwise polymerization, chain polymerization Homogeneous catalysis: features of homogeneous catalysis, enzymes Oscillating reactions: autocatalysis, autocatalytic mechanisms of oscillating reactions, bistability, chemical chaos Photochemistry: kinetics of photophysical and photochemical processes, complex photochemical processes II. Contents 1. Chain reactions The rate lawsof chain reactions Explosions 2. Polymerization kinetics Stepwise polymerization Chain polymerization 3. Homogeneous catalysis Features of homogeneous catalysis *Enzymes 4. Oscillating reactions Autocatalysis *Autocatalytic mechanisms of oscillating reactions Bistability Chemical chaos 5. Photochemistry Kinetics of photophysical and photochemical processes: timescales of photophysical processes, the promary quantum yield Complex photochemical processes: the overall quantum yield of a photochemical reaction, rate laws of complex photochemical reactions, photosensitization 13 The kinetics of complex reactions（4 hours） I. The Basic Requirements Reactive encounters: collision theory, diffusion-controlled reactions, the material-balance PDF 文件使用 "pdfFactory Pro" 试用版本创建 www.fineprint.com.cn