第9期 林海等：香菇培养基废料吸附矿山酸性废水中铜离子 ·1125· 松多孔，吸附后孔道变小，有众多小颗粒物出现. parameters of the biosorption step.Chem Eng J,2011. Zeta电位分析表明香菇培养基废料吸附C2+包括 174(1):9 以静电引力为主的物理吸附，还包括专性吸附，且 [11]Yu J,Zhang M C,Shen Y,et al.Thermogravimetric anal- pH值越高专性吸附越强. ysis of pyrolysis characteristics of biomass.J Shanghai Jiaotong Univ,2002,36(10):1475 (于娟，章明川，沈轶，等.生物质热解特性的热重分析.上 参考文献 海交通大学学报，2002,36(10)：1475) [12]Zhao Y C,Zhang W D.Improvement of BCO determining [1]Cui Z H.Acid mine wastewater treatment research and copper.Chin J Health Lab Technol,1995(1):47 development trend.Mod Min.2009(10):26 (赵艳春，张文德.BCO测定铜方法的改进.中国卫生检验 (崔振红.矿山酸性废水治理的研究现状及发展趋势.现代 杂志，1995(1：47) 矿业，2009(10)：26) [13]Farooq U,Kozinski J A,Khan M A,et al.Biosorption of [2 Dai Y H,Rao YZ,Wu H,et al.Study on law of mine acid heavy metal ions using wheat based biosorbents:a review wastewater and heavy metal pollution from water and soil. of the recent literature.Bioresour Technol,2010,101(14): Gold,2007,28(7):45 5043 (戴玉华，绕运章，吴红，等.矿山酸性废水与重金属污染规 14 Feng N C,Guo X Y,Liang S,et al.Biosorption of heavy 律研究.黄金，2007,28(7)：45) metals from aqueous solutions by chemically modified or- [3]Witek-Krowiak A,Szafran R G,Modelski S.Biosorption ange peel.J Hazard Mater,2011,185(1):49 of heavy metals from aqueous solutions onto peanut shell as a low-cost biosorbent.Desalination,2011,265(1-3): [15]Zhang M L.Adsorption study of Pb(II),Cu(II)and Zn(II) 126 from simulated acid mine drainage using dairy manure [4]Argun M E,Dursun S,Ozdemir C,et al.Heavy metal ad- compost.Chem Eng J,2011,172(1):361 sorption by modified oak sawdust:thermodynamics and [16 Zhang Y S,Liu W G,Zhang L,et al.Application of kinetics.J Hazard Mater,2007,141(1):77 bifunctional saccharomyces cerevisiae to remove lead(II) 5]Sciban M,Radeti B,Zarko K S,et al.Adsorption of heavy and cadmium (II)in aqueous solution.Appl Surf Sci, metals from electroplating wastewater by wood sawdust. 2011,257(23):9809 Bioresour Technol,2007,98(2):402 [17]Xiong B L.Investigation of the Adsorption Characteristic [6]Gundogdu A,Ozdes D,Duran C,et al.Biosorption of of the Bagasses to Cd2+and Cr3+in Wastewater [Dis- Pb(II)ions from aqueous solution by pine bark (Pinus sertation].Chongqing:Southwest University,2009:27 brutia Ten.).Chem Eng J,2009,153(1-3):62 (熊佰炼.甘蔗渣吸附废水中Cd2+和Cx3+的研究[学位 [7]Bansal M,Garg U,Singh D,et al.Removal of Cr(VI)from 论文刘.重庆：西南大学，2009：27) aqueous solutions using pre-consumer processing agricul- [18]Wang X S,LiZ Z,Sun C.A comparative study of removal tural waste:a case study of rice husk.J Hazard Mater, of Cu(II)from aqueous solutions by locally low-cost ma- 2009,162(1):312 terials:marine macroalgae and agricultural by-products. [8 Liu C F,Sun R C,Qin M H.Succinoylation of sugarcane Desalination,2009,235:146 bagasse under ultrasound irradiation.Bioresour Technol, [19]Tong X J,Li J Y,Yuan J H,et al.Adsorption of Cu(II) 2008,99(5):1465 on rice straw char from acidic aqueous solutions.Environ [9]Wang D H,Xiang Q B,Chen G Y.Research progress Chem,2012,31(1):64 of ecological higher value application of spent mushroom (佟雪娇，李九玉，袁金华，等.稻草炭对溶液中Cu(四)的 compost.Nonferrous Met Eng Res,2007,28(2/3):262 吸附作用.环境化学，2012,31(1)：64) (王德汉，项钱彬，陈广银.蘑菇渣资源的生态高值化利用研 [20]Tu X,Zeng G M,Chen G Q,et al.Sorption of Pb2+ 究进展.有色冶金设计与研究，2007,28(2/3)：262) in waters by culture medium waste of mushroom.China [10]Lopez-Mesas M,Navarrete E R,Carrillo F,et al.Biosep- Environ Sci,2006,26(Suppl):45 aration of Pb(II)and Cd(II)from aqueous solution using (涂响，曾光明，陈桂秋，等。香菇培养基废料吸附水体中 cork waste biomass:modeling and optimization of the Pb2+.中国环境科学，2006,26（增刊）：45)第 9 期 林 海等：香菇培养基废料吸附矿山酸性废水中铜离子 1125 ·· 松多孔，吸附后孔道变小，有众多小颗粒物出现. Zeta 电位分析表明香菇培养基废料吸附 Cu2+ 包括 以静电引力为主的物理吸附，还包括专性吸附，且 pH 值越高专性吸附越强. 参 考 文 献 [1] Cui Z H. Acid mine wastewater treatment research and development trend. Mod Min, 2009(10): 26 (崔振红. 矿山酸性废水治理的研究现状及发展趋势. 现代 矿业,2009(10): 26) [2] Dai Y H, Rao Y Z, Wu H, et al. Study on law of mine acid wastewater and heavy metal pollution from water and soil. Gold, 2007, 28(7): 45 (戴玉华, 绕运章, 吴红, 等. 矿山酸性废水与重金属污染规 律研究. 黄金, 2007, 28(7): 45) [3] Witek-Krowiak A, Szafran R G, Modelski S. Biosorption of heavy metals from aqueous solutions onto peanut shell as a low-cost biosorbent. Desalination, 2011, 265(1-3): 126 [4] Argun M E, Dursun S, Ozdemir C, et al. Heavy metal ad￾sorption by modified oak sawdust: thermodynamics and kinetics. J Hazard Mater, 2007, 141(1): 77 [5] S´ciban M, Radeti B, ˇ Zarko K ˇ S, et al. Adsorption of heavy ˇ metals from electroplating wastewater by wood sawdust. Bioresour Technol, 2007, 98(2): 402 [6] Gundogdu A, Ozdes D, Duran C, et al. Biosorption of Pb(II) ions from aqueous solution by pine bark (Pinus brutia Ten.). Chem Eng J, 2009, 153(1-3): 62 [7] Bansal M, Garg U, Singh D, et al. Removal of Cr(VI) from aqueous solutions using pre-consumer processing agricul￾tural waste: a case study of rice husk. J Hazard Mater, 2009, 162(1): 312 [8] Liu C F, Sun R C, Qin M H. Succinoylation of sugarcane bagasse under ultrasound irradiation. Bioresour Technol, 2008, 99(5): 1465 [9] Wang D H, Xiang Q B, Chen G Y. Research progress of ecological higher value application of spent mushroom compost. Nonferrous Met Eng Res, 2007, 28(2/3): 262 (王德汉, 项钱彬, 陈广银. 蘑菇渣资源的生态高值化利用研 究进展. 有色冶金设计与研究, 2007, 28(2/3): 262) [10] L´opez-Mesas M, Navarrete E R, Carrillo F, et al. Biosep￾aration of Pb(II) and Cd(II) from aqueous solution using cork waste biomass: modeling and optimization of the parameters of the biosorption step. Chem Eng J, 2011, 174(1): 9 [11] Yu J, Zhang M C, Shen Y, et al. Thermogravimetric anal￾ysis of pyrolysis characteristics of biomass. J Shanghai Jiaotong Univ, 2002, 36(10): 1475 (于娟, 章明川, 沈轶, 等. 生物质热解特性的热重分析. 上 海交通大学学报, 2002, 36(10): 1475) [12] Zhao Y C, Zhang W D. Improvement of BCO determining copper. Chin J Health Lab Technol, 1995(1): 47 (赵艳春, 张文德. BCO 测定铜方法的改进. 中国卫生检验 杂志，1995(1): 47) [13] Farooq U, Kozinski J A, Khan M A, et al. Biosorption of heavy metal ions using wheat based biosorbents: a review of the recent literature. Bioresour Technol, 2010, 101(14): 5043 [14] Feng N C, Guo X Y, Liang S, et al. Biosorption of heavy metals from aqueous solutions by chemically modified or￾ange peel. J Hazard Mater, 2011, 185(1): 49 [15] Zhang M L. Adsorption study of Pb(II), Cu(II) and Zn(II) from simulated acid mine drainage using dairy manure compost. Chem Eng J, 2011, 172(1): 361 [16] Zhang Y S, Liu W G, Zhang L, et al. Application of bifunctional saccharomyces cerevisiae to remove lead (II) and cadmium (II) in aqueous solution. Appl Surf Sci, 2011, 257(23): 9809 [17] Xiong B L. Investigation of the Adsorption Characteristic of the Bagasses to Cd2+and Cr3+ in Wastewater [Dis￾sertation]. Chongqing: Southwest University, 2009: 27 (熊佰炼. 甘蔗渣吸附废水中 Cd2+ 和 Cr3+ 的研究 [学位 论文]. 重庆：西南大学，2009：27) [18] Wang X S, Li Z Z, Sun C. A comparative study of removal of Cu(II) from aqueous solutions by locally low-cost ma￾terials: marine macroalgae and agricultural by-products. Desalination, 2009, 235: 146 [19] Tong X J, Li J Y, Yuan J H, et al. Adsorption of Cu(II) on rice straw char from acidic aqueous solutions. Environ Chem, 2012, 31(1)：64 (佟雪娇, 李九玉, 袁金华, 等. 稻草炭对溶液中 Cu(II) 的 吸附作用. 环境化学, 2012, 31(1)：64) [20] Tu X, Zeng G M, Chen G Q, et al. Sorption of Pb2+ in waters by culture medium waste of mushroom. China Environ Sci, 2006, 26(Suppl): 45 (涂响, 曾光明, 陈桂秋, 等. 香菇培养基废料吸附水体中 Pb2+. 中国环境科学, 2006, 26(增刊): 45)