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于阳等:微区电化学技术在薄液膜大气腐蚀中的应用 ·657· scanning electrochemical microscope to the examination of organic B1]Tang X,Wang J.Characteristics of micro-areal distribution of coatings on metallic substrates.Prog Organ Coat,2005,53(3): electrochemical parameters on Q235 steel under NaCl electrolyte 177 droplet.Corros Sci Prot Technol,2010,22(4):299 [17]Gabrielli C,Joiret S,Keddam M,et al.A SECM assisted EQCM (唐晓,王佳.Q235钢/NaC1液滴界面微区电化学特征参数 study of iron pitting.Electrochim Acta,2007,52 (27):7706 分布特征.腐蚀科学与防护技术,2010,22(4):299) [18]Fushimi K,Takabatake Y,Nakanishi T,et al.Microelectrode B2]Tsuru T,Tamiya K I,Nishikata A.Formation and growth of mi- techniques for corrosion research of iron.Electrochim Acta, cro-droplets during the initial stage of atmospheric corrosion. 2013,113:741 Electrochim Acta,2004,49 (17-18):2709 [9]Jonsson M,Thierry D,LeBozee N.The influence of microstruc- B3]Liu YY,Wang W,Wang Y H,et al.Electrochemical charac- ture on the corrosion behaviour of AZ91D studied by scanning teristics of 304 stainless steel under a droplet of NaCl.Chin Soc Kelvin probe force microscopy and scanning Kelvin probe.Corros Corras Prot,2012,32(1)28 Sci,2006,48(5):1193 (刘圆圆,王伟,王燕华,等.NCl液滴下304不锈钢表面电 [20]Liu W J,Cao F H.Chen A N,et al.Corrosion behaviour of 化学性质研究.中国腐蚀与防护学报,2012,32(1):28) AM60 magnesium alloys containing Ce or La under thin electro- B4]Xu R,Wang Y H,Wang J,et al.Influence of spreadability of lyte layers.Part 1:microstructural characterization and electro- seawater droplet on electrochemical characteristics of carbon chemical behaviour.Corros Sci,2010,52(2):627 steel.Chin J Mater Res,2015,29(2):95 1]Davoodi A,Esfahani Z,Sarvghad M.Microstructure and corro- (续冉,王燕华,王佳,等.海水液滴铺展因子对碳钢表面电 sion characterization of the interfacial region in dissimilar friction 化学特性的影响.材料研究学报,2015,29(2):95) stir welded AA5083 to AA7023.Corros Sci,2016,107:133 B5] Dubuisson E,Lavie F,Dalard F,et al.Study of the atmospheric [22]Stratmann M.The investigation of the corrosion properties of met- corrosion of galvanised steel in a micrometric electrolytic droplet als,covered with adsorbed electrolyte layers-a new experimental Electrochem Commun,2006,8(6):911 technique.Corros Sci,1987,27(8):869 B6]Jiang J,Wang J,Lu Y H,et al.Effect of length of gas/liquid/ 23]Zou F,Han W.Electrochemical study of metals under thin elec- solid three-phase boundary zone on cathodic and corrosion behav- trolyte layer with Kelvin probe method.Corros Sci Prot Technol, ior of metals.Electrochim Acta,2009,54(5):1426 1995,7(3):192 37]Li SX,Hihara L H.Atmospheric-corrosion electrochemistry of (邹锋,韩薇.利用Klvm探针进行金属薄液层下电化学测 NaCl droplets on carbon steel.J Electrochem Soc,2012,159 量.腐蚀科学与防护技术,1995,7(3):192) (11):C461 [24]Stratmann M,Streckel H.On the atmospheric corrosion of metals B8] Cheng Q L,Zhang W H,Tao B.Investigation of the electro- which are covered with thin electrolyte layers-I.Verification of chemical corrosion of copper under a micrometric electrolyte drop- the experimental technique.Corros Sci,1990,30(67)681 let using a threeelectrode system.Acta Phys Chim Sin,2015, [25]Stratmann M,Streckel H,Kim K T,et al.On the atmospheric 31(7):1345 corrosion of metals which are covered with thin electrolyte lay- B39]Nishikata A,Ichihara Y,Hayashi Y,et al.Influence of electro- ers-Ill.The measurement of polarisation curves on metal sur- lyte layer thickness and pH on the initial stage of the atmospheric faces which are covered by thin electrolyte layers.Corros Sci, corrosion of iron.J Electrochem Soc,1997,144(4):1244 1990,30(67):715 [40]Fan L,Xing Q,Qiu R,et al.Application of wire beam electrode 26]Wang J,Tsuru T.An investigation on oxygen reduction under e- technology in corrosion.Corros Sci Prat Technol,2015,27(5):509 lectrolyte layer using Kelvin probe reference electrode.Chin Soc (范林,邢青,邱日,等.阵列电极技术在腐蚀领域的应用进 Corros Prot,1995,15(3):180 展.腐蚀科学与防护技术,2015,27(5):509) (王佳,水流彻.使用Kelvin探头参比电极技术研究液层厚 [41]Krawiec H,Vignal V,Akid R.Numerical modelling of the elec- 度对氧还原速度的影响.中国腐蚀与防护学报,1995,15 trochemical behaviour of 316L stainless steel based upon static (3):180) and dynamic experimental microcapillary-based techniques.Elec- 227]Frankel G S,Stratmann M,Rohwerder M,et al.Potential con- ochim Acta,2008,53(16):5252 trol under thin aqueous layers using a Kelvin Probe.Corros Sci, 42]Birbilis N.Padgett B N,Buchheit R.Limitations in microelec- 2007,49(4):2021 trochemical capillary cell testing and transformation of electro- 8]Fu A Q,Tang X,Cheng Y F.Characterization of corrosion of chemical transients for acquisition of microcell impedance data. X70 pipeline steel in thin electrolyte layer under disbonded coat- Electrochim Acta,2005,50(16-7):3536 ing by scanning Kelvin probe.Corros Sci,2009,51(1):186 [43]Tan Y J,Liu T,Aung NN.Novel corrosion experiments using 129]Zhong Q D.Study of corrosion behaviour of mild steel and copper the wire beam electrode:(Ill)Measuring electrochemical corro- in thin film salt solution using the wire beam electrode.Corros sion parameters from both the metallic and electrolytic phases. Sci,2002,44(5):909 Corros Sci,2006,48(1):53 B0]Liu Z J,Wang W,Wang J,et al.Study of corrosion behavior of 44]Liu T,Tan Y J,Lin B Z M,et al.Novel corrosion experiments carbon steel under seawater film using the wire beam electrode using the wire beam electrode.(IV)Studying localised anodic method.Corros Sci,2014,80:523 dissolution of aluminium.Corros Sci,2006,48(1):67于 阳等: 微区电化学技术在薄液膜大气腐蚀中的应用 scanning electrochemical microscope to the examination of organic coatings on metallic substrates. 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