李放等：NC30Fe合金在氯化钠溶液中的微动腐蚀特性 ·1349· 活性表面原子又继续与C进行以上化学反应.随着 lead.Corros Sci,2007,49(10):3797 微动磨损的进行不断重复以上过程.表面膜剥落一生 7]Lu B T,Luo J L,Lu Y C.A mechanistic study on lead induced passivity degradation of nickel-based alloy.Electrochem Soc, 成重复进行的过程中伴随磨损和腐蚀的相互促进，这 2007,154(8):C379 样的交互作用导致氯化钠溶液中磨损量增大 [8]Lu B T,Luo J L,Lu Y C.Correlation between film rupture duc- 3结论 tility and PhSCC of alloy 800.Electrochim Acta,2008,53 (12): 4122 (1)微动磨损使NC30Fe合金表面膜破坏，体系 9]Huang J B,Wu X Q,Han E H.Influence of pH value on electro- 的自腐蚀电位显著负移，腐蚀电流增加 chemical properties of passive films formed on alloy 690 in high- (2)在氯化钠溶液中，微动腐蚀作用形成的混合 temperature aqueous environments.Corros Sci,2009,51 (12): 2976 膜层降低了摩擦系数 [10]Zhang B H,Cong W B,Yang P.Electrochemical Corrosion and (3)NC30Fe合金在纯水中的磨损机制为磨粒磨 Protection.Beijing:Chemical Industry Press,2005 损：在氯化钠溶液中的磨损机制为磨粒磨损和剥层磨 (张宝宏，丛文博，杨萍。金属电化学腐蚀与防护.北京：化 损的共同作用. 学工业出版社，2005) (4)磨损和腐蚀交互作用使得氯化钠溶液中的磨 [11]Zhang T C,Jiang XX,Li S Z.Performance ofpassivation action 损量较纯水中的磨损量显著增加. film on stainless steels during corrosive wear process.Corros Sci Prot Technol,1998,10(5):259 (张天成，姜晓霞，李诗卓.钝化膜在腐蚀磨损过程中的作 参考文献 用.腐蚀科学与防护技术，1998,10(5)：259) [12]Ye Y,Ren P D.Zhang X Y,et al.Fretting wear behavior of In- [1]Lgried M,Liskiewicz T,Neville T.Electrochemical investigation conel690/1Crl3 stainless steel in high-emperature air and nitro- of corrosion and wear interactions under fretting conditions.Wear, gen.Chin J Nonferrous Met,2013,23 (7):1900 2012,282-283:52 (叶毅，任平弟，张晓宇，等.高温大气和N2中Inconel690/ 2]Meng F J,Wang J Q,Han E H,et al.The role of TiN inclusions 1C13不锈钢的微动磨损特性.中国有色金属学报，2013,23 in stress corrosion crack initiation for alloy 690TT in high tempera- (7):1900) ture and high-pressure water.Corros Sci,2010,52(8):927 [13]Jiang J,Stack MM,Neville A.Modelling the tribo-corrosion in- B]Jo JC.Jhung M J.Flow-induced vibration and fretting-wear pre- teraction in aqueous sliding conditions.Tribol Int,2002,35 dictions of steam generator helical tubes.Nucl Eng Des,2007, (10):669 238(4):890 [14]Chen YY,Chou L B,Shih H C.Effect of solution pH on the 4]Zhang X Y,Ren PD,Zhang YF,et al.Fretting wear behavior of electrochemical polarization and stress corrosion cracking of al- Incoloy800 alloy at high temperature.Chin J Nonferrous Met, loy690 in 5M NaCl at room temperature.Mater Sci Eng,2005 2010,20(8):1545 396(1-2):129 (张晓字，任平弟，张亚非，等.ncoloy800合金的高温微动磨 [15]Meng F J,Wang J Q,Han E H,et al.Effects of scratching on 损特性.中国有色金属学报，2010,20(8)：1545) corrosion and stress corrosion cracking of alloy 690TT at 58 C [5]Zhang Z M,Wang J Q,Han E H,et al.Trans+wins stress corro- and330℃.Corros Sci,2009,51(1):2761 sion cracking behaviors of alloy 690TT in lead-containing caustic [16]Ding H Y,Dai Z D.Corrosion wear characteristic of TCllalloy solution at 330C.Nucl Eng Des,2011,241 (12)4944 in artificial sea water.Tribology,2008,28 (2):139 [6]Hwang SS,Kim H P,Lim Y S,et al.Transgranular SCC mecha- (丁红燕，戴振东.TC11钛合金在人造海水的腐蚀磨损特性 nism of thermally treated alloy600 in alkaline water containing 研究.摩擦学学报，2008,28(2)：139)李 放等: NC30Fe 合金在氯化钠溶液中的微动腐蚀特性 活性表面原子又继续与 Cl － 进行以上化学反应． 随着 微动磨损的进行不断重复以上过程． 表面膜剥落--生 成重复进行的过程中伴随磨损和腐蚀的相互促进，这 样的交互作用导致氯化钠溶液中磨损量增大． 3 结论 ( 1) 微动磨损使 NC30Fe 合金表面膜破坏，体系 的自腐蚀电位显著负移，腐蚀电流增加． ( 2) 在氯化钠溶液中，微动腐蚀作用形成的混合 膜层降低了摩擦系数． ( 3) NC30Fe 合金在纯水中的磨损机制为磨粒磨 损; 在氯化钠溶液中的磨损机制为磨粒磨损和剥层磨 损的共同作用． ( 4) 磨损和腐蚀交互作用使得氯化钠溶液中的磨 损量较纯水中的磨损量显著增加． 参 考 文 献 ［1］ Lgried M，Liskiewicz T，Neville T． Electrochemical investigation of corrosion and wear interactions under fretting conditions． Wear， 2012，282--283: 52 ［2］ Meng F J，Wang J Q，Han E H，et al． The role of TiN inclusions in stress corrosion crack initiation for alloy 690TT in high tempera￾ture and high-pressure water． Corros Sci，2010，52( 8) : 927 ［3］ Jo J C，Jhung M J． Flow-induced vibration and fretting-wear pre￾dictions of steam generator helical tubes． Nucl Eng Des，2007， 238( 4) : 890 ［4］ Zhang X Y，Ｒen P D，Zhang Y F，et al． Fretting wear behavior of Incoloy800 alloy at high temperature． Chin J Nonferrous Met， 2010，20( 8) : 1545 ( 张晓宇，任平弟，张亚非，等． Incoloy800 合金的高温微动磨 损特性． 中国有色金属学报，2010，20( 8) : 1545) ［5］ Zhang Z M，Wang J Q，Han E H，et al． Trans-twins stress corro￾sion cracking behaviors of alloy 690TT in lead-containing caustic solution at 330℃ ． Nucl Eng Des，2011，241( 12) : 4944 ［6］ Hwang S S，Kim H P，Lim Y S，et al． Transgranular SCC mecha￾nism of thermally treated alloy600 in alkaline water containing lead． Corros Sci，2007，49( 10) : 3797 ［7］ Lu B T，Luo J L，Lu Y C． A mechanistic study on lead induced passivity degradation of nickel-based alloy． J Electrochem Soc， 2007，154( 8) : C379 ［8］ Lu B T，Luo J L，Lu Y C． Correlation between film rupture duc￾tility and PbSCC of alloy 800． Electrochim Acta，2008，53( 12) : 4122 ［9］ Huang J B，Wu X Q，Han E H． Influence of pH value on electro￾chemical properties of passive films formed on alloy 690 in high￾temperature aqueous environments． Corros Sci，2009，51 ( 12) : 2976 ［10］ Zhang B H，Cong W B，Yang P． Electrochemical Corrosion and Protection． Beijing: Chemical Industry Press，2005 ( 张宝宏，丛文博，杨萍． 金属电化学腐蚀与防护． 北京: 化 学工业出版社，2005) ［11］ Zhang T C，Jiang X X，Li S Z． Performance ofpassivation action film on stainless steels during corrosive wear process． Corros Sci Prot Technol，1998，10( 5) : 259 ( 张天成，姜晓霞，李诗卓． 钝化膜在腐蚀磨损过程中的作 用． 腐蚀科学与防护技术，1998，10( 5) : 259) ［12］ Ye Y，Ｒen P D，Zhang X Y，et al． Fretting wear behavior of In￾conel690 /1Cr13 stainless steel in high-temperature air and nitro￾gen． Chin J Nonferrous Met，2013，23( 7) : 1900 ( 叶毅，任平弟，张晓宇，等． 高温大气和 N2 中 Inconel690 / 1Cr13 不锈钢的微动磨损特性． 中国有色金属学报，2013，23 ( 7) : 1900) ［13］ Jiang J，Stack M M，Neville A． Modelling the tribo-corrosion in￾teraction in aqueous sliding conditions． Tribol Int，2002，35 ( 10) : 669 ［14］ Chen Y Y，Chou L B，Shih H C． Effect of solution pH on the electrochemical polarization and stress corrosion cracking of al￾loy690 in 5M NaCl at room temperature． Mater Sci Eng，2005 396( 1--2) : 129 ［15］ Meng F J，Wang J Q，Han E H，et al． Effects of scratching on corrosion and stress corrosion cracking of alloy 690TT at 58 ℃ and 330 ℃ ． Corros Sci，2009，51( 1) : 2761 ［16］ Ding H Y，Dai Z D． Corrosion wear characteristic of TC11alloy in artificial sea water． Tribology，2008，28( 2) : 139 ( 丁红燕，戴振东． TC11 钛合金在人造海水的腐蚀磨损特性 研究． 摩擦学学报，2008，28( 2) : 139) ·1349·