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李永亮等:钒对高强度汽车大梁钢组织细化的影响 *1113· 0.5 [8]Madariaga I,Gutierrez I,Garcia de Andres C,et al.Acicular fer- ,无V钢 rite formation in a medium carbon steel with a two stage continuous 0.4 ·含V钢 cooling.Scripta Mater,1999,41(41):229 9]Avishan B,Yazdani S,Nedjad S H.Toughness variations in 03 nanostructured bainitic steels.Mater Sci Eng A,2012,548:106 [10]Xia D X.Wang X L,Li XC,et al.Properties and microstructure of third generation X90 pipeline steel.Acta Metall Sin,2013,49 (3):271 (夏佃秀,王学林,李秀程,等.X90级别第三代管线钢的力 学性能与组织特征.金属学报,2013,49(3):271) 10 20 30405060 [11]He X L,Shang C J.Yang S W,et al.Highperformance Low-car- 品体学取向差 bon Bainitic Steels.Beijing:Metallurgical Industry Press,2008 图82℃":1下V元素对实验钢品体学取向分布的影响 (贺信莱,尚成嘉,杨善武,等.高性能低碳贝氏体钢.北 Fig.8 Effect of V on the misorientation angle distributions at a cool- 京:治金工业出版社,2008) ing rate of2℃sl [12]Zhang Z H,Xue XX.Bainite transformation of low-earbon and boron-containing steel under continuous cooling.J fron Steel Res 强化效果明显 ,2014,21(3):359 03] Terzic A,Caleagnotto M,Guk S,et al.Influence of boron on 3结论 transformation behavior during continuous cooling of low alloyed steels.Mater Sci Eng A,2013,584:32 在冷速2~7℃s的范围内,实验钢可以得到以 [14]Wang TS,Yang J,Shang C J,et al.Microstructures and impact 针状铁素体+粒状贝氏体为主的显微组织.V的添加 toughness of low-alloy high-earbon steel austempered at low tem- 促进粒状贝氏体转变,细化粒状贝氏体组织,并能有效 perature.Scripta Mater,2009,61(4):434 降低M/A岛尺寸.当冷速为2℃·s时,含V钢的粒 15] Feng C,Fang H S,Bai B Z,et al.Phase transformation and 状贝氏体体积分数提高5%,维氏硬度比无V钢高出 strength-oughness of a FcBA/Bc diphase steel containing 0.02% 15HV,预测抗拉强度提高45MPa,说明V的添加可有 Nb.Acta Metall Sin,2010,46(4)473 (冯春,方鸿生,白秉哲,等.0.02%Nb空冷仿品界型铁素 效提高钢的强度.同时,V的添加使钢的大角晶界比 体/粒状贝氏体复相钢的相变及强韧性.金属学报,2010, 例也提高18.2%,大角度晶界比例的增加与粒状贝氏 46(4):473) 体团的增加和组织的细化有关.添加0.08%的V对钢 [16]Chai F.Yang C F,Zhang Y Q,et al.Effect of granular bainite 硬度和强度的影响,主要来自固溶态V对粒状贝氏体 on impact toughness of CGHAZ of ultra-ow carbon copper-bear- 相变的促进作用和显微组织的细化 ing age-hardening steel.J fron Steel Res,2005,17(1):42 (柴锋,杨才福,张永权,等.粒状贝氏体对超低碳含铜时效 参考文献 钢粗品热影响区冲击韧性的影响.钢铁研究学报,2005,17 [1]Zhao ZZ,Liu J,Zhao A M,et al.Analysis of microstructure (1):42) characteristics and precipitation behavior of automobile beam steels [17]Wei C H,Zhang J,Yang S L,et al.Microstructures and me- produced by compact strip production.ron Steel Res Int,2010. chanical properties for laser tailor welded blanks of DP590 and 17(3):56 low carbon steels.Rare Met Mater Eng,2013,42(Suppl 2):68 2]Zhao ZZ,Kang Y L,Yu H.Microstructure and mechanical prop- D8] Zhang S H,Hattori N,Emnomoto M,et al.Ferrite nucleation at erties of automobile beam steels produced by EAF-CSP process.J ceramic/austenite interfaces.IS/J Int,1996,36(10):1301 Unir Sci Technol Beijing,2006,13(6)508 [19]Li W T,Li Z C,Bai B Z.Effect of V on strength and toughness B]Yu H,Kang Y L,Zhao ZZ,et al.Study of microstructure and of low alloyed air-cooled MnSiCr bainite/martensite multiphase cementite in automobile beam steels produced by compact strip steels.At Energy Sci Technol,2010,44 (Suppl 1):359 production with flexible technologies.Mater Sci Eng A,2005,408 (李文韬,李正操,白秉哲.V对低合金MnSiCr空冷贝氏体/ (1-2):47 马氏体复相钢强韧性的影响.原子能科学技术,2010,44 4]Guan M F,Yu H.Fatigue crack growth behaviors in hot-rolled (增刊1):359) low carbon steels:a comparison between ferrite-pearlite and fer- [20 Pandit A,Murugaiyan A,Podder A S,et al.Strain induced pre- rite-bainite microstructures.Mater Sci Eng A,2013,559:875 cipitation of complex carbonitrides in Nb-V and Ti-V microal- [5]Fang HS,Yang J B,Yang ZG,et al.The mechanism of bainite loyed steels.Scripta Mater,2005,53(11)1309 transformation in steels.Scripta Mater,2002,47(3):157 1]Shanmugam S,Tanniru M,Misra R D K,et al.Microalloyed V- [6]Yang Z G,Fang H S.An overview on bainite formation in steels Nb-Ti and V steels:Part 2.Precipitation behaviour during pro- Curr Opin Solid State Mater Sci,2005,9(6):277 cessing of structural beams.Mater Sci Technol,2005,21 (2): 7]Fang HS,Feng C,Zheng Y K,et al.Creation of air-cooled Mn 165 series bainitic steels.J Iron Steel Research Int,2008,15(6):1 [22]Cheng H J,Wang F M,Pan Z B,et al.Continuous cooling李永亮等: 钒对高强度汽车大梁钢组织细化的影响 图 8 2 ℃·s - 1下 V 元素对实验钢晶体学取向分布的影响 Fig. 8 Effect of V on the misorientation angle distributions at a cool￾ing rate of 2 ℃·s - 1 强化效果明显. 3 结论 在冷速 2 ~ 7 ℃·s - 1的范围内,实验钢可以得到以 针状铁素体 + 粒状贝氏体为主的显微组织. V 的添加 促进粒状贝氏体转变,细化粒状贝氏体组织,并能有效 降低 M /A 岛尺寸. 当冷速为 2 ℃·s - 1时,含 V 钢的粒 状贝氏体体积分数提高 5% ,维氏硬度比无 V 钢高出 15 HV,预测抗拉强度提高 45 MPa,说明 V 的添加可有 效提高钢的强度. 同时,V 的添加使钢的大角晶界比 例也提高 18. 2% ,大角度晶界比例的增加与粒状贝氏 体团的增加和组织的细化有关. 添加0. 08% 的 V 对钢 硬度和强度的影响,主要来自固溶态 V 对粒状贝氏体 相变的促进作用和显微组织的细化. 参 考 文 献 [1] Zhao Z Z,Liu J,Zhao A M,et al. Analysis of microstructure characteristics and precipitation behavior of automobile beam steels produced by compact strip production. J Iron Steel Res Int,2010, 17( 3) : 56 [2] Zhao Z Z,Kang Y L,Yu H. Microstructure and mechanical prop￾erties of automobile beam steels produced by EAF-CSP process. J Univ Sci Technol Beijing,2006,13( 6) : 508 [3] Yu H,Kang Y L,Zhao Z Z,et al. Study of microstructure and cementite in automobile beam steels produced by compact strip production with flexible technologies. Mater Sci Eng A,2005,408 ( 1 - 2) : 47 [4] Guan M F,Yu H. Fatigue crack growth behaviors in hot-rolled low carbon steels: a comparison between ferrite-pearlite and fer￾rite-bainite microstructures. Mater Sci Eng A,2013,559: 875 [5] Fang H S,Yang J B,Yang Z G,et al. The mechanism of bainite transformation in steels. Scripta Mater,2002,47( 3) : 157 [6] Yang Z G,Fang H S. An overview on bainite formation in steels. Curr Opin Solid State Mater Sci,2005,9( 6) : 277 [7] Fang H S,Feng C,Zheng Y K,et al. Creation of air-cooled Mn series bainitic steels. J Iron Steel Research Int,2008,15( 6) : 1 [8] Madariaga I,Gutierrez I,García de Andrés C,et al. Acicular fer￾rite formation in a medium carbon steel with a two stage continuous cooling. Scripta Mater,1999,41( 41) : 229 [9] Avishan B,Yazdani S,Nedjad S H. Toughness variations in nanostructured bainitic steels. Mater Sci Eng A,2012,548: 106 [10] Xia D X,Wang X L,Li X C,et al. Properties and microstructure of third generation X90 pipeline steel. Acta Metall Sin,2013,49 ( 3) : 271 ( 夏佃秀,王学林,李秀程,等. X90 级别第三代管线钢的力 学性能与组织特征. 金属学报,2013,49( 3) : 271) [11] He X L,Shang C J,Yang S W,et al. High-performance Low-car￾bon Bainitic Steels. Beijing: Metallurgical Industry Press,2008 ( 贺信莱,尚成嘉,杨善武,等. 高性能低碳贝氏体钢. 北 京: 冶金工业出版社,2008) [12] Zhang Z H,Xue X X. Bainite transformation of low-carbon and boron-containing steel under continuous cooling. J Iron Steel Res Int,2014,21( 3) : 359 [13] Terzic A,Calcagnotto M,Guk S,et al. Influence of boron on transformation behavior during continuous cooling of low alloyed steels. Mater Sci Eng A,2013,584: 32 [14] Wang T S,Yang J,Shang C J,et al. Microstructures and impact toughness of low-alloy high-carbon steel austempered at low tem￾perature. Scripta Mater,2009,61( 4) : 434 [15] Feng C,Fang H S,Bai B Z,et al. Phase transformation and strength-toughness of a FGBA /BG diphase steel containing 0. 02% Nb. Acta Metall Sin,2010,46( 4) : 473 ( 冯春,方鸿生,白秉哲,等. 0. 02% Nb 空冷仿晶界型铁素 体/粒状贝氏体复相钢的相变及强韧性. 金属学报,2010, 46( 4) : 473) [16] Chai F,Yang C F,Zhang Y Q,et al. Effect of granular bainite on impact toughness of CGHAZ of ultra-low carbon copper-bear￾ing age-hardening steel. J Iron Steel Res,2005,17( 1) : 42 ( 柴锋,杨才福,张永权,等. 粒状贝氏体对超低碳含铜时效 钢粗晶热影响区冲击韧性的影响. 钢铁研究学报,2005,17 ( 1) : 42) [17] Wei C H,Zhang J,Yang S L,et al. Microstructures and me￾chanical properties for laser tailor welded blanks of DP590 and low carbon steels. Rare Met Mater Eng,2013,42( Suppl 2) : 68 [18] Zhang S H,Hattori N,Emnomoto M,et al. Ferrite nucleation at ceramic /austenite interfaces. ISIJ Int,1996,36( 10) : 1301 [19] Li W T,Li Z C,Bai B Z. Effect of V on strength and toughness of low alloyed air-cooled MnSiCr bainite /martensite multiphase steels. At Energy Sci Technol,2010,44( Suppl 1) : 359 ( 李文韬,李正操,白秉哲. V 对低合金 MnSiCr 空冷贝氏体/ 马氏体复相钢强韧性的影响. 原子能科学技术,2010,44 ( 增刊 1) : 359) [20] Pandit A,Murugaiyan A,Podder A S,et al. Strain induced pre￾cipitation of complex carbonitrides in Nb-V and Ti-V microal￾loyed steels. Scripta Mater,2005,53( 11) : 1309 [21] Shanmugam S,Tanniru M,Misra R D K,et al. Microalloyed V￾Nb-Ti and V steels: Part 2. Precipitation behaviour during pro￾cessing of structural beams. Mater Sci Technol,2005,21 ( 2) : 165 [22] Cheng H J,Wang F M,Pan Z B,et al. Continuous cooling · 3111 ·
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