APPENDIX A 781 A-6.(a) CH CHa CH,OH NH, (K<1) (b) CHCH A-7.(a) Three (b, c)CH, CCH, CHCH, CH,CHCHCHCH3 CH_CHCH_ CHCH3 (Least stable) CH3 A-8. CH, CCH3 Cl, CH.CCHCI HCl A-10.△H 57kJ(-13.5kcal) A-ll.(a)(CH3)3C +HBr (CH3)3C一 (CH)CCOH H,O+(CH3)C CH3)C-Br (c) Water is displaced directly from the oxonium ion of 1-butanol by bromide ion. a pri- mary carbocation is not involved CH CH, CH, CH,TOH H,O CH, CH,CH,CH, Br A-12.(a) 3-Methyl-3-pentanol (c) Fluorine(F2) (e) (b) KOC(CH3)3 (d) Ethyl radical, CH3CH B-1.(e)B-2.(c)B-3.(b)B-4.(c) B-5.(e)B-6.(c)B-7.(d)B-8.(a) B-9.(c)B-10.(d)B-11.(c)B-12.(e) B-13.(a)B-14.(c)B-15.(c)B-16.(c) Back Forward Main Menu TOC Study Guide Toc Student OLC MHHE WebsiteAPPENDIX A 781 A-6. (a) (b) A-7. (a) Three (b, c) A-8. A-9. A-10. H°  57 kJ (13.5 kcal) A-11. (a) (b) (c) Water is displaced directly from the oxonium ion of 1-butanol by bromide ion. A pri￾mary carbocation is not involved. A-12. (a) 3-Methyl-3-pentanol (c) Fluorine (F2) (e) Cl2 (b) KOC(CH3)3 (d) Ethyl radical, CH3C . H2 B-1. (e) B-2. (c) B-3. (b) B-4. (c) B-5. (e) B-6. (c) B-7. (d) B-8. (a) B-9. (c) B-10. (d) B-11. (c) B-12. (e) B-13. (a) B-14. (c) B-15. (c) B-16. (c) CH3CH2CH2CH2 OH H2O CH3CH2CH2CH2Br 2 Br C H3C H3C CH3 O H H   (CH3)3C Br (CH3)3C Br (CH3)3C (CH3)3C OH2 H2O (CH3)3C (CH3) OH H Br 3C Br OH2 Br2 Br Br Br HBr CH3CCH3 Cl2 CH3 CH3 CH3CCH2Cl HCl CH3 CH3 CH2CHCH2CHCH3 CH3 CH3 (Least stable) CH3CHCHCHCH3 CH3 CH3 CH3CCH2CHCH3 CH3 CH3 (Most stable) CH3CH2O NH H 2   CH3CH2O NH3 CH3CH2OH NH2 (K  1) Stronger base Stronger acid Conjugate acid Conjugate base Back Forward Main Menu TOC Study Guide TOC Student OLC MHHE Website