屈亚松等：Zn-In LDHs在Zn-Ni二次电池中的电化学性能 ·1629 叶红外光谱(FT-IR)、X射线衍射(XRD)和扫描电 及其在锌镍电池中的应用.无机化学学报，2018,33(9)：1573) 镜(SEM)分析得出，合成的Zn-In LDHs大部分呈 [9]Wen R J,Yang Z H,Fan X M,et al.Electrochemical performances 现出了六边形片状结构，这也是水滑石类化合物 of ZnO with different morphology as anodic materials for Ni/Zn 的特性结构 secondary batteries.Electrochim Acta,2012,83:376 [10]Luo Z G,Sang S B,Wu Q M,et al.A conductive additive for Zn (2)利用电化学工作站，对制备的锌电极进行 electrodes in secondary Ni/Zn batteries:The magneli phase 循环伏安曲线分析得出，Zn-In LDHs电极相较于 titanium sub-oxides conductive ceramic Ti O2 ECS Zn-A1LDHs电极和ZnO电极循环可逆性更好， Electrochem Lett,2012,2(2):A21 Tafel曲线分析得到，Zn-In LDHs电极的腐蚀电位 [11]Long W,Yang Z H,Liao Q F.The application of ZnO coated with 更正，腐蚀电流也更小，即Zn-In LDHs电极有更 carbon for Ni-Zn secondary battery.App/Chem Ind,2013,42(6): 强的耐腐蚀性能 983 (3)充放电性能测试结果分析表明：Zn-In (龙伟，杨占红，廖庆丰，碳包覆氧化锌材料在锌镍二次电池中 LDHs电极的充电平台电压更低，放电平台电压更 的应用研究.应用化工，2013,42(6)：983) 高，经过100次充放电循环之后，Zn-In LDHs电 [12]Yu S L,Yu X H,Lu X,et al.Study on problems and solutions of zinc electrode for zinc-nickel battery.Chin Power Sources,2018, 极的循环保持率高于Zn-Al LDHs电极和ZnO电 42(10):1585 极，其循环保持率达到了92.25%. (俞双林，俞小花，吕祥，等.锌镍电池负极存在的问题及解决途 参考文献 径的研究.电源技术，2018,42(10)：1585) [13]Shi X J,Wang Y H,Zhang Z S.Research progress in calcium [1]Guo B K.Li X H,Yang S Q.Principle and Manufacturing zincate material for Zn-Ni secondary battery.Chin Labat Man, Technology of Chemical Power Battery.Changsha:Central South 2019.56(3):114 University Press,2009 (施学金，汪云华，张战胜.锌镍二次电池用锌酸钙材料的研究 (郭炳焜，李新海，杨松青.化学电源：电池原理及制造技术.长 进展蓄电池.2019.56(3)：114) 沙：中南大学出版社，2009) [14]Li Y G,Yu S L,Yu X H,et al.Preparation of calcium zincate with [2]He H M,Yang Z H,Chi WW,et al.The performance of indium different morphologies and their applications in Zn-Ni battery. oxide coated zinc oxide for Zn-Ni battery.Battery Bimonthhy, Mod Chem Ind,2018,38(5):81 2011,41(2):101 (李永刚，俞双林，俞小花，等.不同形貌锌酸钙的制备及其在锌 (贺红梅，杨占红，迟伟伟，等.锌镍电池用包覆氧化钢的氧化锌 镍电池中的应用研究.现代化工，2018,38(5)：81) 的性能.电池，2011,41(2)：101) [15]Xu J,Pan Y M,Chen Q,et al.Research progress of preparation [3] Yuan Y F,Tu J P,Guo S Y,et al.Characteristics and and applications of layered double hydroxides.China Plast,2016. electrochemical performance of Ni-coated Zno prepared by an 30(4):23 electroless plating proces.App/SufSci,2008,254(16):5080 (徐坚，潘玉妹，陈强，等.水滑石的制备及应用进展.中国塑料， [4]Zhu L Q,Zhang H,Li W P,et al.Investigation of zinc powder 2016,30(4):23) modified by ultrasonic impregnation of rare earth lanthanum.Appl [16]Debecker DP,Gaigneaux E M,Busca G.Exploring.tuning.and Surf Sci,2007,253(24):9443 exploiting the basicity of hydrotalcites for applications in [5]Yuan Y F.Tu J P.Wu H M.et al.Influence of surface heterogeneous catalysis.Chemistry,2009,15(16):3920 modification with SnO(OH)on electrochemical performance of [17]Mokhtar M,Saleh T S,Basahel S N.Mg-Al hydrotalcites as ZnO in Zn/Ni secondary cells.J Power Sources,2007,165(2): efficient catalysts for aza-Michael addition reaction:A green 905 protocol.J Mol Catal 4 Chem,2012,353-354:122 [6]Wu J Z,Tu J P,Yuan Y F,et al.Ag-modification improving the [18]Fan X M,Yang Z H,Long W,et al.The preparation and electrochemical performance of ZnO anode for Ni/Zn secondary electrochemical performance of In(OH),-coated Zn-Al-hydro- batteries.JAlloys Compd,2009,479(1-2):624 talcite as anode material for Zn-Ni secondary cell.Electrochim [7]Zeng D Q.Yang Z H,Wang S W.et al.Preparation and 4ca,2013,92:365 electrochemical performance of In-doped ZnO as anode material [19]Fan X M,Yang Z H.Wen R J,et al.The application of for Ni-Zn secondary cells.Electrochim Acta,2011,56(11):4075 Zn -Al -hydrotalcite as a novel anodic material for Ni-Zn [8]Yu S L,Yu X H,Lu X,et al.SnO(OH)4 coated on ZnO surface: secondary cells.J Power Sources,2013,224:80 preparation and application in zinc-nickel secondary battery. [20]Xie X E,Yang Z H,Feng Z B,et al.Electrochemical properties of Inorg Chem,2018,33(9):1573 ZnO added with Zn-Al-hydrotalcites as anode materials for (俞双林，俞小花，吕祥，等.氧化锌表面包覆SsO(OH的制备 Zinc/Nickel alkaline secondary batteries.Electrochim Acta,2015,叶红外光谱（FT-IR）、X 射线衍射（XRD）和扫描电 镜（SEM）分析得出，合成的 Zn‒In LDHs 大部分呈 现出了六边形片状结构，这也是水滑石类化合物 的特性结构. （2）利用电化学工作站，对制备的锌电极进行 循环伏安曲线分析得出，Zn‒In LDHs 电极相较于 Zn–Al LDHs 电极和 ZnO 电极循环可逆性更好， Tafel 曲线分析得到，Zn‒In LDHs 电极的腐蚀电位 更正，腐蚀电流也更小，即 Zn‒In LDHs 电极有更 强的耐腐蚀性能. （ 3）充放电性能测试结果分析表明 ： Zn‒In LDHs 电极的充电平台电压更低，放电平台电压更 高，经过 100 次充放电循环之后，Zn‒In LDHs 电 极的循环保持率高于 Zn–Al LDHs 电极和 ZnO 电 极，其循环保持率达到了 92.25%. 参    考    文    献 Guo B K, Li X H, Yang S Q. Principle and Manufacturing Technology of Chemical Power Battery. Changsha: Central South University Press, 2009 （郭炳焜, 李新海, 杨松青. 化学电源: 电池原理及制造技术. 长 沙: 中南大学出版社, 2009） [1] He H M, Yang Z H, Chi W W, et al. The performance of indium oxide coated zinc oxide for Zn ‒Ni battery. Battery Bimonthly, 2011, 41（2）: 101 （贺红梅, 杨占红, 迟伟伟, 等. 锌镍电池用包覆氧化铟的氧化锌 的性能. 电池, 2011, 41（2）：101） [2] Yuan Y F, Tu J P, Guo S Y, et al. Characteristics and electrochemical performance of Ni-coated ZnO prepared by an electroless plating proces. Appl Surf Sci, 2008, 254（16）: 5080 [3] Zhu L Q, Zhang H, Li W P, et al. Investigation of zinc powder modified by ultrasonic impregnation of rare earth lanthanum. Appl Surf Sci, 2007, 253（24）: 9443 [4] Yuan Y F, Tu J P, Wu H M, et al. Influence of surface modification with Sn6O4 (OH)4 on electrochemical performance of ZnO in Zn/Ni secondary cells. J Power Sources, 2007, 165（2）: 905 [5] Wu J Z, Tu J P, Yuan Y F, et al. Ag-modification improving the electrochemical performance of ZnO anode for Ni/Zn secondary batteries. J Alloys Compd, 2009, 479（1-2）: 624 [6] Zeng D Q, Yang Z H, Wang S W, et al. Preparation and electrochemical performance of In-doped ZnO as anode material for Ni–Zn secondary cells. Electrochim Acta, 2011, 56（11）: 4075 [7] Yu S L, Yu X H, Lü X, et al. Sn6O4 (OH)4 coated on ZnO surface: preparation and application in zinc-nickel secondary battery. J Inorg Chem, 2018, 33（9）: 1573 （俞双林, 俞小花, 吕祥, 等. 氧化锌表面包覆Sn6O4 (OH)4的制备 [8] 及其在锌镍电池中的应用. 无机化学学报, 2018, 33（9）：1573） Wen R J, Yang Z H, Fan X M, et al. Electrochemical performances of ZnO with different morphology as anodic materials for Ni/Zn secondary batteries. Electrochim Acta, 2012, 83: 376 [9] Luo Z G, Sang S B, Wu Q M, et al. A conductive additive for Zn electrodes in secondary Ni/Zn batteries: The magneli phase titanium sub-oxides conductive ceramic TinO2n−1. ECS Electrochem Lett, 2012, 2（2）: A21 [10] Long W, Yang Z H, Liao Q F. The application of ZnO coated with carbon for Ni‒Zn secondary battery. Appl Chem Ind, 2013, 42（6）: 983 （龙伟, 杨占红, 廖庆丰. 碳包覆氧化锌材料在锌镍二次电池中 的应用研究. 应用化工, 2013, 42（6）：983） [11] Yu S L, Yu X H, Lü X, et al. Study on problems and solutions of zinc electrode for zinc-nickel battery. Chin J Power Sources, 2018, 42（10）: 1585 （俞双林, 俞小花, 吕祥, 等. 锌镍电池负极存在的问题及解决途 径的研究. 电源技术, 2018, 42（10）：1585） [12] Shi X J, Wang Y H, Zhang Z S. Research progress in calcium zincate material for Zn –Ni secondary battery. Chin Labat Man, 2019, 56（3）: 114 （施学金, 汪云华, 张战胜. 锌镍二次电池用锌酸钙材料的研究 进展. 蓄电池, 2019, 56（3）：114） [13] Li Y G, Yu S L, Yu X H, et al. Preparation of calcium zincate with different morphologies and their applications in Zn –Ni battery. Mod Chem Ind, 2018, 38（5）: 81 （李永刚, 俞双林, 俞小花, 等. 不同形貌锌酸钙的制备及其在锌 镍电池中的应用研究. 现代化工, 2018, 38（5）：81） [14] Xu J, Pan Y M, Chen Q, et al. Research progress of preparation and applications of layered double hydroxides. China Plast, 2016, 30（4）: 23 （徐坚, 潘玉妹, 陈强, 等. 水滑石的制备及应用进展. 中国塑料, 2016, 30（4）：23） [15] Debecker D P, Gaigneaux E M, Busca G. Exploring, tuning, and exploiting the basicity of hydrotalcites for applications in heterogeneous catalysis. Chemistry, 2009, 15（16）: 3920 [16] Mokhtar M, Saleh T S, Basahel S N. Mg –Al hydrotalcites as efficient catalysts for aza-Michael addition reaction: A green protocol. J Mol Catal A Chem, 2012, 353-354: 122 [17] Fan X M, Yang Z H, Long W, et al. The preparation and electrochemical performance of In(OH)3 -coated Zn ‒Al ‒hydro￾talcite as anode material for Zn –Ni secondary cell. Electrochim Acta, 2013, 92: 365 [18] Fan X M, Yang Z H, Wen R J, et al. The application of Zn –Al ‒hydrotalcite as a novel anodic material for Ni –Zn secondary cells. J Power Sources, 2013, 224: 80 [19] Xie X E, Yang Z H, Feng Z B, et al. Electrochemical properties of ZnO added with Zn ‒Al ‒hydrotalcites as anode materials for Zinc/Nickel alkaline secondary batteries. Electrochim Acta, 2015, [20] 屈亚松等： Zn‒In LDHs 在 Zn‒Ni 二次电池中的电化学性能 · 1629 ·