杜晨曦等：铁基非晶合金的辐照性能 ·1377· 在以往的研究中，铁基非晶合金的辐照性能研究 products.J Magn Magn Mater,2003,254-255:532 主要关注其结构和磁性能的变化，以及通过优化铁基 [10]Fukumoto M,Ohtsuka Y,Ueda Y,et al.Blister formation on 非晶的结构进而改善其性能9,24,9,5，).然而随着核 tungsten damaged by high energy particle irradiation.INucl Ma- 能的快速发展，增加了对抗辐照材料的需求，同时对材 ter,2008,375(2):224 [11] Khripunov BI,Brukhanov A N,Chugunov OK.et al.Evidence 料的抗辐照性能也提出了更高的要求.铁基非晶合金 of radiation damage impact on material erosion in plasma environ- 由于其优异的抗辐照性能也成为重要候选材料之一. ment.J Nucl Mater,2009,390-391:921 因此，不仅要评价铁基非晶合金的抗辐照性能，辐照后 [12]Rivera A,Valles G.Caturla MJ,et al.Effect of ion flux on he- 的综合性能评价也显得尤为重要，这也将是后续铁基 lium retention in helium-iradiated tungsten.Nucl Instrum Meth- 非晶合金辐照性能研究的重要方向. ods Phys Res Sect B,2013,303:81 [13]Franz W T,Steck G,Kramer JJ,et al.Radiation effects in 3结论 amorphous Fe,Niso-PB.J Appl Phys,1981,52(3):1883 [14]Kuzmanm E.Spirov I N.Mossbauer study of amorphous alloys 由于铁基非晶合金优异的性能和潜在的应用前 irradiated with energetic heavy ions.Hyperfine Interact,1986, 景，针对铁基非晶合金的辐照性能已开展了广泛的研 29(14):1175 究.辐照既是试验铁基非晶合金性能的一种手段，也 [15]Bhagwat A,Kurup M B,Prasad K G,et al.Investigations of 是优化铁基非晶合金性能的有效方法.铁基非晶合金 Ar implantation and proton irradiation of amorphous Fe Nio B2o samples by Mossbauer techniques.Hyperfine Interact,1986, 因合金成分和辐照条件的不同而呈现出不同的结构和 29(14):1167 性能变化.目前，已初步建立了辐照与铁基非晶合金 [16]Schimansky F P,Gerling R,Wagner R,et al.Irradiation-in- 微观结构、性能之间的关系，铁基非晶辐照研究主要关 duced defects in amorphous FeNiP Mater Sci Eng,1988, 注辐照对其微观结构的影响，以及铁基非晶合金辐照 97:173 机理研究，但还没有建立辐照与铁基非晶合金力学和 [17]Skorvinek I,Zentko A.Effects of neutron irradiation on magnet- 腐蚀等性能之间的关系.后续研究工作应着重关注铁 ic properties of FeB amorphous alloys.Phys Status Solidi A. 1987,99(1):275 基非晶合金辐照后在各种介质环境的反应机制、性能 [18]Kopcansky P.The electrical resistivity of the amorphous Fe-Ni- 稳定性等研究，只有综合考虑各种因素，才有助于开发 B system after neutron irradiation-model of a spinodal decomposi- 高性能铁基非晶合金. tion.Phys Status Solidi A,1987,100(2):K159 [19]Skorvanek I,Idzikowski B.Zentko A,et al.Influence of neu- 参考文献 tron irradiation on the properties of FeNiCrMoSiB amorphous al- [1]Telford M.The case for bulk metallic glass.Mater Today,2004, loys.Phys Status Solidi A,1988.108(2):747 7(3):36 [20]Brown R D,Cost J R,Stanley JT.Effects of neutron irradiation [2]Schroers J.Processing of bulk metallic glass.Adr Mater,2010, on magnetic permeability of amorphous and crystalline magnetic 22(14):1566 alloys.J Appl Phys,1984,55(6):1754 [3]Wang W H.Correlation between relaxations and plastic deforma- [21]Hajko V,Zentko A,Timko M,et al.Isotopic effect in neutron- tion,and elastic model of flow in metallic glasses and glass-form- irradiated Fe Ni Bo alloys.Phys Status Solidi A,1984.82 ing liquids.J Appl Phys,2011,110(5):053521-1 (2):K159 [4]Barnard HS,Hartwig Z S,Olynyk G M,et al.Assessing the fea- [22]Grundy P,Jones G,Parker S.Property changes in neutron irra- sibility of a high-temperature,helium-cooled vacuum vessel and diated magnetic glasses.IEEE Trans Magn,1983,19 (5): first wall for the Vulcan tokamak conceptual design.Fusion Eng 1913 Des,2012,87(3):248 [23]Gerling R,Wagner R.Properties of in-core reactor-irradiated [5]Luo W D,Yang B,Chen G L.Effect of Ar'ion irradiation on the amorphous Feao Nig B2o.J Nucl Mater,1982,107(2-3):311 microstructure and properties of Zr-Cu-Fe-Al bulk metallic [24]Li FS,Sun JJ,Xue D S.Fast neutron irradiation effect study of glass.Scripta Mater,2011,64(7):625 amorphous alloy FeNiMoSiB.Lanzhou Unir Nat Sci,1993,29 [6]Wang B,Mei XX,Hou WJ,et al.Behavior of high resistance to (4):82 He2induced irradiation damage in metallic glass.Nucl Instrum (李发伸，孙吉军，薛德胜.非品合金FeNiMoSiB的快中子 Methods Phys Res Sect B,2013,312:84 辐照效应的研究.兰州大学学报（自然科学版），1993,29 [7]Arai K,Zhang W,Jia F,et al.Synthesis and thermal stability of (4):82) new Ni-based bulk glassy alloy with excellent mechanical proper- [25]Gerling R,Wagner R.Two-stage structural relaxation of amor- ties.Mater Trans,2006,47(9):2358 phous Feao Ni B2o Scripta Metall,1983.17(9):1129 [8]Mogilny G S,Shanina B D,Maslov VV,et al.Structure and [26]Audouard A,Jousset JC.Dural J.30-K fast neutron and fission magnetic anisotropy of rapidly quenched FeSiB ribbons.Non. fragment irradiations of two Fe-B type amorphous alloys.Radiat Cryst Solids,2011,357(16-17):3237 Ef,1980,50(1):9 [9]Uriarte J L,Yavari A R,Surinach S,et al.Properties of FeNiB- [27]Farmer JC,Choi J S,Saw C K,et al.Corrosion resistance of based metallic glasses with primary BCC and FCC crystallization amorphous Fe.Cr.7Mn Mo.4 W16Bi5.2C3.s Si24 coating-杜晨曦等: 铁基非晶合金的辐照性能 在以往的研究中,铁基非晶合金的辐照性能研究 主要关注其结构和磁性能的变化,以及通过优化铁基 非晶的结构进而改善其性能[19,24,39,55,87] . 然而随着核 能的快速发展,增加了对抗辐照材料的需求,同时对材 料的抗辐照性能也提出了更高的要求. 铁基非晶合金 由于其优异的抗辐照性能也成为重要候选材料之一. 因此,不仅要评价铁基非晶合金的抗辐照性能,辐照后 的综合性能评价也显得尤为重要,这也将是后续铁基 非晶合金辐照性能研究的重要方向. 3 结论 由于铁基非晶合金优异的性能和潜在的应用前 景,针对铁基非晶合金的辐照性能已开展了广泛的研 究. 辐照既是试验铁基非晶合金性能的一种手段,也 是优化铁基非晶合金性能的有效方法. 铁基非晶合金 因合金成分和辐照条件的不同而呈现出不同的结构和 性能变化. 目前,已初步建立了辐照与铁基非晶合金 微观结构、性能之间的关系,铁基非晶辐照研究主要关 注辐照对其微观结构的影响,以及铁基非晶合金辐照 机理研究,但还没有建立辐照与铁基非晶合金力学和 腐蚀等性能之间的关系. 后续研究工作应着重关注铁 基非晶合金辐照后在各种介质环境的反应机制、性能 稳定性等研究,只有综合考虑各种因素,才有助于开发 高性能铁基非晶合金. 参 考 文 献 [1] Telford M. The case for bulk metallic glass. Mater Today, 2004, 7(3): 36 [2] Schroers J. Processing of bulk metallic glass. Adv Mater, 2010, 22(14): 1566 [3] Wang W H. Correlation between relaxations and plastic deforma鄄 tion, and elastic model of flow in metallic glasses and glass鄄form鄄 ing liquids. J Appl Phys, 2011, 110(5): 053521鄄1 [4] Barnard H S, Hartwig Z S, Olynyk G M, et al. Assessing the fea鄄 sibility of a high鄄temperature, helium鄄cooled vacuum vessel and first wall for the Vulcan tokamak conceptual design. Fusion Eng Des, 2012, 87(3): 248 [5] Luo W D, Yang B, Chen G L. Effect of Ar + ion irradiation on the microstructure and properties of Zr鄄鄄 Cu鄄鄄 Fe鄄鄄 Al bulk metallic glass. Scripta Mater, 2011, 64(7): 625 [6] Wang B, Mei X X, Hou W J, et al. Behavior of high resistance to He 2 + induced irradiation damage in metallic glass. Nucl Instrum Methods Phys Res Sect B, 2013, 312: 84 [7] Arai K, Zhang W, Jia F, et al. Synthesis and thermal stability of new Ni鄄based bulk glassy alloy with excellent mechanical proper鄄 ties. Mater Trans, 2006, 47(9): 2358 [8] Mogilny G S, Shanina B D, Maslov V V, et al. Structure and magnetic anisotropy of rapidly quenched FeSiB ribbons. J Non鄄 Cryst Solids, 2011, 357(16鄄17): 3237 [9] Uriarte J L, Yavari A R, Surinach S, et al. Properties of FeNiB鄄 based metallic glasses with primary BCC and FCC crystallization products. J Magn Magn Mater, 2003, 254鄄255: 532 [10] Fukumoto M, Ohtsuka Y, Ueda Y, et al. Blister formation on tungsten damaged by high energy particle irradiation. J Nucl Ma鄄 ter, 2008, 375(2): 224 [11] Khripunov B I, Brukhanov A N, Chugunov O K, et al. Evidence of radiation damage impact on material erosion in plasma environ鄄 ment. J Nucl Mater, 2009, 390鄄391: 921 [12] Rivera A, Valles G, Caturla M J, et al. Effect of ion flux on he鄄 lium retention in helium鄄irradiated tungsten. Nucl Instrum Meth鄄 ods Phys Res Sect B, 2013, 303: 81 [13] Franz W T, Steck G, Kramer J J, et al. Radiation effects in amorphous FexNi80 - xP14B6 . J Appl Phys, 1981, 52(3): 1883 [14] Kuzmanm E, Spirov I N. M觟ssbauer study of amorphous alloys irradiated with energetic heavy ions. Hyperfine Interact, 1986, 29(1鄄4): 1175 [15] Bhagwat A, Kurup M B, Prasad K G, et al. Investigations of Ar + implantation and proton irradiation of amorphous Fe40 Ni40 B20 samples by M觟ssbauer techniques. Hyperfine Interact, 1986, 29(1鄄4): 1167 [16] Schimansky F P, Gerling R, Wagner R, et al. Irradiation鄄in鄄 duced defects in amorphous Fe40Ni40 P20 . Mater Sci Eng, 1988, 97: 173 [17] 譒korv觃nek I, Zentko A. Effects of neutron irradiation on magnet鄄 ic properties of Fe80B20 amorphous alloys. Phys Status Solidi A, 1987, 99(1): 275 [18] Kopc姚ansk伥 P. The electrical resistivity of the amorphous Fe鄄鄄Ni鄄鄄 B system after neutron irradiation鄄model of a spinodal decomposi鄄 tion. Phys Status Solidi A, 1987, 100(2): K159 [19] 譒korv觃nek I, Idzikowski B, Zentko A, et al. Influence of neu鄄 tron irradiation on the properties of FeNiCrMoSiB amorphous al鄄 loys. Phys Status Solidi A, 1988, 108(2): 747 [20] Brown R D, Cost J R, Stanley J T. Effects of neutron irradiation on magnetic permeability of amorphous and crystalline magnetic alloys. J Appl Phys, 1984, 55(6): 1754 [21] Hajko V, Zentko A, Timko M, et al. Isotopic effect in neutron鄄 irradiated Fe40 Ni40 B20 alloys. Phys Status Solidi A, 1984, 82 (2): K159 [22] Grundy P, Jones G, Parker S. Property changes in neutron irra鄄 diated magnetic glasses. IEEE Trans Magn, 1983, 19 ( 5 ): 1913 [23] Gerling R, Wagner R. Properties of in鄄core reactor鄄irradiated amorphous Fe40Ni40B20 . J Nucl Mater, 1982, 107(2鄄3): 311 [24] Li F S, Sun J J, Xue D S. Fast neutron irradiation effect study of amorphous alloy FeNiMoSiB. J Lanzhou Univ Nat Sci, 1993, 29 (4): 82 (李发伸, 孙吉军, 薛德胜. 非晶合金 FeNiMoSiB 的快中子 辐照效应的研究. 兰州大学学报(自然科学版), 1993, 29 (4): 82) [25] Gerling R, Wagner R. Two鄄stage structural relaxation of amor鄄 phous Fe40Ni40B20 . Scripta Metall, 1983, 17(9): 1129 [26] Audouard A, Jousset J C, Dural J. 30鄄K fast neutron and fission fragment irradiations of two Fe鄄B type amorphous alloys. Radiat Eff, 1980, 50(1): 9 [27] Farmer J C, Choi J S, Saw C K, et al. Corrosion resistance of amorphous Fe49郾 7Cr17郾 7 Mn1郾 9 Mo7郾 4 W1郾 6 B15郾 2 C3郾 8 Si2郾 4 coating— ·1377·