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·1136 工程科学学报,第37卷,第9期 贫区 第二相 样品表面 浮凸 MC、N 图10表面浮凸产生机理示意图 Fig.10 lllustration of surface relief formation 奥氏体品界 150m 150m 图11不同钢种的铁素体分布.(a)A钢种:(b)B钢种 Fig.11 Ferrite distribution of experimental steels:(a)steel A:(b)steel B 存在N(C,N)时,先共析铁素体主要沿晶界分布(见 temperature ductility of continuously cast low carbon Nb containing 图11(b). steel slab.ISI/Int,1995,35(1)34 4]Luo H,Karjalainen L P,Porter D A,et al.The influence of Ti on 3结论 the hot ductility of Nb-bearing steels in simulated continuous cast- ing process..1S0t,2002,43(3):273 (1)随着微合金钢钢液的凝固冷却,样品表面会 [5]Kato T,Ito Y,Wamoto M K,et al.Prevention of slab surface 产生细小浮凸,该浮凸出现的温度与分布位置与第二 transverse cracking by microstructure control./S//Int,2003,43 相的析出理论计算及透射电镜表征结果相一致. (11):1742 (2)第二相析出时,其形成原子偏聚或脱溶,导致 Yong Q L,Liu Z D,Sun X J,et al.Theoretical calculation for 第二相析出位置附近局部区域成为微合金元素及C、N equilibrium solubility and compositional coefficient of V(C,N)in 原子的“贫区”,使得该局部区域与周围基体产生比容 V-bearing microalloyed steel.Iron Steel Vanadium Titanium, 2005,26(2):20 差,促使浮凸的产生 (雍岐龙,刘正东,孙新军,等.钒微合金钢中碳氮化钒固溶 (3)通过原位观察表面细小浮凸的产生,可间接 量及化学组成的计算与分析.钢铁钒钛,2005,26(2):20) 表征连续冷却过程中第二相的析出,有利于分析第二 Yong Q L,Chen M X,Pei HZ,et al.Theoretical calculation for 相对基体组织演变的影响. PTT curve of microalloy carbonitride precipitated in ferrite.IIron Steel Res,2006,18(3):30 参考文献 (雍岐龙,陈明昕,裴和中,等.微合金碳氮化物在铁素体中 Szekeres E S.A review of strand casting factors affecting trans- 沉淀析出的PTT曲线的理论计算.钢铁研究学报,2006,18 verse cracking Proceedings of the 6th International Conference (3):30) on Clean Steel.Hungary,2002:324 8] Strid J,Easterling K E.On the chemistry and stability of complex ]Dippenaar R,Moon SC,Szekeres E S.Strand surface cracks: carbide and nitrides in microalloved steels.Acta Metall,1985,33 the role of abnormally large prior-austenite grains.Iron Steel Tech- (11):2057 nol,2007,4(7):105 9]Ma F J,Wen G H,Wang W L.Effect of cooling rates on the sec- B3]Suzuki K.MiyagawaS,Saito Y,et al.Effect of microalloyed ni- ond-phase precipitation and proeutectoid phase transformation of a tride forming elements on precipitation of carbonitride and high Nb-Ti microalloyed steel slab.Steel Res Int,2013,84(4):370工程科学学报,第 37 卷,第 9 期 图 10 表面浮凸产生机理示意图 Fig. 10 Illustration of surface relief formation 图 11 不同钢种的铁素体分布. ( a) A 钢种; ( b) B 钢种 Fig. 11 Ferrite distribution of experimental steels: ( a) steel A; ( b) steel B 存在 Nb( C,N) 时,先共析铁素体主要沿晶界分布( 见 图 11( b) ) . 3 结论 ( 1) 随着微合金钢钢液的凝固冷却,样品表面会 产生细小浮凸,该浮凸出现的温度与分布位置与第二 相的析出理论计算及透射电镜表征结果相一致. ( 2) 第二相析出时,其形成原子偏聚或脱溶,导致 第二相析出位置附近局部区域成为微合金元素及 C、N 原子的“贫区”,使得该局部区域与周围基体产生比容 差,促使浮凸的产生. ( 3) 通过原位观察表面细小浮凸的产生,可间接 表征连续冷却过程中第二相的析出,有利于分析第二 相对基体组织演变的影响. 参 考 文 献 [1] Szekeres E S. A review of strand casting factors affecting trans￾verse cracking / / Proceedings of the 6th International Conference on Clean Steel. Hungary,2002: 324 [2] Dippenaar R,Moon S C,Szekeres E S. Strand surface cracks: the role of abnormally large prior-austenite grains. Iron Steel Tech￾nol,2007,4( 7) : 105 [3] Suzuki K,Miyagawa S,Saito Y,et al. Effect of microalloyed ni￾tride forming elements on precipitation of carbonitride and high temperature ductility of continuously cast low carbon Nb containing steel slab. ISIJ Int,1995,35( 1) : 34 [4] Luo H,Karjalainen L P,Porter D A,et al. The influence of Ti on the hot ductility of Nb-bearing steels in simulated continuous cast￾ing process. ISIJ Int,2002,43( 3) : 273 [5] Kato T,Ito Y,Wamoto M K,et al. Prevention of slab surface transverse cracking by microstructure control. ISIJ Int,2003,43 ( 11) : 1742 [6] Yong Q L,Liu Z D,Sun X J,et al. Theoretical calculation for equilibrium solubility and compositional coefficient of V( C,N) in V-bearing microalloyed steel. Iron Steel Vanadium Titanium, 2005,26( 2) : 20 ( 雍岐龙,刘正东,孙新军,等. 钒微合金钢中碳氮化钒固溶 量及化学组成的计算与分析. 钢铁钒钛,2005,26( 2) : 20) [7] Yong Q L,Chen M X,Pei H Z,et al. Theoretical calculation for PTT curve of microalloy carbonitride precipitated in ferrite. J Iron Steel Res,2006,18( 3) : 30 ( 雍岐龙,陈明昕,裴和中,等. 微合金碳氮化物在铁素体中 沉淀析出的 PTT 曲线的理论计算. 钢铁研究学报,2006,18 ( 3) : 30) [8] Strid J,Easterling K E. On the chemistry and stability of complex carbide and nitrides in microalloyed steels. Acta Metall,1985,33 ( 11) : 2057 [9] Ma F J,Wen G H,Wang W L. Effect of cooling rates on the sec￾ond-phase precipitation and proeutectoid phase transformation of a Nb--Ti microalloyed steel slab. Steel Res Int,2013,84( 4) : 370 ·1136·
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