Relative Partial Molar Quantities (2) S.J.T.U. Phase Transformation and Applications M=n4F+nBF公 For one mole of solution, rel rel LM =XAVA +XBVB U,F,G,H,S,V The equations for variations of thermodynamic properties with temperature, pressure,and so on apply to solutions as well as to pure components. dGrl =-SredT G=GA-GA=RTInaA SJTU Thermodynamics of Materials Spring 2006 ©X.J.Jin Lecture 13 Solution IlPhase Transformation and Applications S. J. T. U. SJTU Thermodynamics of Materials Spring 2006 © X. J. Jin Lecture 13 Solution II Relative Partial Molar Quantities (2) rel B B rel AM A += VnVnV rel B B rel M A A += VxVxV dTSGd rel rel −= A A A rel A =−= RTGGG lnα D For one mole of solution, U, F, G, H, S, V The equations for variations of thermodynamic properties with temperature, pressure, and so on apply to solutions as well as to pure components