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掌握以下教学内容:Oxidation,.Conversion to alkyl halides,Dehydration,Protection of OH as TMS ether ()Chapter 16 Ethers,Epoxides,and Sulfides(SELF-STUDY) 主要内容 16.1 Introduction 16.2 Physical Properties of Ethers 16.3 Nomenclature of Ethers 16.4 Spectroscopy of Ethers 16.5 The Williamson Ether Synthesis 16.6 Synthesis of Ethers by Alkoxymercuration-Demercuration 16.7 Industrial Synthesis:Bimolecular Dehydration of Alcohols 16.8 Cleavage of Ethers by HBr and HI 16.9 Autoxidation of Ethers 16.10 Sulfides(Thioethers) 16.11 Synthesis of Epoxides 16.12 Acid-Catalyzed Ring Opening of Epoxides 16.13 Base-Catalyzed Ring Opening of Epoxides 16.14 Orientation of Epoxide Ring Opening 16.15 Reactions of Epoxides with Grignard and Organolithium Reagents 16.16 Epoxy Resins:The Advent of Modem Glues 教学要求: 掌握以下教学内容:Villiamson ether synthesis,Alkoxymercuration,Claisen rearrangement, Epoxides. Ring-opening of epoxides,Thiols,Sulfides (十七)Chapter17 Aromatic Compounds4学时 主要内容: 17.1 Introduction:The Discovery of Benzene 17.2 The Structure and Properties of Benzene 17.3 The Molecular Orbitals of Benzene 17.4 The Molecular Orbital Picture of Cyclobutadiene 17.5 Aromatic,Antiaromatic,and Nonaromatic Compounds 17.6 Hueckel Rule 17.7 Molecular Orbital Deviation of Hueckel Rule 17.8 Aromatic ion 17.9 Heterocyclic Aromatic Compounds 掌握以下教学内容:Oxidation, Conversion to alkyl halides, Dehydration, Protection of OH as TMS ether (十六)Chapter 16 Ethers, Epoxides, and Sulfides (SELF-STUDY) 主要内容: 16.1 Introduction 16.2 Physical Properties of Ethers 16.3 Nomenclature of Ethers 16.4 Spectroscopy of Ethers 16.5 The Williamson Ether Synthesis 16.6 Synthesis of Ethers by Alkoxymercuration-Demercuration 16.7 Industrial Synthesis: Bimolecular Dehydration of Alcohols 16.8 Cleavage of Ethers by HBr and HI 16.9 Autoxidation of Ethers 16.10 Sulfides (Thioethers) 16.11 Synthesis of Epoxides 16.12 Acid-Catalyzed Ring Opening of Epoxides 16.13 Base-Catalyzed Ring Opening of Epoxides 16.14 Orientation of Epoxide Ring Opening 16.15 Reactions of Epoxides with Grignard and Organolithium Reagents 16.16 Epoxy Resins: The Advent of Modem Glues 教学要求: 掌握以下教学内容:Williamson ether synthesis, Alkoxymercuration, Claisen rearrangement, Epoxides, Ring-opening of epoxides, Thiols, Sulfides (十七)Chapter 17 Aromatic Compounds 4 学时 主要内容: 17.1 Introduction: The Discovery of Benzene 17.2 The Structure and Properties of Benzene 17.3 The Molecular Orbitals of Benzene 17.4 The Molecular Orbital Picture of Cyclobutadiene 17.5 Aromatic, Antiaromatic, and Nonaromatic Compounds 17.6 Hüeckel Rule 17.7 Molecular Orbital Deviation of Hüeckel Rule 17.8 Aromatic ion 17.9 Heterocyclic Aromatic Compounds
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